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S. Panic V. Guzsvány Z. Kónya Á. Kukovecz G. Boskovic 《International Journal of Environmental Science and Technology》2017,14(6):1297-1306
Because of their high adsorption capacity, carbon nanotubes have caught the attention of the scientific community and a number of experimental results confirmed their ability to adsorb many toxins from water. The aim of this work was to study the kinetics, equilibrium and thermodynamics of thiamethoxam adsorption by multi-walled carbon nanotubes in aqueous solutions. To further elucidate the influence of nanotube structure on the adsorption mechanism, the experiments were performed on both fresh (pristine) and nitric acid-modified multi-walled carbon nanotubes. The results of the kinetic studies were analyzed using three kinetic models, while the adsorption equilibrium was tested against four different adsorption models. Based on the results, and the physico-chemical properties of the adsorbent and adsorbate, it is proposed that the dominant mechanism for thiamethoxam molecules attaching to multi-walled carbon nanotubes is caused by aromatic π–π interactions (electron donor–acceptor interactions). The results of thermodynamic calculations based on the adsorption data indicate the exothermic nature of the process, regardless of the carbon nanotube type used. The decrease in entropy and the consequent negative change in Gibbs free energy, as expected, confirm the spontaneity of thiamethoxam adsorption on both pristine and functionalized multi-walled carbon nanotubes. 相似文献
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Lucija Boskovic Igor S. Altman Roger D. Braddock Igor E. Agranovski 《洁净——土壤、空气、水》2009,37(11):843-849
Elongated aerosol particle removal on fibrous filters has been investigated. It was shown that particle agglomerates are removed much more efficiently compared to the regularly shaped single particles with identical electrical mobility diameter at two filtration velocities tested. The experimental results were compared with the classical filtration theory and it was shown that the theoretical predictions, which are based on the assumption that the particles are spherical, are significantly different compared to an agglomerate filtration efficiency value. In order to account for a particle shape non-regularity, dominating nanoparticle removal mechanisms were firstly evaluated for a regular particle of certain size and then adjusted by fitting coefficients k1 (for diffusion component) and k2 (for interception). These coefficients were determined by fitting the theoretical values that gives the best coincidence with the measured data points. As was further demonstrated theoretically, the coefficient k1 is identical to the ratio of the actual particle surface area to the surface area of the spherical particle of the equivalent diameter. On the other hand, the coefficient k2 was found to be equal to the ratio of the projection of a given particle on a plane perpendicular to a streamline, to that of the spherical particle of the equivalent diameter. The reported findings would allow undertaking more accurate evaluation of the removal efficiency of non-regular aerosol particle, which is especially important for industrial applications where non-regular aerosols are frequently met. 相似文献
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G. Boskovic M. Kovacevic E. Kiss J. Radnik M. Pohl M. Schneider U. Bentrup A. Bruckner 《International Journal of Environmental Science and Technology》2012,9(2):235-246
Two nanocrystalline palladium-supported tin oxide catalysts for water denitration were synthesized by a modified sol?Cgel technique using appropriate chloride precursors for both support and active phases, and citric acid to tune the rate of hydrolysis and condensation. The difference among sample preparation procedures refers to the moment of the noble metal loading to the support, as well as to the calcination temperature altitude followed. Thus, mesoporous tin oxide was synthesized by a sol?Cgel method following calcination at 700°C. The palladium active phase was introduced afterwards by means of palladium chloride solution impregnation, followed by calcination at 400°C (sample 1). Alternatively, simultaneous complexation of both metal and support precursors followed by single calcination at 700°C was applied for preparation of sample 2. The former sample showed higher activity and selectivity in hydro-denitration of water model system initially containing 100?ppm of nitrates. This was explained by preferential textural, morphological and structural properties accomplished by early contact of metal and support nanoparticles, while achieved by calcination at high single temperature forcing diffusion of palladium ions into the tin oxide matrix. The outcome is very well distribution of palladium and strong metal?Csupport interaction leading to multivalent tin. This indicates partly reduced tin oxide formation in the course of its reduction in hydrogen, which may act as active site in denitration reaction. 相似文献
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A new thermophoretic particle precipitator has been developed for representative and efficient collection of aerosol particles from the ambient air and technological pipelines. The device consists of hot and cold plates (5 × 5 cm2) capable of operation at temperature gradients ranging from 20 000 to 100 000 K/m. A gas sample is made to pass through a 1‐mm slot between the plates at a flow rate of up to 1.5 L/min, which makes the device suitable for operation in conjunction with common aerosol instruments including DMA and diffusion batteries with similar operational flow rates. It was shown that the efficiency of the device was highest for the lowest gas flow rate used (0.3 L/min) reaching a level of above 99%. The efficiency was decreased reaching its minimal values at the highest flow rate investigated (1.5 L/min). However, even for highest flow rate, the average efficiency for removal of particle smaller than 60 nm was around 50%. 相似文献
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