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The influence of intertidal crab beds on the concentrations of organochlorine (OC) pesticides in sediment was studied in two different coastal environments in Argentina. Samples of male burrowing crabs (Chasmagnathus granulatus) were collected for this study. Our field data showed lower bioaccumulation of OC pesticides in crabs from sediments with a higher total organic carbon (TOC) and higher clay content. Thus, concentrations in crabs depend on the physico-chemical characteristics of the sediment where they live more than on the OC pesticide concentrations in the environment. The distribution patterns in sediment from inside and outside crab burrows were similar for both coastal areas being HCHs  γ-chlordane > p,p′-DDE for San Antonio Bay (SAO), and HCHs > p,p′-DDE  γ-chlordane for Mar Chiquita (MCh) coastal lagoon. OC pesticide concentrations in sediment were significantly lower inside than outside crab burrows, irrespective of the sediment physico-chemical characteristics due to the bioturbation activity of C. granulatus.  相似文献   
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Organochlorine pesticides (OCPs) use has been restricted or forbidden in Argentina since 1998 and technical endosulfan is the last currently used OCPs on the soybean-wheat production. As they persist in soil for several years after application, OCPs constitute a source of environmental pollution. This work aims to assess OCPs contamination of groundwater (Gw) and streamwater (Sw) in the Quequén Grande River watershed from south Argentinean Pampas in relation to the hydrogeological characteristics. OCPs were analyzed in Sw, Gw, surface bottom sediments, soils and borehole cutting sediments (Cs) by gas chromatograph-electron capture detector. Pesticide distribution in Cs was dependent on the characteristic of the non-saturated zone. Leached pesticides over 3 m in Cs showed the pattern: HCHs = endosulfan > chlordanes > DDTs, and from 3 to 6 m heptachlor was the main group as a consequence of the past use of this compound in the area, mainly on potato crops. Endosulfan reaches Gw during application season as well as during flooding events while a retard effect was observed for Sw. Levels of α- and β-isomers were in certain cases above national (7 ng L−1) and international (3 ng L−1) limits for aquatic biota protection. As the endosulfan sulfate metabolite was present in Gw and Sw and due to its high toxicity, it should be considered in the establishment of water quality criteria for human and environmental protection.  相似文献   
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The general goal of this study was to investigate the role of Cynoscion guatucupa as a biomonitor of organochlorine pesticides (OCP) contamination in Bahía Blanca estuary. Thus, we evaluated whether or not OCP fish distribution pattern reflects the OCP land sources, and if size-related bioaccumulation and biomagnification of these contaminants does occur by comparing different tissues of juvenile and adults of C. guatucupa (Cuvier, 1830). Size-related bioaccumulation in C. guatucupa was observed and it was more important for the more lipophilic and biomagnifying OCP, being determined over time by diet influence. Endosulfan sulfate, chlordanes, HCH isomers and DDT compounds predominated in tissues and ingested food of C. guatucupa, being alpha-chlordane, heptachlor and p,p'-DDE highly bioaccumulated and biomagnificated. Our findings also showed that male adults of C. guatucupa are biomonitors of OCP pollution so we propose this species for further investigations in other coastal zones of South America.  相似文献   
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The effect of crab beds and bioturbation activity of the SW Atlantic intertidal crab Chasmagnathus granulata on the organochlorine pesticide (OCP) concentrations in Bahía Blanca estuary, Argentina were studied. Total OCP concentration was significantly lower inside than outside the crab burrows. Nevertheless, the concentrations from outside the crab beds were lower than from outside crab burrows, which indicated that crab beds act as sinks of sediment-bound OCP due to the bioturbation activities of the crabs. The same distribution patterns were found in all sediments as well as in crabs, being cyclodienes>HCHs>DDTs, although large amounts of metabolites rather than the respective parental were found in the organism showing the capacity of C. granulata for metabolising parental compounds. These more water-soluble compounds are excreted by the faeces and finally removed by tidal flushing to the sea. Our results suggest that crabs when present play a role in the distribution of sediment-bound OCP and the crab beds are modifiers of the dynamic of organic pollutants in estuarine areas.  相似文献   
