Th sorption and export models in the water column: A review   总被引：2，自引：3，他引：2  

Nicolas Savoye  Claudia Benitez-Nelson  Adrian B. Burd  J. Kirk Cochran  Matthew Charette  Ken O. Buesseler  George A. Jackson  Matthieu Roy-Barman  Sabine Schmidt  Marc Elskens 《Marine Chemistry》2006,100(3-4):234

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.  相似文献   

Re-Os Isotopic Measurements at the Femtomole Level in Natural Samples   总被引：17，自引：0，他引：17  

Jean Louis Birck  Matthieu Roy Barman  Françoise Capmas 《Geostandards and Geoanalytical Research》1997,21(1):19-27

Here we describe a new chemical separation method for Os and an improved mass spectrometric procedure for Re and Os. This technique is based on the selective extraction of OsO₄ from aqueous solution in liquid bromine. Among other advantages, this procedure avoids the cumbersome distillation procedure for Os and uses only commercial "off the shelf" PFA teflon labware. Blank levels for 0.5 g sample sizes are: 0.06 pg and 0.5 pg for Os and Re respectively. Samples containing as little as 1 pg g⁻¹ Os can be analysed reliably with this method. Adaptation to other dissolution methods is also discussed.  相似文献   

Nouvelles données pour l’histoire des fluctuations holocènes du niveau du lac de Neuchatel (Suisse): la séquence sédimentaire de Marin-Les Piécettes     

Michel Magny  Matthieu Honegger et Laurent Chalumeau 《Eclogae Geologicae Helvetiae》2005,98(2):249-259

Resume. Les fouilles archéologiques réalisées de 1998 à 2002 sur le site néolithique de Marin-Les Piécettes sur la rive nord-ouest du lac de Neuchatel ont offert l’opportunité d’observer deux séquences sédimentaires intéressantes pour la reconstitution des variations holocènes du niveau du lac, en particulier au cours de la période correspondant au changement de cours de l’Aar en direction du nord-est, vers 5650–5500 cal BP. La géométrie des corps sédimentaires et les changements lithologiques permettent de reconna?tre plusieurs phases majeures de bas niveaux relatifs du plan d’eau vers 6870, 5660, 5060–3990, 3580, 2280, 1640 et 1170 cal BP. Le site néolithique de Marin-Les Piécettes s’est développé vers 5454–5433 cal BP à la faveur d’un court épisode de bas niveau du lac qui a interrompu une importante phase de haut niveau au début du Subboréal. Les événements paléohydrologiques identifiés à Marin-Les Piécettes apparaissent cohérents avec ceux reconstitués sur le site de Montilier au bord du lac de Morat, ainsi qu’avec les variations paléohydrologiques reconstituées à partir des lacs du Jura, du Plateau suisse et des Préalpes du Nord fran?aises. Ceci suggère qu’ils témoignent d’un signal climatique. La séquence sédimentaire de Marin-Les Piécettes met enfin en évidence la formation d’un cordon littoral sur la rive nord-ouest du lac juste après 5660 cal BP. Manuscrit re?u le 22 septembre 2004 Révision acceptée le 11 mars 2005  相似文献   

Hydrogen isotopic composition of water from fossil micrometeorites in howardites     

Matthieu Gounelle  Cécile Engrand  Philip A. Bland  Michael E. Zolensky  Jean Duprat 《Geochimica et cosmochimica acta》2005,69(13):3431-3443

We have measured the hydrogen isotopic composition (D/H ratios) of the water from 13 carbonaceous chondritic microclasts (CCMs, size <1 mm) trapped in two howardites (Kapoeta and Yamato-793497) early in the evolution of Solar System. The division into tochilinite-rich; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich CCM types is corroborated by the hydrogen isotopic compositions. Both mineralogy and hydrogen isotopic compositions demonstrate that tochilinite-rich CCMs represent CM2 chondritic matter. In contrast, there is no good match between the isotopic and mineralogical properties of the magnetite-rich CCMs and the known groups of carbonaceous chondrites, suggesting that magnetite-rich CCMs represent a new kind of chondritic matter, not yet sampled in meteorite collections. This demonstrates that the view of the asteroid belt revealed by the collection of meteorites is incomplete. The study of (micro)clasts offers a unique opportunity to better decipher the nature and relative abundance of asteroids.The average hydrogen isotopic composition of water belonging to CCMs, D/H = (152.0 ± 4.8) × 10⁻⁶ (1σ_m), is similar to that of Antarctic micrometeorites (AMMs), D/H = (161.2 ± 3.8) × 10⁻⁶ (1σ_m). The similarity, in terms of mineralogy and hydrogen isotopic composition, between CCMs and AMMs demonstrates that the composition of the micrometeorites has not been modified over the whole history of the Solar System. It indicates that the composition of the micrometeorite flux onto Earth has been, and is, dominated by a mixture of CM2-like; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich carbonaceous chondritic matter exemplified by CCMs found in howardites. Because CCMs have not suffered atmospheric entry, they provide an abundant source of pristine micrometeorites.The average D/H ratio of the whole population of CCMs is identical within errors to that of the Earth (149 ± 3 × 10⁻⁶). The match between the CCMs D/H ratio and that of the Earth is especially remarkable because 1) three different populations of CCMs are needed to make the D/H ratio of the Earth; 2) there is no single carbonaceous chondrite group for which a similar match exists. This observation suggests that CCMs population might be representative of the late veneer agent(s) that delivered water to the Earth.  相似文献   

