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The stability constants K1 and K12 of phosphoric acid were determined for artificial seawater of six different salinities (5, 10, 20, 30, 35, 40‰) and in 0.2, 0.4 and 0.7 M NaCl at three temperatures (5, 15, 25°C). The results are compared with those of Kester and Pytkowicz (1967), Atlas et al. (1976) and Dickson and Riley (1979). The ionic product of water, Kw, was determined in sodium chloride media at 5, 15 and 25°C. Complex formation among Ca2+, Mg2+, HPO42? and PO43? is discussed. 相似文献
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High resolution electric field and particle data, obtained by the S23L1 rocket crossing over a discrete prebreakup arc in January 1979, are studied in coordination with ground observations (Scandinavian Magnetometer Array—SMA, TV and all-sky cameras) in order to clarify the electrodynamics of the arc and its surroundings. Height-integrated conductivities have been calculated from the particle data, including the ionization effects of precipitating protons and assuming a steady state balance between ion production and recombination losses. High resolution optical information of arc location relative to the rocket permitted a check of the validity of this assumption for each flux tube passed by the rocket. Another check was provided by a comparison between calculated (equilibrium values) and observed electron densities along the rocket trajectory. A way to compensate for the finite precipitation time when calculating the electron densities is outlined. The height-integrated HalI-Pedersen conductivity ratio is typically 1.4 within the arc and about 1 at the arc edges, indicative of a relatively softer energy spectrum there. The height-integrated conductivities combined with the DC electric field measurements permitted calculation of the horizontal ionospheric current vectors (J⊥), Birkeland currents (from div J⊥) and energy dissipation through Joule heating (ΣpE2). An eastward current of typically 1 A m?1 was found to be concentrated mainly to the arc region and equatorward of it. A comparison has been made with the equivalent current system deduced from ground based magnetometer data (SMA) showing a generally good agreement with the rocket results. An intense Pedersen current peak (1.2 A m?1) was found at the southern arc edge. This edge constituted a division line between a very intense (> 10 μA m?1) and localized (~ 6 km) downward current sheet to the south, probably carried by upward flowing cold ionospheric electrons and a more extended upward current sheet (> 10 μA m?2) over the arc carried by measured precipitating electrons. Joule and particle heating across the arc were anticorrelated, consistent with the findings of Evans et al. (1977) with a total value of about 100mW m?2. 相似文献
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The formation of the ion pairs MgSO4 and NaSO4? was investigated calorimetrically at 0.75 M ionic strength, 25°C, 1 atm. Simultaneous determinations of enthalpy changes, ΔH10, and stability constants, K1, were not possible, and values of K1 determined independently had to be introduced for the calculation of ΔH10. The values of ΔH10 obtained were 1–3 kJ mol?1 for MgSO4 and 0 kJ mol?1 for NaSO4?. 相似文献
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In order to investigate the photobleaching potential of estuarine waters from different depths and redox conditions and with varying degree of biological activity, filtered, unfiltered and chloroform-poisoned water samples from the Baltic Sea were exposed to ambient sunlight. Fluorescence, at excitation 350 nm and emission 450 nm, was used as an indication of humic substance concentration. Fluorescence and organic carbon concentration were measured at regular time intervals during light exposure. We found that the decrease in humic substance fluorescence can be fitted to an exponential decay function. The fluorescence half-lives were within the range 0.4 – 4.6 days in different water masses, with fluorescence decreasing to between 20% and 60% of initial concentration, respectively. Results from the curve fitting procedure indicate a rest concentration of humic substance fluorescence, similar among the sampled sites, that is resistant to further photochemical degradation. The largest relative decreases in fluorescence were found in deep waters, but samples from deep waters also had a higher fluorescence rest concentration than samples from surface waters. Biological activity was reduced by filtering the samples through 0.2μm pore size filters or adding chloroform. No statistically significant differences were found after 3 days of irradiation between samples with and without treatment to reduce biological activity. The highest initial fluorescence values and the largest fluorescence decrease were found in the anoxic waters of the Gotland Deep. The organic carbon concentrations decreased 3–7% at all stations. The shortest half-life of humic substance, and the largest decrease in organic carbon concentrations, were found in samples from the northern basins of the Baltic Sea. 相似文献