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Proper urban planning and effective implementation requires reliable urban land use statistics. In this context, satellite remote sensing data has been studied using both visual and digital techniques. A portable eight-band radiometer has been used to collect spectral signatures of surface features present in Ahmedabad city and its environs. Using these signatures a suitable approach employing visual and digital techniques has been developed for urban land use/sprawl mapping. Urban land-use maps of Ahmedabad city and its environs were prepared on 1:25,000 scale and for Ahmedabad Urban Development Authority Area on 1:50,000 scale using this methodology. It has been found that edge-enhancement techniques are useful to enhance the contrast among different urban land uses. Classification techniques such as MXL and Bayes classifiers are not successful in discriminating urban land uses. Tonal characteristics alongwith other elements of interpretation are required to classify urban land uses such as residential, industrial etc. Spatial distribution of various urban and uses and the space devoted to each urban land use has been brought out.  相似文献   
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To understand the nature of land degradation and factors responsible for it, investigations were carried out in Etah district with an area of 4.45 lakh hectares. For identification of soil/land degradation problems, multidate Landsat, TM spectral bands and FCC were used. It is observed that salt-affected soils are sharply depicted by light and dark gray mixed tone on band 3, while they are not clear on band 4. Flood plain and waterlogged soils are clearly observed on band 4. Band 6 (10.3 – 12.5 µm) helps in separation of broad zones of coarse and fine-textured soils, active flood plain of rivers, and eroded and gullied lands. The confusion between coarse-textured droughty soils and salt-affected areas in TM FCC (2, 3, 4) could be eliminated by use of band-6 data in combination with FCC. For delineation of problematic areas, two approaches were followed viz. (i) physiographic approach, and (ii) direct approach. In the physiographic approach landscape map associated with image characteristics was prepared. Further the image interpretation units were interpreted for land degradation hazards. With this approach physiography and soil relationship and the degradation problems vis-a-vis soil units could be established and ameliorative measures as per soil condition can be suggested. In direct approach, the problematic areas as per predetermined key were demarcated. Out of 4.45 lakh ha of the area, 1.99 lakh ha is affected by various soil degradation problems, like droughty soils, flooding hazard and salinity and alkalinity which cover 22.1%, 50.0% and 27.9%, respectively. To study the distribution of a salt-affected lands, major physiographic boundaries were superimposed over the land degradation map prepared by direct approach. It is observed that 81.5% of the salt-affected areas lie in the old alluvial plain while 18.5% is in recent flood plain.  相似文献   
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The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. In an investigation of sources of fine-grained sediment (clay and silt) within the Perry Lake Basin in northeast Kansas, representative samples of channel-bank sources, surface-soil sources (cropland and grassland), and reservoir bottom sediment were collected, chemically analyzed, and compared. The samples were sieved to isolate the 〈63μt m fraction and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclide cesium-137 (^137Cs). On the basis of substantial and consistent compositional differences among the source types, total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and ^137Cs were selected for use in the estimation of sediment sources. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment, constituent ratio and clay-normalization techniques were used. Computed ratios included TOC to TN, TOC to TP, and TN to TP. Constituent concentrations (TN, TP, TOC) and activities (^137Cs) were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators. Within the Perry Lake Basin, the consensus of the seven indicators was that both channel-bank and surface-soil sources were important in the Atchison County Lake and Banner Creek Reservoir subbasins, whereas channel-bank sources were dominant in the Mission Lake subbasin. On the sole basis of ^137Cs activity, surface-soil sources contributed the most free-grained sediment to Atchison County Lake, and channel-bank sources contributed the most fine-grained sediment to Banner Creek Reservoir and Mission Lake. Both the seven-indicator consensus and ^137Cs indicated that channelbank sources were dominant for Perry Lake and that channel-bank sources increased in importance with distance downstream in the basin.  相似文献   
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