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1.
Masanori Kurosawa Simon E. Jackson Shigeho Sueno 《Geostandards and Geoanalytical Research》2002,26(1):75-84
Fifty elements in NIST SRM 614 and 616 glass reference materials were determined by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). The values determined for NIST SRM 614 agreed well with the NIST-certified and information values (mean relative difference ± 3.6%), except for B, Sc and Sb. The values determined for NIST SRM 616 agreed with the NIST-certified and information values within a mean relative difference of ± 1.5%, except for B, Sc and Ga. In addition, at an 80 μm sampling scale, NIST SRM 614 and 616 glass discs were homogeneous for trace elements within the observed precisions of 5 and 15% (mean), respectively. Detection limits were in the range 0.01 - 0.3 μg g−1 for elements of lower mass numbers (amu < 80) and 1 - 10 ng g−1 for heavy elements (amu > 80). Detection at the sub ng g−1 level is possible for most of the heavy elements by using an ablation pit size larger than 10 0 μm. 相似文献
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The concentrations of hydrogen and the other trace elements in olivines from mantle xenoliths have been determined by secondary
ion mass spectrometry (SIMS) for clarifying the incorporation mechanism and the behavior of the hydrogen. The hydrogen contents
in olivines from mantle xenoliths range from 10 to 60 ppm wt. H2O and the concentration range is consistent with the previous infrared (IR) spectroscopic data. IR spectra of the olivine
crystals show no effects of the weathering or secondary alteration. The hydrogen is distributed homogeneously among olivine
grains in each mantle xenolith. However, the hydrogen contents of the olivine crystals are less than those for the olivine
phenocrysts crystallized from the host magma. Olivine inclusions in diamonds also show similar hydrogen contents to the xenolithic
olivines. Thus the hydrogen content of xenolithic olivines does not attain equilibrium with water in the host magma during
the transportation from the Earth's mantle to the surface, and is taken as a reflection of the hydrogen condition in the mantle.
Correlations of hydrogen with trivalent cation contents in garnet peridotitic olivines indicate the incorporation of hydrogen
into mantle olivines by a coupled substitution mechanism, with the hydrogen present in the form of hydroxyl in oxygen positions
adjacent to the M site vacancies. The hydrogen content of xenolithic olivines increases with pressure but decreases with increasing
temperature, suggesting importance of olivine as a water reservoir at low temperature regions such as in subducting slabs.
Received August 15, 1995/Revised, accepted November 19, 1996 相似文献
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Observed summer (May–October) rainfall in Myanmar for the period 1981–2010 was used to investigate the interannual variability of summer monsoon rainfall over Myanmar. Empirical orthogonal function, the sequential Mann-Kendall test, power spectrum analysis, and singular value decomposition (SVD) were deployed in the study. Results from spectral analysis showed that the variability of rainfall over Myanmar exhibits a 2- to 6-year cycle. An abrupt change in rainfall over the country was noted in 1992. There was a notable increasing rainfall trend from 1989. After the sudden change, the mean rainfall increased by 36.1 mm, compared with the mean rainfall before the sudden change, and was associated with a rise in temperature of about 0.2 °C. An increase in heavy rainfall days was observed from the early 1990s to 2010. IOD and ENSO play an important role in the interannual variability of the summer rainfall over Myanmar. The covariability between rainfall over Myanmar and Indian Ocean SST generally suggests that a positive IOD mode is associated with suppressed rainfall in the central and northern parts of Myanmar. During a negative IOD mode, nearly the whole Myanmar experiences enhanced rainfall, which is associated with devastating socioeconomic impacts. The covariability between the rainfall over Myanmar and the sea surface temperature in the Pacific Ocean in the first and second SVD modes was dominated by warming in the east and central Pacific—an El Niño-like pattern—resulting in dry conditions in central Myanmar. 相似文献
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Ryuichi Kurosawa Tim J. Harries S. P. Littlefair 《Monthly notices of the Royal Astronomical Society》2006,372(4):1879-1887
We present the results of a radial velocity (RV) survey of 14 brown dwarfs (BDs) and very low-mass (VLM) stars in the Upper Scorpius OB association (UScoOB) and three BD candidates in the ρ Ophiuchi dark cloud core. We obtained high-resolution echelle spectra at the Very Large Telescope using the Ultraviolet and Visual Echelle Spectrograph (UVES) at two different epochs for each object, and measured the shifts in their RVs to identify candidates for binary/multiple systems in the sample. The average time separation of the RV measurements is 21.6 d, and our survey is sensitive to the binaries with separation <0.1 au. We found that four out of 17 objects (or 24+16 −13 per cent by fraction) show a significant RV change in 4–33 d time-scale, and are considered as binary/multiple 'candidates'. We found no double-lined spectroscopic binaries in our sample, based on the shape of cross-correlation curves. The RV dispersion of the objects in UScoOB is found to be very similar to that of the BD and VLM stars in Chamaeleon I (Cha I). We also found the distribution of the mean rotational velocities ( v sin i ) of the UScoOB objects is similar to that of the Cha I, but the dispersion of v sin i is much larger than that of the Cha I objects. 相似文献
