Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

A crack model of afterslip events on shallow faults     

Maria Elina Belardinelli  Maurizio Bonafede 《Geophysical Journal International》1991,106(3):521-530

  相似文献   

Transforming observational data and theoretical isochrones into the ACS/WFC Vega-mag system     

Luigi R. Bedin †  Santi Cassisi  Fiorella Castelli  Giampaolo Piotto  Jay Anderson  Maurizio Salaris  Yazan Momany  Adriano Pietrinferni 《Monthly notices of the Royal Astronomical Society》2005,357(3):1038-1048

We propose a zero-point photometric calibration of the data from the Advanced Camera for Surveys (ACS) Wide Field Channel (WFC) on board the Hubble Space Telescope , based on a spectrum of Vega and the most up-to-date in-flight transmission curves of the camera. This calibration is accurate at the level of a few hundredths of a magnitude. The main purpose of this effort is to transform the entire set of evolutionary models into a simple observational photometric system for ACS/WFC data, and to make them available to the astronomical community. We provide the zero-points for the most used ACS/WFC bands, and give basic recipes for calibrating both the observed data and the models. We also present the colour–magnitude diagram from ACS data of five Galactic globular clusters, spanning the metallicity range  −2.2 <[Fe/H] < −0.04  , and we provide fiducial points representing their sequences from several magnitudes below the turn-off to the red giant branch tip. The observed sequences are compared with the models in the newly defined photometric system.  相似文献   

Depth and Seasonal Distribution of Some Groups of the Vagile Fauna of the Posidonia oceanica Leaf Stratum: Structural and Trophic Analyses     

Maria Cristina  Gambi  Maurizio  Lorenti  Giovanni F.  Russo  Maria Beatrice  Scipione Valerio  Zupo 《Marine Ecology》1992,13(1):17-39

Abstract. The taxonomical and trophic structures of the vagile fauna communities of the leaf stratum in a Posidonia oceanica meadow at Ischia (Gulf of Naples, Italy) were investigated at five stations along a depth gradient (1 to 25 m). Sampling was performed in July, November, February, and May. The analyzed groups - polychaetes, molluscs, tanaids, isopods, amphipods, and decapods - exhibited similar distributional trends in all seasons, with coenotic discontinuities occurring at well-defined depths. The same zonation pattern was produced by feeding-guild analysis. Eleven trophic groups were identified. The most abundant groups were: Herbivores, which were found mainly at the shallow stations; Herbivores-deposit feeders, which were widely distributed along the transect; Deposit feeders-carnivores, found mainly at the deep stations.
This study suggests that in the Posidonia leaf stratum, herbivores and herbivores-deposit feeders, as consumers of epiphytic micro- and macroflora and deposited particulate organic matter, play an important role in the energy transfer from producers to higher trophic levels of the system.  相似文献   

A virtual voyage through 3D structures generated by chaotic mixing of magmas and numerical simulations: a new approach for understanding spatial and temporal complexity of magma dynamics     

Diego Perugini  Maurizio Petrelli  Giampiero Poli 《Visual Geosciences》2008,13(1):1-24

In this contribution, we present a virtual voyage through 3D structures generated by chaotic mixing of magmas and numerical simulations with the aim to highlight the power of 3D representations in the understanding of this geological phenomenon. In particular, samples of mixed juveniles from Salina island (Southern Italy) are reconstructed in 3D by serial lapping and digital montage and numerical simulations are performed by using a 3D chaotic dynamical system. Natural and simulated magma mixing structures are visualized by using several multimedia tools including animations and “virtual reality” models. It is shown that magma interaction processes can generate large spatial and temporal compositional heterogeneities in magmatic systems. The same topological structures are observed in both 3D reconstructed rock samples and chaotic numerical simulations, indicating that the mixing of magmas is governed by chaotic dynamics. The use of 3D multimedia models gives the opportunity to penetrate into magma mixing structures and to understand their significance in the context of magma dynamics. Such an approach is very powerful since multimedia tools can strongly capture the attention of the reader bringing him/her into an interactive and memorable geological experience. Electronic supplementary material  enclosed:  相似文献   

Sunspots: Their rotation,their expansion in the activity zone,their links with the giant convective cells     

