排序方式： 共有19条查询结果，搜索用时 312 毫秒
1.
Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most
rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable
excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this
type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive
decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed
by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had
dissolved. 相似文献
2.
Gerrit de Leeuw Lucinda Spokes Tim Jickells Carsten Ambelas Skjth Ole Hertel Elisabetta Vignati Susanne Tamm Michael Schulz Lise-Lotte Srensen Britta Pedersen Laura Klein K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743
The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m−2 day−1, which has the potential to promote primary productivity of 5.3 mmol C m−2 day−1. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km−1, i.e. 0.19 mmol N m−2 day−1 which has the potential to promote primary productivity of 1.2 mmol C m−2 day−1. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NOx and NH3 are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m−2 day−1, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m2 is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem. 相似文献
3.
4.
Information on fatalities from lightning strikes has been extracted from a specially compiled database on natural hazards in Australia. Records dating from 1803–1991 indicate that at least 650 persons have been killed by lightning strikes. Maps and charts show the percentages of victims with respect to age, sex, locality, activity, and other circumstances of the strike. The majority of the 650 fatalities recorded have occurred along the more populous southeastern coast. The overall death rate, from 1910–1989, is 0.08 per 100 000 population. The annual number of lightning fatalities has decreased with time, from a death rate of 0.21 in 1910–1919 to 0.01 in 1980–1989. This trend is more pronounced when population figures are taken into account. The group that has been most at risk in Australia is that of males aged 15–19, followed by males aged 20–34. The male:female ratio of victims has decreased with time but is not approaching equality, being 11.6 in 1910–1919 and 5.3 in 1980–1989. The diurnal and monthly occurrences of lightning fatalities peak at 12.00–18.00 hours and November-February respectively. About 86% of fatalities have occurred outdoors and 14% have occurred indoors. Approximately three-fifths of fatalities have been work-related, and the group of workers that has traditionally been most at risk is that of land-workers. Approximately one-fifth of fatalities have been recreation-related, although this proportion has been increasing with time. The recreational activities of water sports, golf, and cricket have had the greatest number of lightning fatalities. Comparisons are made between these data and the results of other similar studies, both in Australia and overseas. 相似文献
5.
Steven Emerson Susan Kalhorn Lucinda Jacobs Bradley M Tebo Kenneth H Nealson Reinhardt A Rosson 《Geochimica et cosmochimica acta》1982,46(6):1073-1079
A simple mass balance for dissolved manganese(II) in waters containing low levels of oxygen in Saanich Inlet indicates that the residence time for Mn(II) removal to the solid phase is on the order of a few days. The average oxidation state of Mn in particulate material sampled from the region of Mn removal was 2.3–2.7, and electron micrographs revealed structures characteristic of bacterially formed Mn precipitates. Radiotracer experiments utilizing 54Mn(II) indicated that removal of Mn from solution in the region of active uptake was substantially blocked by a poison mixture, demonstrating that Mn(II) binding to particulates is catalyzed by bacteria in this environment. 相似文献
6.
7.
The study of aerosols and rainwater presented here demonstrates that episodic atmospheric deposition events associated with southeasterly flow are quantitatively significant for large areas of the North Atlantic Ocean. This paper considers aluminium and manganese, with predominantly crustal sources, and lead and zinc, which are mobilised into the atmosphere primarily through anthropogenic activity. High levels of all trace metals are associated with southeasterly flow from Europe as the air passes over heavily populated and industrialised regions before reaching the northeast Atlantic Ocean. Fluxes calculated using the 1% HNO3 acid soluble metal concentration show that, although the climatological norm for this area is westerly flow, short-lived southeasterly transport events dominate the input of trace metals to this ocean region. This material may be toxic to phytoplankton or may be represent a new source of nutrients to the biological community. A significant decrease in atmospheric lead levels in polluted air is seen between June 1996 and May 1997, reflecting the decrease in use of leaded fuels in Europe. Comparing atmospheric flux values to sediment trap metal fluxes shows that the atmosphere represents the dominant source of zinc to the deep ocean, whereas an additional, non-atmospheric, manganese source this required, perhaps from mobilisation of sedimentary material from the continental shelf or long range advection of manganese rich Saharan material. 相似文献
8.