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Ryuichi Kurosawa Tim J. Harries Neil H. Symington 《Monthly notices of the Royal Astronomical Society》2005,358(2):671-683
We present time-series echelle spectra of the Paβ line of the T Tauri star SU Aur, observed over three consecutive nights. The line shows strong variability (∼10 per cent) over the velocity range 100–420 km s−1 in the red broad absorption component, and weaker variability (∼2 per cent) over the velocity range −200–0 km s−1 in the blue wing. The variability in the velocity range −200–0 km s−1 is correlated with that in 200–400 km s−1 , and the variability in these velocity ranges anticorrelates with that in 0–100 km s−1 . The mean spectrum from the second night shows the suggestion of a blueshifted absorption component at about −150 km s−1 , similar to that found in the Hα and Hβ lines. We find the position of the subpeak in the red absorption component changes steadily with time, and its motion modulates at half the rotational period. We also find that the modulation of the line equivalent width is possibly associated with a half and a third of the rotational period, which is consistent with the surface Doppler images of SU Aur. Radiative transfer models of a rotationally modulated Paβ line, produced in the shock-heated magnetospheric accretion flow, are also presented. Models with a magnetic dipole offset reproduce the overall characteristics of the observed line variability, including the line equivalent width and the motion of the subpeak in the red absorption trough. 相似文献
7.
Estimates of daily lake evaporation based on energy‐budget data are poor because of large errors associated with quantifying change in lake heat storage over periods of less than about 10 days. Energy‐budget evaporation was determined during approximately biweekly periods at a northern Minnesota, USA, lake for 5 years. Various combinations of shortwave radiation, air temperature, wind speed, lake‐surface temperature, and vapour‐pressure difference were related to energy‐budget evaporation using linear‐regression models in an effort to determine daily evaporation without requiring the heat‐storage term. The model that combined the product of shortwave radiation and air temperature with the product of vapour‐pressure difference and wind speed provided the second best fit based on statistics but provided the best daily data based on comparisons with evaporation determined with the eddy‐covariance method. Best‐model daily values ranged from ?0.6 to 7.1 mm/day over a 5‐year period. Daily averages of best‐model evaporation and eddy‐covariance evaporation were nearly identical for all 28 days of comparisons with a standard deviation of the differences between the two methods of 0.68 mm/day. Best‐model daily evaporation also was compared with two other evaporation models, Jensen–Haise and a mass‐transfer model. Best‐model daily values were substantially improved relative to Jensen–Haise and mass‐transfer values when daily values were summed over biweekly energy‐budget periods for comparison with energy‐budget results. 相似文献
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Contributions of individual countries?? emissions to climate change and their uncertainty 总被引：1，自引：0，他引：1
Niklas H?hne Helcio Blum Jan Fuglestvedt Ragnhild Bieltvedt Skeie Atsushi Kurosawa Guoquan Hu Jason Lowe Laila Gohar Ben Matthews Ana Claudia Nioac de Salles Christian Ellermann 《Climatic change》2011,106(3):359-391
We have compiled historical greenhouse gas emissions and their uncertainties on country and sector level and assessed their contribution to cumulative emissions and to global average temperature increase in the past and for a the future emission scenario. We find that uncertainty in historical contribution estimates differs between countries due to different shares of greenhouse gases and time development of emissions. Although historical emissions in the distant past are very uncertain, their influence on countries?? or sectors?? contributions to temperature increase is relatively small in most cases, because these results are dominated by recent (high) emissions. For relative contributions to cumulative emissions and temperature rise, the uncertainty introduced by unknown historical emissions is larger than the uncertainty introduced by the use of different climate models. The choice of different parameters in the calculation of relative contributions is most relevant for countries that are different from the world average in greenhouse gas mix and timing of emissions. The choice of the indicator (cumulative GWP weighted emissions or temperature increase) is very important for a few countries (altering contributions up to a factor of 2) and could be considered small for most countries (in the order of 10%). The choice of the year, from which to start accounting for emissions (e.g. 1750 or 1990), is important for many countries, up to a factor of 2.2 and on average of around 1.3. Including or excluding land-use change and forestry or non-CO2 gases changes relative contributions dramatically for a third of the countries (by a factor of 5 to a factor of 90). Industrialised countries started to increase CO2 emissions from energy use much earlier. Developing countries?? emissions from land-use change and forestry as well as of CH4 and N2O were substantial before their emissions from energy use. 相似文献
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