Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Book review     

D. W. Connell  Thomas M. Baugh 《Estuaries and Coasts》1992,15(2):255-255

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Numerical models of subduction and forearc deformation     

Thomas M. Tharp 《Geophysical Journal International》1985,80(2):419-437

Summary. Finite element models for shallow subduction produce realistic behaviour for a wide variety of mechanical strength and density distributions. Characteristic displacements are found to occur even without a discrete low-strength megathrust if there is a high-density subducted plate to localize lithospheric compression. A high-density plate is itself unnecessary in the presence of a low-strength megathrust and regional compression.
Successful finite element models produce an outer arc at the top of the trench slope, and forearc basin with geometry characteristic of natural analogues. These structural features occur by upward inelastic bending of the lithospheric wedge overlying the megathrust. This mechanically unstable behaviour may dissipate significant energy and cause the megathrust to migrate continuously by accretion, tectonic erosion, or abandonment and reinitiation farther offshore. Upward bending in the overriding plate is promoted by low megathrust dip, low megathrust shear strength, and high horizontal compression in the overriding plate.  相似文献   

Multiple longshore sand bars in the upper Chesapeake Bay     

Thomas J. Dolan  Robert G. Dean 《Estuarine, Coastal and Shelf Science》1985,21(5):727-743

In the upper Chesapeake Bay (Maryland, U.S.A.) field surveys were conducted at 18 multiple longshore sand bar sites. The multiple bar systems were found in water depths less than approximately 2 m (mean sea level), and exhibited mild bottom slopes of 0·0052 or less. The number of bars composing each system ranged from four to 17 and the spacing between the crests typically increased in the offshore direction, ranging from 12 to 70 m. Bar height also typically increased with distance offshore and ranged from 0·03 to 0·61 m. A grain size analysis of crest and trough sediment did not reveal any significant differences and the sediment was categorized as ‘fine sand’. A review of the literature data indicated that the Chesapeake Bay multiple bars possessed similar characteristics to those found in Gelding Bay (Baltic Sea); similarities in fetch, wave height and tidal range between the two bays may account for this finding. The surf-scaling parameter indicated that the multiple bar systems were extremely dissipative with regard to wave energy, and wave height appeared to be an important factor in controlling bar spacing and bar height. A multiple wave break point hypothesis was discussed as a possible mechanism for the formation of Chesapeake Bay multiple longshore bars, and limited observational evidence appeared to support such a mechanism.  相似文献   

Simulation of adaptive optics for the Vacuum Tower Telescope     

Anita Enmark  Thomas Berkefeld  Oskar von der Lühe  Torben Andersen 《Experimental Astronomy》2006,21(2):87-99

A simulation model of the adaptive optics of the German Vacuum Tower Telescope (VTT), Observatorio del Teide, Tenerife, is presented. The model uses modules from the integrated model of the Euro50 extremely large telescope, and includes submodels of a Shack-Hartmann wavefront sensor, a de-formable mirror, a tip-tilt mirror, high-voltage amplifier low-pass filters, a reconstructor and a controller. We investigate the impact on the closed loop bandwidth of changes in controller configuration and certain system parameters, such as low pass filter bandwidth and camera integration and readout time. Control strategies were tested on simple models before implementation on the full VTT model. Using the models, different control strategies are compared.  相似文献   

A multi‐level parallelized substructuring‐frontal solution for coupled thermo/hydro/mechanical problems in unsaturated soil     

H.R. Thomas  H.T. Yang  Y. He  P.J. Cleall 《国际地质力学数值与分析法杂志》2003,27(11):951-965

This paper proposes a multi‐level parallelized substructuring–frontal combined algorithm for the analysis of the problem of thermo/hydraulic/mechanical behaviour of unsaturated soil. Temperature, displacement, pore water pressure and pore air pressure are treated as the primary variables in a non‐linear analysis. Details are given firstly of the substructuring–frontal combined approach. The incorporation of the algorithm in a multi‐level parallel strategy is then discussed. The parallel processing can thus be carried out at different substructural levels. The method thus developed impacts, in a positive way, on both computer storage requirement and execution time. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Mesoscale linear streaks on Mars: environments of dust entrainment     