Abstract— Velocities of ejecta from seven impacts of aluminum projectiles into coarse-grained sand have been measured with a laser-based apparatus that produces stroboscopic photographs of individual grains in ballistic flight. Speeds and angles of the majority of the ejecta can then be measured very precisely. There appears to be little effect of impact velocity on the functional relationship between the scaled, radial launch position and either the speed or angle of ejection; the seven experiments covered a range of impact velocities from 0.8 to 1.9 kms—1. The measured ejection speeds follow power-law distributions, as predicted by dimensional analysis, but the angle of ejection is not constant throughout a given event as predicted. Indeed, the angle of ejection declines gradually with increasing radial distance from the impact point, but there are indications that the angle increases again as the position of the final crater's rim is approached. The exponents determined from scaled crater dimensions and ejection-speed distributions are substantially different. Although this might imply that assumptions used in the dimensional analysis are not valid, it is also possible that the coarse sand, whose component grains were comparable in dimension to the diameter of the impactors, instead presented a target that was more of an inhomogeneous aggregate of large fragments than a uniform, continuous medium. 相似文献
9.
Previous work has shown that the type and pH history of an aerosol governs trace metal solubility in rainwater. This study concentrates on the crustal elements Al, Fe and Mn and identifies additional processes which affect dissolution not only in the atmosphere but also on mixing into seawater. Aerosol dissolution experiments (at aerosol concentrations of about 30 mg 1–1) show manganese exhibiting high solubility at the low pH values typical of clouds (54±2.5% at pH 2, with results expressed in mole percent units) with 85% of this increase occurring within 6 hours of acidification. The percentage dissolution decreases to 50% at pH values representative of rainwater (pH 5.5) and to 26±4% at pH 8, typical of seawater. No such dramatic solution phase removal occurs at pH 8 in the presence of inorganic anions (to a final solubility of 44±2%). Thus the extent of manganese dissolution depends strongly on whether aerosols are cycled through acidic environments and on subsequent inorganic complexation once rainwater mixes into sea. Aluminium shows highest dissolution (7.1±0.6%) at low pH with 78% of this increase occurring within 6 hours of acidification. Rapid solution phase removal occurs on increasing the pH to that representative of rainwater (to 0.9±0.4% with 87% of this decrease occurring within 15 min). As a consequence of acid cycling and aluminium's amphoteric nature, solubility is enhanced at seawater pH (2.3±0.3%) over that in rain. Iron shows a strong pH-solubility relationship with highest solubility at low pH (4.7±0.2%), 70% of this value being reached within 6 hours of acidification, and decreasing rapidly to 0.17% as pH is raised to 8. Addition of inorganic anions at pH 8 to simulate mixing into seawater causes a further decrease in solubility, perhaps due to anion induced colloid destabilisation. Photochemical reduction also effects solubility under low pH conditions with Fe(II) comprising 1% of the total iron in the Saharan Aerosol used and 8.4% in an Urban material at a pH of 2. This element shows rapid solution phase removal with increasing particulate load which is tentatively rationalised in terms of a simple Kd approach. 相似文献
10.
Bioaccumulation of chromium and its effects on reproduction in Neanthes arenaceodentata (polychaeta)
The levels of hexavalent chromium (Cr VI) that caused diminished reproductive ability in the polychaete Neanthes arenaceodentata were determined. Changes in numbers of offspring and time of spawning caused by Cr VI at 1 to 38 ug/litre during two generations of exposure (309 days) were measured. Time to spawning was unaffected but it was found that reductions in numbers of offsprings occurred at 16 to 38 μl/litre. Bioaccumulation of chromium was also measured and found to be proportional to exposure levels; however, a direct relationship between tissue concentration and reduced numbers of offspring could not be established. 相似文献