Rumuruti chondrites: Noble gases,exposure ages,pairing, and parent body history     

Ludolf SCHULTZ  Hartwig W. WEBER  Luitgard FRANKE 《Meteoritics & planetary science》2005,40(4):557-571

Abstract— In this paper, we present concentration and isotopic composition of the light noble gases He, Ne, and Ar as well as of ⁸⁴Kr, ¹³²Xe, and ¹²⁹Xe in bulk samples of 33 Rumuruti (R) chondrites. Together with previously published data of six R chondrites, exposure ages are calculated and compared with those of ordinary chondrites. A number of pairings, especially between those from Northwest Africa (NWA), are suggested, so that only 23 individual falls are represented by the 39 R chondrites discussed here. Eleven of these meteorites, or almost 50%, contain solar gases and are thus regolithic breccias. This percentage is higher than that of ordinary chondrites, howardites, or aubrites. This may imply that the parent body of R chondrites has a relatively thick regolith. Concentrations of heavy noble gases, especially of Kr, are affected by the terrestrial atmospheric component, which resides in weathering products. Compared to ordinary chondrites, ¹²⁹Xe/¹³²Xe ratios of R chondrites are high.  相似文献   

Soil CO2 flux baseline in an urban monogenetic volcanic field: the Auckland Volcanic Field, New Zealand     

Agnès Mazot  Elaine R. Smid  Luitgard Schwendenmann  Hugo Delgado-Granados  Jan Lindsay 《Bulletin of Volcanology》2013,75(11):1-9

The Auckland Volcanic Field (AVF) is a dormant monogenetic basaltic field located in Auckland, New Zealand. Though soil gas CO₂ fluxes are routinely used to monitor volcanic regions, there have been no published studies of soil CO₂ flux or soil gas CO₂ concentrations in the AVF to date or many other monogenetic fields worldwide. We measured soil gas CO₂ fluxes and soil gas CO₂ concentrations in 2010 and 2012 in varying settings, seasons, and times of day to establish a baseline soil CO₂ flux and to determine the major sources of and controlling influences on Auckland's soil CO₂ flux. Soil CO₂ flux measurements varied from 0 to 203 g m^?2 day^?1, with an average of 27.1 g m^?2 day^?1. Higher fluxes were attributed to varying land use properties (e.g., landfill). Using a graphical statistical approach, two populations of CO₂ fluxes were identified. Isotope analyses of δ¹³CO₂ confirmed that the source of CO₂ in the AVF is biogenic with no volcanic component. These data may be used to assist with eruption forecasting in the event of precursory activity in the AVF, and highlight the importance of knowing land use history when assessing soil gas CO₂ fluxes in urban environments.  相似文献   

Itqiy: A study of noble gases and oxygen isotopes including its terrestrial age and a comparison with Zakłodzie     

Andrea Patzer  Dolores H. Hill  William V. Boynton  Luitgard Franke  Ludolf Schultz  A. J. Timothy Jull  Lanny R. McHargue  Ian A. Franchi 《Meteoritics & planetary science》2002,37(6):823-833

Abstract— We report noble gas, oxygen isotope, ¹⁴C and ¹⁰Be data of Itqiy as well as noble gas, ¹⁴C and ¹⁰Be results for Zak?odzie. Both samples have been recently classified as anomalous enstatite meteorites and have been compared in terms of their mineralogy and chemical composition. The composition of enstatite and kamacite and the occurrence of specific sulfide phases in Itqiy indicate it formed under similar reducing conditions to those postulated for enstatite chondrites. The new results now seem to point at a direct spatial link. The noble gas record of Itqiy exhibits the presence of a trapped subsolar component, which is diagnostic for petrologic types 4–6 among enstatite chondrites. The concentration of radiogenic ⁴He is very low in Itqiy and indicates a recent thermal event. Its ²¹Ne cosmic‐ray exposure age is 30.1 ± 3.0 Ma and matches the most common age range of enstatite chondrites (mostly EL6 chondrites) but not that of Zak?odzie. Itqiy's isotopic composition of oxygen is in good agreement with that observed in Zak?odzie as well as those found in enstatite meteorites suggesting an origin from a common oxygen pool. The noble gas results, on the other hand, give reason to believe that the origin and evolution of Itqiy and Zak?odzie are not directly connected. Itqiy's terrestrial age of 5800 ± 500 years sheds crucial light on the uncertain circumstances of its recovery and proves that Itqiy is not a modern fall, whereas the ¹⁴C results from Zak?odzie suggest it hit Earth only recently.  相似文献   

New noble gas data of primitive and differentiated achondrites including Northwest Africa 011 and Tafassasset     

Andrea PATZER  Ludolf SCHULTZ  Luitgard FRANKE 《Meteoritics & planetary science》2003,38(10):1485-1497

Abstract— This work reports on the noble gas inventory of 3 new acapulcoites, 3 brachinites, 2 new eucrites from the Dar al Gani region in Libya, the unique achondrite Dar al Gani (DaG) 896 from the same locality, the new eucrite‐like achondrite Northwest Africa (NWA) 011, and the controversial sample Tafassasset. We determined cosmic ray exposure and gas retention ages, evaluated shielding conditions, and discuss the trapped noble gas component of the specimens. All exposure ages are within the known range of stony meteorites and partly confirm previously established age clusters. Shielding conditions vary, suggesting substantial shielding for all 3 brachinites and Tafassasset. We cannot exclude, however, that the Mg‐rich composition of brachinites simply simulates heavy shielding. Regarding the trapped component, we found Q‐like compositions only for the acapulcoite Thiel Mountains (TIL) 99002. The brachinite Elephant Moraine (EET) 99402 yields a high, subsolar ³⁶Ar/¹³²Xe ratio of ?400 along with a slightly elevated ⁸⁴Kr/¹³²atio, indicating minor atmospheric contamination. All the other samples, particularly the eucrite DaG 983, are characterized by clearly elevated Ar/Kr/Xe ratios due to significant terrestrial alteration. Tafassasset exhibits noble gas parameters that are different from those of CR chondrites, including a relatively high cosmic ray exposure age, the absence of a solar component, low ¹³²Xe concentrations, a low trapped ³⁶Ar/¹³²Xe ratio of ?30, and a noticeable amount of radiogenic ¹²⁹Xe. Similar attributes have been observed for some primitive achondrites. These attributes are also consistent with the metamorphic character of the sample. We, therefore, consider Tafassasset's noble gas record to be inconclusive as to its classification (primitive achondrite versus metamorphosed CR chondrite).  相似文献   