Environmental changes over the past 25 000 years in the southern Middle Atlas,Morocco          下载免费PDF全文

Jalal Tabel  Carla Khater  Ali Rhoujjati  Laurent Dezileau  Ilham Bouimetarhan  Matthieu Carre  Laurence Vidal  Abdelfattah Benkaddour  Majda Nourelbait  Rachid Cheddadi 《第四纪科学杂志》2016,31(2):93-102

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Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials     

Hervé di Benedetto  Matthieu Blanc  Samir Tiouajni  Alan Ezaoui 《国际地质力学数值与分析法杂志》2014,38(14):1477-1502

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

A New Generation Earth Mantle Model from Global Adjoint Tomography     

Youyi Ruan  Wenjie Lei  Matthieu Lefebvre  Ryan Modrak  James Smith  Ridvan Orsvuran  Ebru Bozdag  Judith Hill  Norbert Podhorszki  Dave Pugmire  Jeroen Tromp 《《地质学报》英文版》2018,92(Z1):140-140

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Morphological and sedimentary impacts and recovery on a mixed sandy to pebbly seabed exposed to marine aggregate extraction (Eastern English Channel,France)     

Sophie Le Bot  Robert Lafite  Matthieu Fournier  Agnès Baltzer  Michel Desprez 《Estuarine, Coastal and Shelf Science》2010

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Crystal size distribution (CSD) in rocks and the kinetics and dynamics of crystallization     

Katharine V. Cashman  John M. Ferry 《Contributions to Mineralogy and Petrology》1988,99(4):401-415

Crystal size distributions (CSDs) measured in metamorphic rocks yield quantitative information about crystal nucleation and growth rates, growth times, and the degree of overstepping (T) of reactions during metamorphism. CSDs are described through use of a population density function n=dN/dL, where N is the cumulative number of crystals per unit volume and L is a linear crystal size. Plots of ln (n) vs. L for olivine+pyroxene and magnetite in high-temperature (1000° C) basalt hornfelses from the Isle of Skye define linear arrays, indicating continuous nucleation and growth of crystals during metamorphism. Using the slope and intercept of these linear plots in conjunction with growth rate estimates we infer minimum mineral growth times of less than 100 years at T<10° C, and nucleation rates between 10^–4 and 10^–1/cm³/s. Garnet and magnetite in regionally metamorphosed pelitic schists from south-central Maine have CSDs which are bell-shaped. We interpret this form to be the result of two processes: 1) initial continuous nucleation and growth of crystals, and 2) later loss of small crystals due to annealing. The large crystals in regional metamorphic rocks retain the original size frequency distribution and may be used to obtain quantitative information on the original conditions of crystal nucleation and growth. The extent of annealing increases with increasing metamorphic grade and could be used to estimate the duration of annealing conditions if the value of a rate constant were known. Finally, the different forms of crystal size distributions directly reflect differences in the thermal histories of regional vs. contact metamorphosed rocks: because contact metamorphism involves high temperatures for short durations, resulting CSDs are linear and unaffected by annealing, similar to those produced by crystallization from a melt; because regional metamorphism involves prolonged cooling from high temperatures, primary linear CSDs are later modified by annealing to bell shapes.  相似文献   

Contact metamorphism of roof pendants at Hope Valley,Alpine County,California, USA     

John M. Ferry 《Contributions to Mineralogy and Petrology》1989,101(4):402-417

Calcareous hornfelses and marbles all contain calcite+K-feldspar+quartz+sphene±diopside±plagioclase ±scapolite±clinozoisite. In addition, rocks on one side of a fault contain combinations of biotite, amphibole, and muscovite while those on the other side contain combinations of grossular, wollastonite, and axinite. At bars, mineral-fluid equilibria in biotite and amphibole-bearing rocks record T= 440° C and garnet-bearing rocks record T=540° C and Conventional volumetric fluid-rock ratios were calculated using measured progress of prograde decarbonation reactions and the conditions of metamorphism: marbles, 0–0.4; amphibole-bearing hornfelses, 1.0–1.4; garnet-bearing hornfelses, 2.8–6.7. Decarbonation reactions were driven by pervasive infiltration of rock by reactive aqueous fluids. Differences in fluid-rock ratio between interbedded marble and hornfels and lack of correlation between fluid-rock ratio and whole-rock Cl-content, however, argue for channelized fluid flow along lithologic layers. A new analysis of reaction progress allows estimation of time-integrated fluxes for a specified temperature gradient along the direction of flow. Results are: marbles, 0–0.1×10⁵ cm³/cm²; amphibole-bearing hornfelses, 0.8–1.3×10⁵ cm³/cm²; garnet-bearing hornfelses, 1.2–2.5 × 10⁵ cm³/cm². Fluid flowed from regions of low to regions of high temperature. Using a simple thermal model for the area, the duration of contact metamorphism was estimated as 10⁵ years. Assuming the time of fluid flow was the same as the duration of the thermal event, the first measurements of average metamorphic fluxes (q) and permeabilities (k) are: average marbles, q=0–0.3×10^–8 cm/s and k =2×10^–6 darcy; hornfels, q=3–8×10^–8 cm/s and k =20–53×10^–6 darcy. Estimated premeabilities are within the range of values measured for metamorphic rocks in the laboratory. Fluxes, permeabilities, and whole-system fluidrock ratios are similar to those estimated for the Skaergaard hydrothermal system by Norton and Taylor (1979).  相似文献