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新疆尼勒克县圆头山后碰撞花岗斑岩的同位素年代学及地球化学特征 总被引：1，自引：1，他引：0
圆头山黑云母花岗斑岩位于尼勒克县城南,岩体普遍发育的铜矿化,以中部碎裂带中矿化最强。岩石具有典型的斑状结构,斑晶由碱性长石和黑云母组成,基质以长石、云母和石英为主,并含有少量的硫化物。圆头山黑云母花岗斑岩的轻重稀土分馏明显,并且明显富集大离子亲石元素(LILE) (除Sr外)和Pb,同时亏损高场强元素(HFSE)和Nb、Ta、P、Ti,显示出弧火山岩的地球化学特征。圆头山黑云母花岗形成年龄为269±3Ma,其源区以具有弧火山岩特征的下地壳为主,同时含有少量的幔源物质,而且在岩体的侵位过程中有高(87Sr/86Sr)i (0.706054~0.709228)和高Pb含量(5.05×10-6~32.5×10-6)的陆壳物质混染。在下地壳物质熔融过程中,位于下地壳底部的富水和成矿元素的MASH带物质也被圈入,使原始岩浆富水和成矿物质。圆头山黑云母花岗斑形成于碰撞后阶段,岩石的形成主要受岩石圈地幔拆沉作用的控制,而岩石圈地幔的拆沉可能与中亚造山带的垮塌或塔里木地幔柱活动有关。 相似文献
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华北克拉通南缘潘河~1.5Ga正长岩的厘定及其构造意义 总被引：2，自引：2，他引：0
华北克拉通是否曾是Columbia超大陆的组成部分并具有一致的裂解过程一直存在争议,而已知的中元古代非造山岩浆组合集中分布于华北克拉通北缘是引起有关裂解过程争论的重要原因。作者近来在华北克拉通南缘,河南省卢氏县潘河地区,厘定了一组中元古代走向近东西的正长岩脉群。正长岩LA-ICP-MS锆石U-Pb年龄为1469±8Ma(MSWD=1.4)。岩石类型主要为黑云母正长岩,局部有少量霞石正长岩。岩体的SiO2变化于51.3%～65.7%之间,碱含量较高,K2O+Na2O总量8.32%～13.0%,铝含量较高(Al2O3=18.7%～20.0%),为碱性过铝质岩类。岩体轻重稀土分馏较为显著(La/Yb)N=14.5～34.5,具有显著的Eu负异常(δEu=0.2～0.3),强烈富集Rb、Ba、Th等大离子亲石元素和Nb、Ta、Nd、Tb等高场强元素,而Sr、Ti、P、Eu等元素显著亏损。岩石εHf(t)=-14.79～+8.16,Hf模式年龄为2.93～1.74Ga,指示成岩物质主要来源于富集岩石圈地幔的部分熔融并有地壳物质的加入。岩体形成于板内伸展构造环境,这表明华北克拉通的南缘也同时记录了华北克拉通曾经在中元古代发生过大规模的伸展作用,其伸展过程可能与Columbia超大陆的裂解有关。 相似文献
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中条山铜矿峪变石英二长斑岩的锆石U-Pb年龄和Hf同位素特征及其地质意义 总被引：6，自引：3，他引：3
中条山铜矿峪斑岩型矿床的成矿斑岩形成时代一直存在争议。本文通过对铜矿峪矿床中变石英二长斑岩的U-Pb年代学研究发现:铜矿峪变石英二长斑岩的36颗锆石的上交点年龄为2121±10Ma,207Pb/206Pb年龄从2065Ma到2196Ma,加权平均年龄为2117±13Ma,这与铜矿峪矿床的Re-Os同位素年龄(2108Ma)在误差范围内一致,暗示了成岩成矿的一致性。锆石的Hf同位素特征显示,样品的εHf(t)值介于-7.79～0.39,显示出斑岩的形成与古老地壳的部分熔融有关。同时,铜矿峪变石英二长斑岩的形成时代与华北地区的一些A型花岗岩,双峰式火山岩等与伸展有关的火成岩的形成时代大体一致,同时也与中条裂谷的活动一致,说明铜矿峪变石英二长斑岩形成于一个伸展的动力学背景下。因此,本文认为铜矿峪矿床是与大陆伸展环境的斑岩型矿床。 相似文献
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Wheat straw burning and its associated impacts on Beijing air quality 总被引：18，自引：0，他引：18
Based on MODIS images, large-scale flow field charts and environmental monitoring data, we thor- oughly analyzed the spatial distribution of wheat straw burning in North China, with focus on its envi- ronmental impacts on the air quality of Beijing and pollution transport paths. And we anatomized changes of air quality in Beijing under the impacts of pollution generated by wheat straw burning around. The results indicate that: (1) The North China Plain, a winter-wheat growing area, is the main source of pollutants induced by wheat straw burning in Beijing. The direction of south-west is the dominant heavy pollution transport path. (2) Impacts of wheat straw burning on air quality are mainly manifested by significantly increasing CO concentration. (3) Precursors of O3 generated by wheat straw burning, combining with favorable meteorological conditions, can induce increasing O3 concentration greatly. NO concentration will be greatly increased due to decreasing O3 concentration at night. (4) Atmospheric particles, especially the fine ones, from wheat straw burning exert considerable influ- ence on Beijing air quality. (5) Different contributions of wheat straw burning to pollutants are identified. Ratios of PM10/SO2, CO/SO2, etc., can be applied to indicate pollution extent of wheat straw burning. High ratios of PM10/SO2 and CO/SO2 show that the air quality was heavily impacted by wheat straw burning and these ratios can be employed as indicators of contribution of wheat straw burning to the degradation of Beijing air quality. (6) Randomness of wheat straw burning activities renders random outbreak of air pollution of this type. Regional and extensive wheat straw burning activities can cause serious air pollution event. 相似文献
