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1.
The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO2(g) and the resulting SO42−. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude. 相似文献
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Laurent Millet Boris Vannière Valérie Verneaux Michel Magny Jean Robert Disnar Fatima Laggoun-Défarge Anne Véronique Walter-Simonnet Gilles Bossuet Elena Ortu Jacques-Louis de Beaulieu 《Journal of Paleolimnology》2007,38(4):525-539
This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological,
environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages,
organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany,
Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the
chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional
climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main
lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical
of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids
through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development.
Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested
that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral
chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings
that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group
level, may be necessary to increase the sensibility of the indicators to lake-level changes. 相似文献
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Laurent Millet Charline Giguet-Covex Valérie Verneaux Jean-Claude Druart Thierry Adatte Fabien Arnaud 《Journal of Paleolimnology》2010,44(4):963-978
This paper presents the recent history of a large prealpine lake (Lake Bourget) using chironomids, diatoms and organic matter
analysis, and deals with the ability of paleolimnological approach to define an ecological reference state for the lake in
the sense of the European Framework Directive. The study at low resolution of subfossil chironomids in a 4-m-long core shows
the remarkable stability over the last 2.5 kyrs of the profundal community dominated by a Micropsectra-association until the beginning of the twentieth century, when oxyphilous taxa disappeared. Focusing on this key recent period,
a high resolution and multiproxy study of two short cores reveals a progressive evolution of the lake’s ecological state.
Until AD 1880, Lake Bourget showed low organic matter content in the deep sediments (TOC less than 1%) and a well-oxygenated
hypolimnion that allowed the development of a profundal oxyphilous chironomid fauna (Micropsectra-association). Diatom communities were characteristic of oligotrophic conditions. Around AD 1880, a slight increase in the
TOC was the first sign of changes in lake conditions. This was followed by a first limited decline in oligotrophic diatom
taxa and the disappearance of two oxyphilous chironomid taxa at the beginning of the twentieth century. The 1940s were a major
turning point in recent lake history. Diatom assemblages and accumulation of well preserved planktonic organic matter in the
sediment provide evidence of strong eutrophication. The absence of profundal chironomid communities reveals permanent hypolimnetic
anoxia. From AD 1995 to 2006, the diatom assemblages suggest a reduction in nutrients, and a return to mesotrophic conditions,
a result of improved wastewater management. However, no change in hypolimnion benthic conditions has been shown by either
the organic matter or the subfossil chironomid profundal community. Our results emphasize the relevance of the paleolimnological
approach for the assessment of reference conditions for modern lakes. Before AD 1900, the profundal Micropsectra-association and the Cyclotella dominated diatom community can be considered as the Lake Bourget reference community, which reflects the reference ecological
state of the lake. 相似文献
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Aidan S. R. Allan Daniel J. Morgan Colin J. N. Wilson Marc-Alban Millet 《Contributions to Mineralogy and Petrology》2013,166(1):143-164
The magmatic systems that give rise to voluminous crystal-poor rhyolite magma bodies can be considered to operate on two contrasting timescales: Those governed by longer-term processes by which a magma acquires its chemical and isotopic characteristics (e.g., fractional crystallisation and assimilation), and those operating at shorter timescales during the physical accumulation of the melt-dominant magma body that finally erupts. We explore the compositional and textural relationships between amphibole and orthopyroxene crystals from the 25.4 ka, 530 km3 (magma) Oruanui eruption products (Taupo volcano, New Zealand) to investigate how processes related to the physical assembly of the pre-eruptive magma body are represented in the crystal record. Over 90 % of orthopyroxenes from the volumetrically dominant high-SiO2 (>74 wt%) rhyolite pumices record textural evidence for a significant disequilibrium event (partial dissolution ± resorption of cores and interiors) prior to the growth of 40–500 μm thick rim zones. This dissolution/regrowth history of orthopyroxene is recorded in the chemistry of co-crystallising amphiboles as a prominent inflection in the concentrations of Mn and Zn, two elements notably enriched in orthopyroxene relative to amphibole. Textural and chemical features, linked with in situ thermobarometric estimates, indicate that a major decompression event preceded the formation of the melt-dominant body. The decompression event is inferred to represent the extraction of large volumes of melt plus crystals from the Oruanui crystal mush/source zone at pressures of 140–300 MPa (~6–12 km depth). Orthopyroxene underwent partial dissolution during ascent before reestablishing in the melt-dominant magma body at pressures of 90–140 MPa (~3.5–6 km). We model Fe–Mg diffusion across the core-rim boundaries along the crystallographic a or b-axes to constrain the timing of this decompression event, which marked establishment of the melt-dominant magma body. Maximum modelled ages indicate that this event did not begin until ~1,600 years before eruption, consistent with constraints from zircon model-age spectra. Once extraction began, it underwent runaway acceleration with a peak extraction age of ~230 years, followed by an apparent period of stasis of ~60 years prior to eruption. The rapidity of the extraction and accumulation processes implies the involvement of a dynamic driving force which, in the rifted continental arc setting of the Taupo Volcanic Zone, seems likely to be represented by magma-assisted extensional tectonic processes. 相似文献
6.
