Re-equilibration of detrital muscovite and the formation of interleaved phyllosilicate grains in low temperature metamorphism,northern Apennines,Italy     

Marcello Franceschelli  Isabella Memmi  Giovanni Gianelli 《Contributions to Mineralogy and Petrology》1991,109(2):151-158

Low temperature metamorphosed clastic rocks of northern Apennines (Verrucano) contain detrital and metamorphic muscovite along with aggregates of interleaved phyllosilicate grains. The extent of celadonite substitution in the metamorphic muscovite progressively increases from Al-rich pyrophyllite-bearing samples to Al-poor K-feldspar-bearing samples and appears to be compatible with the phase relation in the AKF and AKNa diagrams. Some detrital muscovite grains, not equilibrated with the present metamorphic mineral assemblages, seem to be unreacted grains retaining their premetamorphic composition. The chemistry of the re-equilibrated detrital muscovite is mainly controlled by the activity of Al₂O₃ that is implied by mineral assemblages in the host rocks and is independent of the original composition of detrital mica. Four types of phyllosilicate associations in the interleaved phyllosilicate grains were recognized: 1) muscovite- pyrophyllite-sudoite; 2) muscovite-pyrophyllite-chlorite; 3) muscovite-paragonite-chlorite; 4) muscovite-chlorite. A microstructural and petrological model is proposed for the origin of interleaved phyllosilicate grains in the Verrucano rocks. The model supports the idea that the interleaved phyllosilicate grains are the result of the trend towards equilibrium between detrital muscovite, metamorphic mineral assemblages and the fluid phase.  相似文献   

Local remineralization patterns in the mesopelagic zone of the Eastern North Atlantic, off the NW Iberian Peninsula     

C.G. Castro  M. Nieto-Cid  X.A. lvarez-Salgado  F.F. Prez 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1925-1940

The short-time-scale variability of the remineralization patterns in the domain of Eastern North Atlantic Central Waters (ENACW) off the NW Iberian Peninsula is studied based on biogeochemical data (oxygen, nutrient salts, total alkalinity, pH, dissolved organic matter and fluorescence of dissolved humic substances) collected weekly between May 2001 and April 2002. The temporal variability of inorganic variables points to an intensification of remineralization during the summer and autumn, with an increase of nutrients, total inorganic carbon and fluorescence and a decrease of oxygen. During the subsequent winter mixing, there is a biogeochemical reset of the system, with lower nutrients, total inorganic carbon and fluorescence and higher oxygen. In contrast to inorganic variables, the levels of dissolved organic matter in the ENACW seem to respond to short-term events probably associated with fast sinking particles, where solubilisation of organic matter prevails over remineralization. Applying a previously published stoichiometric model, we observed a vertical fractionation of organic-matter remineralization. Although there is a preferential remineralization of proteins and P compounds in the entire domain of ENACW, the percentage was higher in the upper ENACW (σ<27.10 kg/m³) than in the lower; the percentage of N and P compounds in the oxidised organic matter was >80% for the upper ENACW and 63% for the lower. Likewise, the redissolution of calcareous structures contributes about 6% and 13% to the carbon regenerated in the upper and lower layers of ENACW, respectively.  相似文献   

Nutrient variability during El Niño 1997–98 in the California current system off central California     

C. G. Castro  C. A. Collins  P. Walz  J. T. Pennington  R. P. Michisaki  G. Friederich  F. P. Chavez   《Progress in Oceanography》2002,54(1-4)

Nutrient conditions off central California during the 1997–98 El Niño are described. Data were collected on 11 cruises from March 1997 to January 1999 along a hydrographic section off central California, as well as every two weeks at a coastal station in Monterey Bay. Perturbations associated with El Niño are shown as anomalies of thermohaline and nutrient distributions along this section. The anomalies were obtained by subtracting seasonal averages for the period from April 1988 to April 1991 from the 1997–98 observations. The first indications of El Niño conditions (high sea levels) were observed at Monterey between late May and early June 1997, but the coastal nutricline did not begin to deepen until August 1997. It reached maximum depth of 130 dbar in January 1998 at the time that maximum sea level anomalies were observed. During this period: (1) the highest subsurface temperature anomalies coincided with subsurface nutrient anomaly minima at the depth of the pycnocline; (2) southern saline and nutrient-poor waters occupied the upper 80 dbar of the water column along the entire section; and (3) nitrate levels were close to zero in the euphotic zone, collapsing the potential new primary production in the coastal domain. At the end of February 1998, the nutricline shoaled to 40 dbar at the coast although it remained anomalously deep offshore. Higher temperatures and lower nutrient levels were observed for the entire section through August 1998 although in contrast with the previous winter, there was a strong freshening mainly due to an onshore movement of subarctic waters.  相似文献   