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Abundant natural gas inclusions were found in calcite veins filled in fractures of Central Fault Belt across the centre of Ordos Basin. Time of the calcite veins and characteristics of natural gas fluid inclusion were investigated by means of dating of thermolum luminescence (TL) and analyzing stable isotope of fluid inclusion. Results show that natural gas inclusion formed at 130–140°C with salinity of 5.5 wt%–6.0 wt% NaCl. It indicates that natural gas inclusion is a kind of thermal hydrocarbon fluid formed within the basin. Method of opening inclusion by heating was used to analyze composition of fluid inclusion online, of which the maximal hydrocarbon gas content of fluid inclusion contained in veins is 2.4219 m3/t rock and the maximal C1/ΣC i ratio is 91%. Laser Raman spectroscopy (LRS) was used to analyze chemistry of individual fluid inclusion in which the maximal hydrocarbon gas content is 91.6% compared with little inorganic composition. Isotope analysis results of calcite veins show that they were deposited in fresh water, in which the δ 13CPDB of calcite veins is from −5.75‰ to 15.23‰ and δ 18OSMOW of calcite veins is from 21.33‰ to 21.67‰. Isotope results show that δ 13C1 PDB of natural gas fluid inclusion is from −21.36‰ to −29.06‰ and δDSMOW of that is from −70.89‰ to −111.03‰. It indicates that the gas of fluid inclusion formed from coal source rocks and it is the same as that of natural gas of Mizhi gas reservoir. Results of TL dating show that time of calcite vein is (32.4±3.42)×104 a, which is thought to be formation time of gas inclusion. It indicated that natural gas inclusion contained in calcite veins recorded natural gas leakage from Mizhi gas reservoir through the Central Fault Belt due to Himalayan tectonic movement.
相似文献6.
滇东北峨眉山玄武岩区的沉积型铜矿床 总被引：3，自引：0，他引：3
在滇东北峨眉山玄武岩分布区上二叠统宣威组中发现沉积型铜矿床。文章对此类沉积型铜矿床的地质特征和成矿作用特征进行了较系统的研究,结合矿物成分和硫同位素测试结果,探讨了矿床的形成过程和找矿前景。研究表明,区内沉积型铜矿床主要有两种矿化类型:结核状铜矿化和浸染状铜矿化,矿石矿物以辉铜矿、斑铜矿、铜蓝等为主;成矿受上二叠统宣威组沉积地层控制,与峨眉山玄武岩喷溢形成的古火山构造和古地形以及火山期后的热泉活动关系密切,有机质在成矿过程中可能发挥了作用;成矿过程可能从沉积成岩阶段一直延续到成岩期后。区域上假整合覆盖于上二叠统峨眉山玄武岩之上的宣威组沉积岩系具有良好的找矿前景。 相似文献
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Abundant natural gas inclusions were found in calcite veins filled in fractures of Central Fault Belt across the centre of Ordos Basin. Time of the calcite veins and characteristics of natural gas fluid inclusion were investigated by means of dating of thermolum luminescence (TL) and analyzing stable isotope of fluid inclusion. Results show that natural gas inclusion formed at 130―140℃ with salinity of 5.5 wt%―6.0 wt% NaCl. It indicates that natural gas inclusion is a kind of thermal hydrocarbon fluid formed within the basin. Method of opening inclusion by heating was used to analyze composition of fluid inclusion online, of which the maximal hydrocarbon gas content of fluid inclusion contained in veins is 2.4219 m3/t rock and the maximal C1/Σci ratio is 91%. Laser Raman spectroscopy (LRS) was used to analyze chemistry of individual fluid inclusion in which the maximal hydrocarbon gas content is 91.6% compared with little inorganic composition. Isotope analysis results of calcite veins show that they were deposited in fresh water, in which the δ13CPDB of calcite veins is from -5.75‰ to 15.23‰ andδ18OSMOW of calcite veins is from 21.33‰ to 21.67‰. Isotope results show thatδ13C1 PDB of natural gas fluid inclusion is from -21.36‰ to -29.06‰ and δDSMOW of that is from -70.89‰ to -111.03‰. It indicates that the gas of fluid inclusion formed from coal source rocks and it is the same as that of natural gas of Mizhi gas reservoir. Results of TL dating show that time of calcite vein is (32.4±3.42)×104 a, which is thought to be formation time of gas inclusion. It indicated that natural gas inclusion contained in calcite veins recorded natural gas leakage from Mizhi gas reservoir through the Central Fault Belt due to Himalayan tectonic movement. 相似文献
8.