In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Anne-Lise Mariet Fabrice Monna Frédéric Gimbert Carole Bégeot Christophe Cloquet Simon Belle Laurent Millet Damien Rius Anne-Véronique Walter-Simonnet 《Journal of Paleolimnology》2018,60(3):399-412
A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline. 相似文献
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Charline Giguet-Covex Fabien Arnaud Jérôme Poulenard Dirk Enters Jean-Louis Reyss Laurent Millet Jérome Lazzaroto Olivier Vidal 《Journal of Paleolimnology》2010,43(1):171-190
Sedimentological, geochemical and particle-size analyses were used to reconstruct the evolution of both trophic state and
hypolimnetic anoxia in Lake Bourget (French Alps) during the last century. Radionuclide dating (210Pb, 137Cs and 241Am) confirmed the annual rhythm of laminations in the upper sediment profile. In Lake Bourget, biochemical varves are triplets
composed of a diatom layer (spring lamina), a bio-precipitated calcite-rich layer (spring/summer lamina), and a layer rich
in organic matter and detrital particles (winter lamina). The onset of eutrophication and the first appearance of an anoxic
facies occurred simultaneously and were dated by laminae counting to AD 1943±1 year. Persistent anoxic conditions began in
AD 1960. Eutrophication is characterised by drastic increases in the flux of biogenic silica (mostly diatoms), lacustrine
organic matter, and larger calcite crystals (15–30 μm). The increase of organic matter also represents a marker of the onset
of anoxic conditions in the hypolimnion. Our results show that eutrophication was the main factor controlling anoxia in the
hypolimnion. This eutrophication was caused mostly by the inflow of untreated sewage effluents, and to a lesser extent, by
input of fertilizer-derived phosphorus during floods of the Rhone River and run-off from the lake catchment. The Rhone River,
however, can also be a source of re-oxygenation via underflows that originate during flood events. Oxygenation of the hypolimnion
is also controlled by low winter temperatures, which enable turnover of the lake. Thus, global warming, associated with a
forecasted reduction in precipitation, might reduce the efficiency of hypolimnetic re-oxygenation in Lake Bourget. 相似文献
9.
M. S. Korchinski J. Vry T. A. Little M.‐A. Millet R. Bicknell E. Smith A. von der Handt 《Journal of Metamorphic Geology》2014,32(9):1019-1039
The youngest known ultrahigh‐pressure (UHP) rocks in the world occur in the Woodlark Rift of southeastern Papua New Guinea. Since their crystallization in the Late Miocene to Early Pliocene, these eclogite facies rocks have been rapidly exhumed from mantle depths to the surface and today they remain in the still‐active geodynamic setting that caused this exhumation. For this reason, the rocks provide an excellent opportunity to study rates and processes of (U)HP exhumation. We present New Rb–Sr results from 12 rock samples from eclogite‐bearing gneiss domes in the D'Entrecasteaux Islands, and use those results to examine the time lag between (U)HP metamorphism and later ductile thinning, penetrative fabric development and accompanying metamorphic retrogression at amphibolite facies conditions during their exhumation. A Rb–Sr age for a sample of mafic eclogite (with no preserved coesite) from the core zone of the Mailolo gneiss dome (Fergusson Island) provides a new estimate of the timing of HP metamorphism (5.6 ± 1.6 Ma). The strongly deformed quartzofeldspathic and granitic gneisses (90–95% by volume) that enclose variably retrogressed relict blocks of mafic eclogite (5–10% by volume) yield Rb–Sr isochron ages from 4.4 to 2.4 Ma. For the UHP‐bearing gneisses of Mailolo dome, previously published U–Pb ages on zircon and our Rb–Sr isochron ages are consistent with a mean time lag of 2.2 ± 1.5 Ma (~95% c.i.) for passage of the rock between eclogite and amphibolite facies conditions. New thermobarometric data indicate that the main syn‐exhumational foliation developed at amphibolite facies conditions of 630–665 °C and 12.1–14.4 kbar. These pressure estimates indicate that the lower crust of the Woodlark Rift was unusually thick (>40 km) at the time of the amphibolite facies overprint, possibly as a result of accumulation and underplating of UHP‐derived material from below. Our data imply a minimum unroofing rate of 10 ± 7 mm year?1 (~95% c.i.) for the (U)HP body from minimum HP depths (73 ± 7 km) to lower crustal depths. This minimum unroofing rate reinforces previous inferences that the exhumation from the mantle to the surface of the gneiss domes in the D'Entrecasteaux Islands took place at plate tectonic rates. On the basis of previous structural studies and the new thermobarometry, we attribute the high (cm year?1) exhumation to diapiric ascent of the partially molten terrane from mantle depths, with a secondary contribution from pure shear thinning of the terrane after its arrival in the crust. 相似文献
10.
This second part of the work deals firstly with carrying out materials characterization, mainly mercury intrusion porosimetry and chloride electrodiffusion tests on two cement pastes. Experimental data allowed fixing the perturbation parameter ? and other dimensionless numbers highlighted in part I of this work. Secondly, a series of parametric simulations were performed in order to compute the chloride diffusion coefficient through a gradual complexity of the elementary cell, approaching as close as possible the real microstructure of the cement pastes tested. Results highlighted that taking into account microstructure parameters (porosity, tortuosity and constrictivity) allows to approach the experimental diffusion coefficient. However, they also showed that electrochemical interactions between ions and the liquid‐solid interface, and the multi‐scale character of cementitious material microstructure, must be considered. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献