The distribution of chlorophyll-a and dominant planktonic components in the coastal transition zone off Concepción, central Chile, during different oceanographic conditions     

Carmen E. Morales  Humberto E. González  Gabriel Yuras  Leonardo R. Castro 《Progress in Oceanography》2007,75(3):452-469

The oceanographic setting and the planktonic distribution in the coastal transition zone off Concepción (∼35-38°S, ∼73-77°W), an area characterized by its high biological production, were assessed during two different seasons: austral spring with equatorward upwelling favorable winds and austral winter with predominately northerly winds. Oceanographic and biological data (total chlorophyll-a, particulate organic carbon, microplankton, large mesozooplankton >500 μm as potential consumers of microplankton) were obtained during two cruises (October 1998, July 1999) together with satellite imagery for wind stress, geostrophic flow, surface temperature, and chlorophyll-a data. The physical environment during the spring sampling was typical of the upwelling period in this region, with a well-defined density front in the shelf-break area and high concentrations of surface chlorophyll-a (>5 mg m⁻³) on the shelf over the Itata terrace. During the winter sampling, highly variable though weakly upwelling-favorable winds were observed along with lower surface chlorophyll-a values (<2 mg m⁻³) on the shelf. In the oceanic area (>100 km from the coast), cyclonic and anti-cyclonic eddies were evident in the flow field during both periods, the former coinciding with higher chlorophyll-a contents (∼1 mg m⁻³) than in the surrounding waters. Also, a cold, chlorophyll-a rich filament was well defined during the spring sampling, extending from the shelf out to 350-400 km offshore. Along a cross-shelf transect, the micro- and meso-planktonic assemblages displayed higher coastal abundances during the spring cruise but secondary peaks appeared in the oceanic area during the winter cruise, coinciding with the distribution of the eddies. These results suggest that the mesoscale features in this region, in combination with upwelling, play a role in potentially increasing the biological productivity of the coastal transition zone off Concepción.  相似文献   

Changes in the hydrography of Central California waters associated with the 1997–98 El Niño     

C. A. Collins  C. G. Castro  H. Asanuma  T. A. Rago  S. -K. Han  R. Durazo  F. P. Chavez 《Progress in Oceanography》2002,54(1-4)

Oceanographic conditions off Central California were monitored by means of a series of 13 hydrographic cruises between February 1997 and January 1999, which measured water properties along an oceanographic section perpendicular to the California Coast. The 1997–98 El Niño event was defined by higher than normal sea levels at Monterey, which began in June 1997, peaked in November 1997, and returned to normal in March 1998. The warming took place in two distinct periods. During June and July 1997, the sea level increased as a result of stronger than normal coastal warming below 200 dbars and within 100 km of the coast, which was associated with poleward flow of saltier waters. During this period, deeper (400–1000 dbar) waters between 150–200 km from shore were also warmed and became more saline. Subsequently, sea level continued to rise through January 1998, mostly as a result of the warming above 200 dbars although, after a brief period of cooling in September 1997, waters below 200 dbar were also warmer than normal during this period. This winter warm anomaly was also coastally trapped, extending 200 km from shore and was accompanied by cooler and fresher water in the offshore California current. In March and April 1998, sea level dropped quickly to normal levels and inshore waters were fresher and warmer than the previous spring and flowed southward.The warming was consistent with equatorial forcing of Central California waters via propagation of Kelvin or coastally-trapped waves. The observed change in heat content associated with the 1997–98 El Niño was the same as that observed during the previous seasonal cycle. The warming and freshening events were similar to events observed during the 1957–58 and 1982–83 El Niños.  相似文献   