P.C Thomas  P Gierasch  D.S Miller  B Cantor 《Icarus》2003,162(2):242-258

Variable surface albedo features on Mars are likely caused by the entrainment and deposition of dust by the wind. Most discrete markings are associated with topographic forms or with regional slopes that serve to alter the effective wind shear stress on the surface. Some of the largest variable features, here termed mesoscale linear streaks, are up to 400 km in length and repeatedly occur in one of the smoothest regions of Mars: Amazonis Planitia. Their orientations and apparent season of variability as observed by Viking and Mars Orbiter cameras indicate linear streak formation by enhanced surface wind stresses during regional or local dust storms and during the initial stages of global dust storms. They provide an example of the ability of large-scale winds, without significant local enhancement, to initiate dust motion on Mars. The sizes and spacing of the linear streaks may be controlled by boundary layer rolls. The repetitive formation of these streaks, over a span of more than 11 Mars years, gives one measure of the stability of Mars’ eolian processes.  相似文献   

40Ar-39Ar dating of the H3 chondrite Sainte Rose     

Thomas Stephan  Elmar K. Jessberger 《Meteoritics & planetary science》1992,27(5):580-584

Abstract— A whole rock sample from the H3 chondrite Sainte Rose, which was discovered in 1983, was dated with the ⁴⁰Ar-³⁹Ar technique. From the K/Ca spectrum and from an analysis of the ³⁹Ar recoil effect we conclude that this meteorite has at least two distinguishable K-carriers: a low temperature, high-K/Ca, fine-grained carrier with a typical grain size of about 2 μm and a high temperature, low-K/Ca, more coarse-grained carrier. The K-Ar clocks of both were started 4.40 ± 0.01 Ga ago.  相似文献   

A comparison of theoreticalCIV emission line strengths with active region observations obtained with the Solar EUV Rocket Telescope and Spectrograph (SERTS)     

F. P. Keenan  R. J. Thomas  W. M. Neupert  E. S. Conlon  V. M. Burke 《Solar physics》1993,144(1):69-74

Theoretical line ratios involving 2s ² S - 3p ² P, 2p ² P - 3s ² S, and 2p ² S - 3d ² D transitions inCiv between 312 and 420 Å are presented. A comparison of these with solar active region observational data obtained during a rocket flight by the Solar EUV Rocket Telescope and Spectrograph (SERTS) reveals good agreement between theory and experiment, with discrepancies that average only 22%. This provides experimental support for the accuracy of the atomic data adopted in the line ratio calculations, and also resolves discrepancies found previously when the theoretical results were compared with solar data from the S082A instrument on boardSkylab. The potential usefulness of theCIV line ratios as electron temperature diagnostics for the solar transition region is briefly discussed.  相似文献   

EFFECT OF LIGHT INTENSITY ON THE TOTAL LIPID AND FATTY ACID COMPOSITION OF SIX STRAINS OF MARINE DIATOMS     

梁英麦康森  孙世春于道展 《中国海洋湖沼学报》2001,19(3):249-254

The effect of light intensity ( 1500 Ix and 5000 Ix) on the total lipid and fatty acid composition of six strains of marine diatoms Cylindrotheca fusiformis (B211 ), Phaeodactylum tricornutum (Bl14, Bl18 and B221) Nitzschia closterium (B222) and Chaetoceros gracilis (B13) was investigated.The total lipids of B13, Bl14, and B211 grown at 5000 Ix were lower than those grown at 1500 Ix. No evident changes were observed in Bl18, B221 and B222. Fatty acid composition changed considerably at different light intensity although no consistent correlation between the relative proportion of a single FA and light intensity. The major fatty acids of the 6 strains were 14:0, 16:0, 16:l(n- 7) and 20:5(n-3) . Cylindrothecafusiformis had high percentage of 20:4n - 6 (9.2 - 10.9% ) . The total polyunsaturated fatty acid /rl all 6 strains decreased with increasing light intensity. The percentage of the highly unsaturated fatty acid eicosapentaenoic acid (EPA) decreased with increasing light intensity in all strains except Chaetoceros gracilis.  相似文献