Abundant natural gas inclusions were found in calcite veins filled in fractures of Central Fault Belt across the centre of Ordos Basin. Time of the calcite veins and characteristics of natural gas fluid inclusion were investigated by means of dating of thermolum luminescence (TL) and analyzing stable isotope of fluid inclusion. Results show that natural gas inclusion formed at 130–140°C with salinity of 5.5 wt%–6.0 wt% NaCl. It indicates that natural gas inclusion is a kind of thermal hydrocarbon fluid formed within the basin. Method of opening inclusion by heating was used to analyze composition of fluid inclusion online, of which the maximal hydrocarbon gas content of fluid inclusion contained in veins is 2.4219 m3/t rock and the maximal C1/ΣC i ratio is 91%. Laser Raman spectroscopy (LRS) was used to analyze chemistry of individual fluid inclusion in which the maximal hydrocarbon gas content is 91.6% compared with little inorganic composition. Isotope analysis results of calcite veins show that they were deposited in fresh water, in which the δ 13CPDB of calcite veins is from ?5.75‰ to 15.23‰ and δ 18OSMOW of calcite veins is from 21.33‰ to 21.67‰. Isotope results show that δ 13C1 PDB of natural gas fluid inclusion is from ?21.36‰ to ?29.06‰ and δDSMOW of that is from ?70.89‰ to ?111.03‰. It indicates that the gas of fluid inclusion formed from coal source rocks and it is the same as that of natural gas of Mizhi gas reservoir. Results of TL dating show that time of calcite vein is (32.4±3.42)×104 a, which is thought to be formation time of gas inclusion. It indicated that natural gas inclusion contained in calcite veins recorded natural gas leakage from Mizhi gas reservoir through the Central Fault Belt due to Himalayan tectonic movement. 相似文献
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Evaluation of the carbon isotopic effects of NDIR and CRDS analyzers on atmospheric CO2 measurements
LingJun Xia LingXi Zhou Marcel V. van der Schoot Chris W. Rella LiXin Liu Gen Zhang HongYang Wang 《中国科学:地球科学(英文版)》2016,59(6):1299-1307
Non-dispersive infrared(NDIR) and cavity ring-down spectroscopy(CRDS) CO_2 analyzers use 12CO_2 isotopologue absorption lines and are insensitive to all or part of other CO_2-related isotopologues. This may produce biases in CO_2 mole fraction measurements of a sample if its carbon isotopic composition deviates from that of the standard gases being used. To evaluate and compare the effects of carbon isotopic composition on NDIR and CRDS CO_2 analyzers, we prepared three test sample air cylinders with varying carbon isotopic abundances and calibrated them against five standard cylinders with ambient carbon isotopic composition using CRDS and NDIR systems. We found that the CO_2 mole fractions of the sample cylinders measured by G1301(CRDS) were in good agreement with those measured by Lo Flo(NDIR). The CO_2 values measured by both instruments were higher than that of a CO_2 isotope measured by G2201i(CRDS) analyzer for a test cylinder with depleted carbon isotopic composition δ~(13)C =-36.828‰, whereas no obvious difference was found for other two test cylinders with δ~(13)C=-8.630‰ and δ~(13)C=-15.380‰, respectively. According to the theoretical and experimental results, we concluded that the total CO_2 mole fractions of samples with depleted isotopic compositions can be corrected on the basis of their 12CO_2 values calibrated by standard gases using Lo Flo and G1301 if the δ~(13)C and δ18O values are known. 相似文献
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