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1.
Geochemical analyses and geobarometric determinations have been combined to create a depth vs. radiogenic heat production database for the Sierra Nevada batholith, California. This database shows that mean heat production values first increase, then decrease, with increasing depth. Heat production is 2 μW/m3 within the 3-km-thick volcanic pile at the top of the batholith, below which it increases to an average value of 3.5 μW/m3 at 5.5 km depth, then decreases to 0.5–1 μW/m3 at 15 km depth and remains at these values through the entire crust below 15 km. Below the crust, from depths of 40–125 km, the batholith's root and mantle wedge that coevolved beneath the batholith appears to have an average radiogenic heat production rate of 0.14 μW/m3. This is higher than the rates from most published xenolith studies, but reasonable given the presence of crustal components in the arc root assemblages. The pattern of radiogenic heat production interpreted from the depth vs. heat production database is not consistent with the downward-decreasing exponential distribution predicted from modeling of surface heat flow data. The interpreted distribution predicts a reasonable range of geothermal gradients and shows that essentially all of the present day surface heat flow from the Sierra Nevada could be generated within the 35 km thick crust. This requires a very low heat flux from the mantle, which is consistent with a model of cessation of Sierran magmatism during Laramide flat-slab subduction, followed by conductive cooling of the upper mantle for 70 m.y. The heat production variation with depth is principally due to large variations in uranium and thorium concentration; potassium is less variable in concentration within the Sierran crust, and produces relatively little of the heat in high heat production rocks. Because silica content is relatively constant through the upper 30 km of the Sierran batholith, while U, Th, and K concentrations are highly variable, radiogenic heat production does not vary directly with silica content.  相似文献   
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The Rarotonga coral Sr/Ca time series (Linsley et al. in Science 290:1145–1148, 2000) provides a near-monthly resolved proxy record of South Pacific climate variability over the last ~300 years. Here we show that two distinct interdecadal, quasi-periodic time components with periods of ~80 and ~25 years can be identified in this time series by Singular Spectrum Analysis. Their associated spatial patterns in the global sea surface temperature (SST) field show notable differences. Whereas the multidecadal component is associated with a global SST pattern that was recently associated with solar forcing on multidecadal timescales, the bidecadal component is associated with a well known pattern of Pacific decadal to interdecadal SST variability.  相似文献   
4.
The basement of the Romanian Carpathians is made of Neoproterozoic to early Paleozoic periGondwanan terranes variably involved in the Variscan orogeny,similarly to other basement terrains of Europe.They were hardly dismembered during the Alpine orogeny and traditionally have their own names in the three Carpathian areas.The Danubian domain of the South Carpathians comprises the Dragsan and Lainici-Paius peri-Amazonian terranes.The Dragsan terrane originated within the ocean surrounding Rodinia and docked with Rodinia at ~800 Ma.It does not contain Cadomian magmatism and consequently it is classified as an Avalonian extra-Cadomian terrane.The Lainici-Paius terrane is a Ganderian fragment strongly modified by Cadomian subduction-related magmatism.It is attached to the Moesia platform.The Tisovita terrane is an ophiolite that marks the boundary between Dragsan and Lainici-Paius terranes.The other basement terranes of the Romanian Carpathians originated close to the Ordovician NorthAfrican orogen,as a result of the eastern Rheic Ocean opening and closure.Except for the Sebes-Lotru terrane that includes a lower metamorphic unit of Cadomian age,all the other terranes(Bretila,Tulghes,Negrisoara and Rebra in the East Carpathians,Somes,Biharia and Baia de Aries in the Apuseni mountains,Fagaras,Leaota,Caras and Pades in the South Carpathians) represent late Cambrian—Ordovician rock assemblages.Their provenance,is probably within paleo-northeast Africa,close to the Arabian-Nubian shield.The late Cambrian-Ordovician terranes are defined here as Carpathian-type terranes.According to their lithostratigraphy and origin,some are of continental margin magmatic arc setting,whereas others formed in rift and back-arc environment and closed to passive continental margin settings.In a paleogeographic reconstruction,the continental margin magmatic arc terranes were first that drifted out,followed by the passive continental margin terranes with the back-arc terranes in their front.They accreted to Laurussia during the Variscan orogeny.Some of them(Sebes-Lotru in South Carpathians and Baia de Aries in Apuseni mountains) underwent eclogite-grade metamorphism.The Danubian terranes,the Bretila terrane and the Somes terrane were intruded by Variscan granitoids.  相似文献   
5.