Maurizio Ternullo 《Solar physics》1990,127(1):29-50

The rotational properties of sunspots during the time interval 1977–1986 (solar cycle 21) are studied; only sunspot groups older than 4 days have been the object of this research. We have looked systematically for any kind of anomaly or fine structure in the differential rotation latitudinal profile and any significant change occurring during the course of the solar cycle.Some latitudinal bands are found where the angular rotation rate, rather than decreases according to its overall tendency, increases or is constant with the latitude. The differential rotation profile is, therefore, finely structured. The whole fine-structure pattern is affected by a slow equatorward shift. It is suggested that these fine structure features are due to the Coriolis forces acting on the meridional motions associated with giant toroidal convective cells. Some of the properties of such cells are inferred.Moreover, while the spot zone shifts equatorward, it is found to expand poleward; this expansion occurs by the addition of new belts of activity on the poleward side of the pre-existing active zone. The active zone is therefore found to consist, at the maximum activity epoch, of three different belts of spot production, each of them being centered around a local maximum-activity latitude; each of these centroids of activity is hypothesized to lie where a couple of meridional streams - associated with giant cells - converge. The activity belts are independent of each other as far as their activation, maximum, and end time, as well as their lifetime and level of activity are concerned. The angular rotation rate is correlated, in each belt, with the local level of activity.  相似文献   

Use of the Sr/Sr isotopic ratio as an environmental tracer: an example of the application to the Fossil Forest of the Dunarobba (FFD) sedimentary system near Aviglano Umbro (Terni—Central Italy)     

Maurizio Barbieri   《Applied Geochemistry》2002,17(12)

A recent discovery of Pliocene tree trunks (Taxodium, Glyptostrobus or Sequoia) perfectly preserved in the fluvial lacustrine sediments deposited in the old Tiberin Lake (near the town of Dunarobba, Central Italy) has led to the study of the conditions responsible for the trunks preservation. The present work has applied Sr isotope techniques to examine and confirm fluid migration in the different sediment types which cross the entire fluvial-lacustrine sequence. Based on the ⁸⁷Sr/⁸⁶Sr ratios measured in carbonate and in silicate fractions of samples collected from a bore hole (from 0 to 120 m) it is concluded that each sedimentary level has limited communication between zones and is characterised by different isotope values. This suggests that the intrinsic properties of these clays make them a good material for isolating waste, both for direct use and for a better buffer in other formations, possibly less secure, such as salt or granite. The results obtained in the present work have demonstrated some of the potential uses of the ⁸⁷Sr/⁸⁶Sr isotopic ratio as an environmental tracer for confirming results from some of the geotechnical (such as permeability) and geochemical parameters of these host sediments.  相似文献   

Orbitolinidae and Alveolinidae (Foraminiferida) from the uppermost Albian-lower Cenomanian of Monti d'Ocre (Abruzzi, Italy)     

Anna Mancinelli  Maurizio Chiocchini  Barbara Coccia 《Cretaceous Research》2003,24(6):729-741

A biostratigraphic study carried out in the Monti d'Ocre area, Abruzzi, Central Apennines, allowed us to recognize Orbitolina (Conicorbitolina) moulladei ‘Strata 5 (1985) 1’, Praealveolina iberica Reichel and Praealveolina simplex Reichel in uppermost Albian–lower Cenomanian shelf-edge deposits of the Fossato Machè succession. These foraminifers have now been found for the first time in the Apennines of central Italy; their finding is quite important from a palaeobiogeographic viewpoint, as it contributes to the improvement of our knowledge on facies distribution in the circum-Mediterranean regions during the Cretaceous Period. In the study area, the coeval Monte Rotondo and Monte Orsello sections also crop out; these are characterized by bauxite deposits and stratigraphic gaps reflecting episodes of emergence on the carbonate platform. The Monte Rotondo and Monte Orsello sections accumulated in a platform back-reef environment; consequently, in this sector of the Monti d'Ocre area, the depositional environment shifted from a back-reef westward and southward to a shelf-edge northward, during the latest Albian–early Cenomanian. Owing to synsedimentary tectonics, the area investigated underwent differential subsidence: westward and southward, wide areas were uplifted and subjected to emergence, karstification and bauxite accumulation, whereas sedimentation continued in a shelf-edge environment in the north-eastern area.  相似文献   

Hot fluid migration in compressible saturated porous media     

Maurizio Bonafede  Mariangela Mazzanti 《Geophysical Journal International》1997,128(2):383-398

  相似文献   

Magnetobiostratigraphy of the Spathian to Anisian (Lower to Middle Triassic) Kçira section, Albania     

Giovanni Muttoni  Dennis V. Kent  Selam Meço  Alda Nicora  Maurizio Gaetani  Marco Balini  Daniela Germani  Roberto Rettori 《Geophysical Journal International》1996,127(2):503-514

  相似文献