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides     

Kees WELTEN  Marc W. CAFFEE  Luitgard FRANKE  A. J. Timothy JULL  Marlene D. LeCLERC  Knut METZLER  Ulrich OTT 《Meteoritics & planetary science》2011,46(7):970-988

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.  相似文献   

Cosmogenic radionuclides and noble gases in Antarctic H chondrites with high and normal natural thermoluminescence levels     

Jennifer L. MOKOS  Luitgard FRANKE  Peter SCHERER  Ludolf SCHULTZ  Michael E. LIPSCHUTZ 《Meteoritics & planetary science》2000,35(4):713-721

Abstract— We report noble gas data for 37 H chondrites collected from the Allan Hills by EUROMET in the 1988–1989 field season. Among these are 16 specimens with high levels (>100 krad) of natural thermoluminescence (NTL), originally interpreted as signaling their derivation from a single meteoroid with an orbit that became Earth‐crossin‐100 ka ago. One of these 16 is an H3 chondrite with a cosmic‐ray exposure age of ～33 Ma and clearly represents a separate fall. The other 15 H4–6 chondrites derive from three separate meteoroids, each of which is represented by a five or six member group. These groups have mean exposure ages of 3.7, 4.1, and 6.6 Ma: the middle‐group members all contain solar Ne. The two younger groups also seem to each include a few H chondrites with normal NTL levels. Measurements of cosmogenic ¹⁰Be (1.5 Ma), ²⁶AI (710 ka), and ³⁶CI (301 ka) in 14 of the high‐NTL chondrites indicate that all reflect a simple irradiation history. In contrast, many of a different (38 member) randomly selected suite of Antarctic H chondrites seem to have different cosmic‐ray irradiation histories. The 3.7 and 6.6 Ma groups from the 37 member Allan Hills suite come from about 5–30 and about 5–10 cm depths in 80–125 and 60–125 cm radius meteoroids, respectively.  相似文献   

Noble gas record and cosmic‐ray exposure history of the new CO3 chondrite Moss––Comparison with Lancé and other CO chondrite falls     

Rainer BARTOSCHEWITZ  Ulrich OTT  Luitgard FRANKE  Siegfried HERRMANN  Yukio YAMAMOTO  Keisuke NAGAO  Morten BILET  Thomas GRAU 《Meteoritics & planetary science》2010,45(8):1380-1391

Abstract– The Moss meteorite is the first CO chondrite fall after a time period of 70 yr and the least terrestrially contaminated member of its group. Its cosmic‐ray exposure (CRE) age (T₃ ～ 13.5 Ma; T₂₁ ～ 14.6 Ma) is distinct among CO chondrites and, within witnessed falls is the shortest after Lancé, which we have reanalyzed. Gas retention ages are approximately 3.95 × 10⁹ yr (U/Th‐He) and approximately 4.43 × 10⁹ yr (K/Ar), respectively. Trapped Ar, Kr, and Xe are present in Moss in abundances typical for CO chondrites, with “planetary” elemental and isotopic compositions. Presence of HL‐xenon from presolar diamonds is observed in the stepwise release analysis of Lancé. It may also be present in Moss, but it is difficult to ascertain in single‐step bulk analyses. It follows from our new data combined with a survey of the literature that the abundance of trapped gases in CO chondrites is not a good indicator of their petrological subtype.  相似文献   

Throughfall and stemflow vary seasonally in different land‐use types in a lower montane tropical region of Panama          下载免费PDF全文

Catriona M.O. Macinnis‐Ng  Eric E. Flores  Henry Müller  Luitgard Schwendenmann 《水文研究》2014,28(4):2174-2184

Catchment hydrology is influenced by land‐use change through alteration of rainfall partitioning processes. We compared rainfall partitioning (throughfall, stemflow and interception) and soil water content in three land‐use types (primary forest, secondary forest and agriculture) in the Santa Fe region of Panama. Seasonal patterns were typified by larger volumes of throughfall and stemflow in the wet season, and the size of precipitation events was the main driver of variation in rainfall redistribution. Land‐use‐related differences in rainfall partitioning were difficult to identify due to the high variability of throughfall. However, annual throughfall in agricultural sites made up a larger proportion of gross precipitation than throughfall in forest sites (94 ± 1, 83 ± 6 and 81 ± 1% for agriculture, primary and secondary forests, respectively). Proportional throughfall (% of gross precipitation becoming throughfall) was consistent throughout the year for primary forest, but for secondary forest, it was larger in the dry season than the wet season. Furthermore, proportional stemflow in the dry season was larger in secondary forest than primary forest. Stemflow, measured only in primary and secondary forests, ranged between 0.9 and 3.2% of gross precipitation. Relative soil moisture content in agricultural plots was generally elevated during the first half of the dry season in comparison to primary and secondary forests. Because throughfall is elevated in agricultural plots, we suggest careful management of the spatial distribution and spread of this land‐use type to mitigate potential negative impacts in the form of floods and high erosion rates in the catchment. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献