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The stability of the ion pair CaSO4 was determined from measurement of the change in calcium ion activity with medium composition at constant ionic strength. A calcium selective PVC-matrix liquid membrane electrode was used to monitor the calcium ion activity. All measurements were performed at 1 atm, 25 ± 0.1°C and 0.7 M formal ionic strength. The evaluation of the stability constant depends on the degree of complexation between calcium and chloride and between sodium and sulphate. The dependence of KCaSO4, on KNaSO4 and KCaCl can be described by the following relations:KCaSO4=17.7 KCaCl+16.5 (KNaSO4=1.8)KCaSO4=18.8 KCaCl+17.3 (KNaSO4=2) for KCaCl=0–1A value of KCaSO4=25.4 is suggested. 相似文献
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Barbara Delmonte Carlo Baroni Per S. Andersson Hans Schoberg Margareta Hansson Sarah Aciego Jean‐Robert Petit Samuel Albani Claudia Mazzola Valter Maggi Massimo Frezzotti 《第四纪科学杂志》2010,25(8):1327-1337
A new ice core (TALDICE) drilled at Talos Dome (East Antarctica, Ross Sea sector) preserves a ca. 250 ka long record of palaeoclimate and atmospheric history. We investigate dust variability and provenance at the site during glacial periods and the Holocene through the Sr–Nd isotopic composition of ice core dust and potential source areas (PSA). We provide new isotopic data on dust sources from Victoria Land such as regoliths, glacial drifts, aeolian sands and beach deposits. Some of these sources are located at high altitude and are known to have been ice free throughout the Pleistocene. The major features of the TALDICE dust record are very similar to those from central East Antarctica. During glacial times, South America was the dominant dust supplier for Talos Dome as well as for the entire East Antarctic plateau. Conversely, during the Holocene the principal input of mineral dust at Talos Dome probably derives from proximal sources which are the ice‐free areas of northern Victoria Land, located at similar altitude with respect to the drilling site. Atmospheric mobilisation of dust from these neighbouring areas and transport inland to Talos Dome can be ultimately associated with advection of maritime air masses from the Pacific/Ross Sea region. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Future vegetation changes in thawing subarctic mires and implications for greenhouse gas exchange—a regional assessment 总被引：1，自引：1，他引：0
Julia Bosi? Margareta Johansson Terry V. Callaghan Bernt Johansen Torben R. Christensen 《Climatic change》2012,115(2):379-398
One of the major concerns regarding climate change in high latitudes is the potential feedback from greenhouse gases (GHG) being released from thawing peat soils. In this paper we show how vegetational patterns and associated GHG fluxes in subarctic palsa (peat mounds with a permanently frozen core) mires can be linked to climate, based on field observations from fifteen palsa sites distributed in northern Fennoscandia. Fine resolution (100?m) land cover data are combined with projections of future climate for the 21st century in order to model the potential future distribution of palsa vegetation in northern Fennoscandia. Site scale climate-vegetational relationships for two vegetation types are described by a climate suitability index computed from the field observations. Our results indicate drastic changes in the palsa vegetational patterns over the coming decades with a 97?% reduction in dry hummock areas by 2041?C2060 compared to the 1961?C1990 areal coverage. The impact of these changes on the carbon balance is a decrease in the efflux of CO2 from 130 kilotonnes C y?1 to a net uptake of 11 kilotonnes C y?1 and a threefold increase in the efflux of CH4 from 6 to 18 kilotonnes C y?1 over the same period and over the 5,520?km2 area of palsa mires. The combined effect is equivalent to a slight decrease in CO2-C emissions, from 182 to 152 kilotonnes C y?1. Main uncertainties involve the ability of the vegetation community to adapt to new conditions, and long-term changes in hydrology due to absence of ice and frost heaving. 相似文献
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The dependence of the total carbonate concentration of ocean water on temperature and atmospheric partial pressure of carbon dioxide is calculated. The results show that the increase in total carbonate caused by the increase of carbon dioxide in the atmosphere is ca. 25–50 times larger than the precision in the experimental determination of Ct. 相似文献
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I. Sandahl S. Barabash H. Borg E. Yu. Budnik E. M. Dubinin U. Eklund H. Johansson H. Koskinen K. Lundin R. Lundin A. Mostrom R. Pellinen N. F. Pissarenko T. Pulkkinen P. Toivanen A. V. Zakharov 《Annales Geophysicae》1997,15(5):542-552
PROMICS-3 is a plasma experiment flown in the Russian project Interball. It performs three-dimensional (3D) measurements of ions in the energy range 4 eV–70 keV with mass separation and of electrons in the energy range 12 eV–35 keV. The Interball project consists of two main satellites, the Tail Probe and the Auroral Probe, each with one subsatellite. The Interball Tail Probe was launched on 3 August 1995, into a 65° inclination orbit with apogee at about 30 RE. Both main satellites carry identical PROMICS-3 instruments and thus direct comparisons of the particle distributions will be possible once the Auroral Probe is launched. Furthermore, PROMICS-3-Tail is the first instrument measuring the 3D ion distribution function in the magnetospheric boundary layers at high latitudes. In this paper we describe the PROMICS-3 instrument and show initial results from the Tail probe, measurements of the mag-netosheath, plasma sheet, and ring current plasmas. 相似文献