Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

自然和自然贡献情景模型研究综述     

岳天祥  范泽孟  史文娇  赵娜 《地球信息科学学报》2020,22(4):743-750

本文回顾了自然和自然贡献情景模型发展的背景、历史和内容,概括总结了自然和自然贡献情景模型的发展进程以及联合国生物多样性与生态系统服务政府间科学—政策平台(IPBES)情景模型的概念框架,讨论了自然和自然贡献情景模型存在的问题和发展方向。为了在全球层面解决现有综合集成模型存在的问题,根据地球表层建模基本定理和生态环境曲面建模基本定理,提出了具有中国原创特点的自然与自然贡献情景模型概念框架。  相似文献   

三峡重庆库区深部地球物理特征与断裂构造   总被引：1，自引：0，他引：1  

胡建平  赵军龙  汪文秉  李娜 《地球科学与环境学报》2005,27(3):49-54

为了深入研究三峡重庆库区岩石圈动力学特征及其对断裂构造活动的控制和影响．并为之提供基础资料，为三峡重庆库区地震、地质灾害的监测与防治提供基础依据，在已有地球物理资料的基础上，从综合地球物理研究角度出发，通过实测地震测线资料的再解释．采用新的处理技术方法，对本区的东西向主剖面和南北向支测线的地震测深资料进行二维射线追踪处理、Pg波成像；选用场分离技术、位移数字成像技术重新处理了重力和航磁资料，通过联合反演来建立深部二维构造剖面，对剖面所揭示的基底构造特征和地壳结构特征、主要断裂构造特征以及莫霍面的起伏特征进行了精细分析和细致研究．从地球物理平面场特征出发建立了岩石圈构造三维框架。研究结果表明，这样的研究思路准确、方法得当．结论可靠；沿该剖面，把可解译的断裂分为Ⅲ级：Ⅰ级为超岩石圈断裂；Ⅱ级为壳断裂；Ⅲ级为盖层断裂。依据地球物理特征，准确揭示了库区的断裂构造特征，达到了预期效果。  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

  相似文献   

Southern Meridional Atmospheric Circulation Associated with IOD     

LIU Na CHEN Hongxia 《中国海洋大学学报(英文版)》2006,5(2):99-105

Using the monthly wind and sea surface temperature （SST） data, southern meridional atmospheric circulation cells associated with the Indian Ocean Dipole Mode （IOD） events in the Indian Ocean are for the first time described and examineS. The divergent wind and pressure vertical velocity are employed for the identification of atmospheric circulation cells. During the four different phases of the positive IOD events, the anomalous meridional Hadley circulation over the western Indian Ocean shows that the air rises in the tropics, flows poleward in the upper troposphere, sinks in the subtropics, and returns back to the tropics in the lower troposphere. The anomalous Hadley circulation over the eastern Indian Ocean is opposite to that over the western Indian Ocean. During positive IOD events, the meridional Hadley circulation over the eastern Indian Ocean is weakened while it is strengthened over the western Indian Ocean. Correlation analysis between the IOD index and the indices of the Hadley cells also proves that, the atmospheric circulation patterns are evident in every IOD event over the period of record.  相似文献   

浅议地勘单位的物业管理     

柯娜 《南方国土资源》2001,14(4):57-60

文章阐述了地勘单位物业管理社会化的必然性和内函 ,提出发展地勘单位物业管理的基本内容和需要解决的问题 ,最终实现以业养业 ,自我发展。  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

  相似文献   

江西省德兴铜矿矿区重金属元素的环境效应   总被引：6，自引：0，他引：6  

初娜  赵元艺  张光弟  杨慧 《地质学报》2008,82(4):562-576

本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质（水土植物）中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。  相似文献   

Distribution of the C₃₇ tetra-unsaturated alkenone in Lake Qinghai, China: A potential lake salinity indicator     

Weiguo Liu  Zhonghui Liu  Zhisheng An 《Geochimica et cosmochimica acta》2008,72(3):988-997

The alkenone unsaturation index U^K′₃₇ has been applied to reconstruct past temperature changes in both marine and lacustrine systems. However, few studies have addressed whether the relative abundance of the C_37:4 alkenone to the total C₃₇ production (%C_37:4) can reflect surface salinity changes in lacustrine systems. Here we present long-chain C₃₇ alkenone distribution patterns in surface sediments from Lake Qinghai, China. Surface sediments were sampled over a large range of surface salinity changes (1.7-25 g/l) within Lake Qinghai and its surrounding lakes, while temperature differences at these sampling locations should be relatively small. We have found that %C_37:4 varies from 15% to 49% as surface salinity decreases. We tentatively describe this %C_37:4-salinity link with a general linear regression: %C_37:4 = 53.4 (±7.8) − 1.73 (±0.45) × S (n = 28, r² = 0.62), although step-wise %C_37:4 changes in response to salinity variation may exist. U^K′₃₇ values vary between 0.10 and 0.16 at these sites and the inferred range of lake water temperature changes is ∼2-3 °C, suggesting that U^K′₃₇ largely reflects temperature signal across a large salinity range, consistent with previous findings that U^K′₃₇ can indicate temperature changes over a large diversity of environmental settings. We have also found that U^K′₃₇ values are correlated with salinity changes (r² = 0.4), and thus cannot exclude potential temperature effect on %C_37:4 and salinity effect on U^K′₃₇ in this study. However, even extreme estimates of temperature differences within the lake are still unable to explain the observed %C_37:4 changes. We therefore suggest that %C_37:4 could be used to infer past lake salinity changes at a regional scale.  相似文献   

Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system   总被引：2，自引：0，他引：2  

Daniel G. Brown  Derek T. Robinson  Li An  Moira Zellner  William Rand  Rick Riolo  Bobbi Low 《Geoforum》2008,39(2):805-818

We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.  相似文献