Equilibrium constants of triethanolamine in major seawater salts     

I. Brandariz  P. Castro  M. Montes  F. Penedo  M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.  相似文献   

Measuring lysosomal stability as an effective tool for marine coastal environmental monitoring     

Castro M  Santos MM  Monteiro NM  Vieira N 《Marine environmental research》2004,58(2-5):741-745

The use of lysosomal stability in the mussel, Mytilus galloprovincialis, as a potential biomarker of environmental contamination has been evaluated along the Portuguese coast. To this end, the neutral red retention (NRR) time was measured in mussel haemocytes gathered from nine different locations reflecting different degrees of anthropogenic contamination. Mussels collected in the vicinity of industrial and urban areas showed the lowest lysosomal stability. Additionally, no significant seasonal variability (winter-spring/summer) for NRR time was observed. In order to further support the usefulness of this method as an integrated tool for monitoring marine coastal environments, we compared the levels of xenobiotics in mussel tissues with the obtained NRR values. The results highlighted a consistent pattern, with the lowest lysosomal stability intimately correlated with the higher contaminant concentrations. In summary, this integrated approach further demonstrated that the NRR assay can provide useful and objective indications of the real health status of organisms subjected to different stress agents, being a valid option for environmental monitoring.  相似文献   

Carbon cycling through the pelagic foodweb in the northern Humboldt Current off Chile (23{degrees}S)     

Gonzalez  H.E.; Giesecke  R.; Vargas  C.A.; Pavez  M.; Iriarte  J.; Santibanez  P.; Castro  L.; Escribano  R.; Pages  F. 《ICES Journal of Marine Science》2004,61(4):572-584

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Reconstruction of total annual rainfall in Andalusia (Southern Spain) during the 16th and 17th centuries from documentary sources     

F. S. Rodrigo  M. J. Esteban Parra  Y. Castro Diez 《Theoretical and Applied Climatology》1995,52(3-4):207-218

Summary This study describes a reconstruction of rainfall characteristics in Southern Spain from 1501 to 1700 AD, during the beginning of the period called the Little Ice Age. Weather information was taken from original documentary sources (urban annals, local and religious histories, municipal documents, relations, etc.) in the region. A numerical index was established to characterize the rainfall, its characteristics, evolution and geographical distribution. Results were characteristics compared with modern precipitation data and with the results of other studies of historical climate. The general conclusion is that rainfall in Western Andalusia increased from approximately 1550 to 1650 AD. Some perspectives for future research work are outlined.With 6 Figures  相似文献   

Light curves of SZ Piscium for 1977 and 1978     

Joel A. Eaton  Franco Scaltriti  M. Cerruti-Sola  M. B. K. Sarma  B. D. Ausekar  Santo Catalano  Marcello Rodono 《Astrophysics and Space Science》1982,82(2):289-306

We present a relatively completeV-band light curve of SZ Psc for 1978 and a partial light curve for 1977. From the 1978 light curve we derive a new time of primary minimum, JD2443823.674±0.001, and a Russell-model solution,i=75°.8±0°.1,r _h =0.096±0.003,r _c =0.351±0.001, andL _h =0.253±0.002. The hotter component of this system is a F5-8 main-sequence star, the cooler component a K3-4 star well above the main sequence. The system is detached with the larger component filling only 82% of its Roche lobe. The distortion wave in this RS CVn-type binary seems not to migrate regularly as do those in many other such systems, but rather seems to change phase and amplitude more erratically. Between 1977 and 1978 its phase stayed practically constant while its amplitude decreased by a factor of three. We discuss the implications of this behavior for the spot model of RS CVn-type activity. We find that the traditional comparison star for SZ Psc, HD 219018, is very likely a constant star contrary to a recent suggestion that it is variable. Its brightness and colors,V=7.705, (B-V)=0.628, and (V-I) _c =0.688, are those of a G2V star.Visiting Astronomer, Kitt Peak National Observatory, which is operated by AURA, Inc., under contract with the National Science Foundation, and Visiting Astronomer, Prarie Observatory, University of Illinois.  相似文献