An Early Permian volcanic assemblage is well exposed in the central-western part of the Apuseni Mountains (Romania). The rocks are represented by rhyolites, basalts and subordinate andesites suggesting a bimodal volcanic activity that is intimately associated with a post-orogenic (Variscan) syn-sedimentary intra-basinal continental molasse sequences. The mafic and mafic-intermediate rocks belong to sub-alkaline tholeiitic series were separated in three groups (I–III) showing a high Th and Pb abundances, depletion in Nb, Ta and Sr, and slightly enriched in LREE patterns (LaN/YbN = 1.4–4.4). Isotopically, the rocks of Group I have the initial ratios 87Sr/86Sr(i) = 0.709351–0.707112, 143Nd/144Nd(i) = 0.512490–0.512588 and high positive ?Nd270 values from 3.9 to 5.80; the rocks of Group II present for the initial ratios values 87Sr/86Sr(i) = 0.709434–0.710092, 143Nd/144Nd(i) = 0.512231–0.512210 and for ?Nd270 the negative values from −1.17 to −1.56; the rocks of Group III display for the initial ratios the values 87Sr/86Sr(i) = 0.710751–0.709448, 143Nd/144Nd(i) = 0.512347–0.512411 and for ?Nd270 the positive values from 1.64 to 2.35. The rocks resembling continental tholeiites, suggest a mantle origin and were further affected by fractionation and crustal contamination. In addition, the REE geochemistry (1 > SmN/YbN < 2.5; 0.9 > LaN/SmN < 2.5) suggests that these rocks were generated by high percentage partial melting of a metasomatized mantle in the garnet peridotite facies. The felsic rocks are enriched in Cs, Rb Th and U and depleted in Nb, Ta, Sr, Eu, and Ti. The REE fractionation patterns show a strong negative Eu anomaly (Eu/Eu* = 0.23–0.40). The felsic rocks show the initial ratios the values: 87Sr/86Sr(i) = 0.704096–0.707805, 143Nd/144Nd(i) = 0.512012–0.512021 and for ?Nd270 the negative values from −5.27 to −5.44. They suggest to be generated within the lower crust during the emplacement of mantle-derived magmas that provided necessary heat to crustal partial melting.  相似文献   
6.
Deep-water gravity depositional processes and evolution in arc systems have become topics of intense research focus in recent years. This study discusses the co-evolution of volcanism and deep-water gravity flow deposits at the southern margin of the Junggar Basin, based on petrology, geochronology and geochemical analyses. The results show that a massive collapse of unstable sediments from the slope was triggered by volcanism, resulting in the formation of slumping gravity flows. The occurrence...  相似文献   
7.
We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial 87Sr/86Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial εNd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial εNd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (<0.15), and initial εNd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H2O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K2O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.  相似文献   
8.
The late Triassic to early Tertiary Coast Mountains Batholith (CMB) of British Columbia provides an ideal locale to study the processes whereby accreted terranes and subduction-related melts interact to form stable continental crust of intermediate to felsic composition and complementary ultramafic residuals. Seismic measurements, combined with calculated elastic properties of various CMB rock compositions, provide a window into the deep-crustal lithologies that are key to understanding the processes of continental growth and evolution. We use a combination of seismic observations and petrologic modeling to construct hypothetical crustal sections at representative locations across the CMB, then test the viability of these sections via forward modeling with synthetic seismic data. The compositions that make up our petrologic forward models are based on calculations using the free energy minimization program Perple_X to predict mineral assemblages at depth for the bulk compositions of exposed plutonic rocks collected in the study area. Seismic data were collected along two transects in west-central British Columbia: a southern line that crossed the CMB near the town of Bella Coola (near 52° N), and a northern line centered on the towns of Terrace and Kitimat (near 54° N). Along both transects, seismic receiver functions reveal high Vp/Vs ratios near the Insular/Intermontane terrane boundary and crustal thickness increasing from 26 ± 3 km to 34 ± 3 km (at the 1 sigma certainty level) from west to east across the Coast Shear Zone (CSZ). On the southern line, we observe an anomalous region of complex receiver functions and diminished Moho signals beneath the central portion of the CMB. Our petrologic and seismic profiles show that observed seismic data from much of the CMB can be well-matched in terms of crustal thickness and structure, average Vp/Vs, and amplitude of the Moho converted phase, without including ultramafic residual material in the lower crust.  相似文献   
9.
The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10−3 mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca2+ concentration of 2.1 × 10−4 mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca2+ ion exchange against Li+ and Na+ at the permanently charged basal clay planes. Furthermore, the Ca2+ concentration lies close to the critical coagulation concentration (CCC) of 10−3 mol L−1 for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO2(OH)3 complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.  相似文献   
10.
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