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A palynological analysis of the Late Miocene and Early Pliocene successions of the Cappadocian Volcanic Province (Central Anatolia, Turkey) has been carried out with the aim of reconstructing the palaeovegetation and palaeoclimatic conditions. The samples are collected from outcrop sections from three different localities (A: Akda?, B: Bayramhac?l? and G: Güzelöz). The pollen spectra reveals the existence of a steppe vegetation dominated by Amaranthaceae–Chenopodiaceae and Artemisia, typical of present day arid and semi-arid continental areas (i.e. Middle East), and Asteraceae Asteroideae in the A section (Late Miocene) developed in arid climatic conditions. The flora of the G (Early Pliocene) and lower part of the B (Late Miocene) sections reflects steppes on which Asteraceae Asteroideae was dominant. This flora also indicates arid conditions. The development of trees in the upper part of the B section was possibly related to local paleoenvironmental conditions rather than a climatic change. This study provides the first palynological data to reveal the presence of an Amaranthaceae–Chenopodiaceae and Artemisia steppe already during the Late Miocene in Turkey.  相似文献   
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Inorganic industrial waste landfills have the potential to contaminate subsurface groundwater supplies through migration of leachates down to the water table and into groundwater aquifers, despite the use of compacted low permeability clay or polyethene liners. This paper aims the removal of Cu2+ and Zn2+ in the leachate from an industrial waste landfill using natural materials (natural zeolite, expanded vermiculite, pumice, illite, kaolinite, and bentonite) as a liner material. Cu2+ and Zn2+ concentrations for all treatments decreased during the process. Of all the different natural materials, natural zeolite, expanded vermiculite and pumice, with bentonite, were effective in removing Cu2+ and Zn2+ present in the leachate. However, the use of illite and kaolinite with bentonite as liner materials could be of disadvantage in Cu2+ and Zn2+ removal from leachate. The adsorption kinetic models were also tested for the validity. The second order kinetics with the high correlation coefficients best described adsorption kinetic data.  相似文献   
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The Equotip hardness tester (EHT) is a portable and non-destructive instrument used mainly for the dynamic rebound hardness testing of metals. Although various versions of the ‘single impacts’ and ‘repeated impacts’ testing procedures have been employed by different authors for different applications, it is not yet known whether a particular testing procedure is more relevant for a specific application in rock engineering. To be able to contribute to the subject, the present study was carried out to determine the suitability of different rebound testing procedures with this instrument for uniaxial compressive strength (UCS) estimations of some selected carbonate rocks. To achieve this goal, as well as four different existing rebound testing procedures, a newly proposed testing methodology involving the parameter hybrid dynamic hardness (HDH) was also employed. The statistical analyses performed on the experimental data, on the whole, showed that the test procedures which are based on single impacts test procedures outperformed the repeated impacts test procedures in terms of UCS prediction accuracy. The prediction capability of the newly introduced testing methodology was found to be superior to those of other procedures considered in this work, suggesting that it could be an efficient tool in practice for preliminary estimates of rock strength. The statistical analyses also indicated that, in practical applications of the EHT using different test procedures, it may be possible to predict the UCS more accurately when apparent density data is available. For the range of specimen sizes considered, no clear evidence of size effect was observed in the mean rebound values. The argument raised by some other authors that the EHT might not be a convenient instrument for the dynamic rebound hardness determination of relatively high-porosity rocks was not confirmed in this study.  相似文献   
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This paper presents several types of new information including U–Pb radiometric dating of ophiolitic rocks and an intrusive granite, micropalaeontological dating of siliceous and calcareous sedimentary rocks, together with sedimentological, petrographic and structural data. The new information is synthesised with existing results from the study area and adjacent regions (Central Pontides and Lesser Caucasus) to produce a new tectonic model for the Mesozoic–Cenozoic tectonic development of this key Tethyan suture zone.

The Tethyan suture zone in NE Turkey (Ankara–Erzincan–Kars suture zone) exemplifies stages in the subduction, suturing and post-collisional deformation of a Mesozoic ocean basin that existed between the Eurasian (Pontide) and Gondwanan (Tauride) continents. Ophiolitic rocks, both as intact and as dismembered sequences, together with an intrusive granite (tonalite), formed during the Early Jurassic in a supra-subduction zone (SSZ) setting within the ?zmir–Ankara–Erzincan ocean. Basalts also occur as blocks and dismembered thrust sheets within Cretaceous accretionary melange. During the Early Jurassic, these basalts erupted in both a SSZ-type setting and in an intra-plate (seamount-type) setting. The volcanic-sedimentary melange accreted in an open-ocean setting in response to Cretaceous northward subduction beneath a backstop made up of Early Jurassic forearc ophiolitic crust. The Early Jurassic SSZ basalts in the melange were later detached from the overriding Early Jurassic ophiolitic crust.

Sedimentary melange (debris-flow deposits) locally includes ophiolitic extrusive rocks of boninitic composition that were metamorphosed under high-pressure low-temperature conditions. Slices of mainly Cretaceous clastic sedimentary rocks within the suture zone are interpreted as a deformed forearc basin that bordered the Eurasian active margin. The basin received a copious supply of sediments derived from Late Cretaceous arc volcanism together with input of ophiolitic detritus from accreted oceanic crust.

Accretionary melange was emplaced southwards onto the leading edge of the Tauride continent (Munzur Massif) during latest Cretaceous time. Accretionary melange was also emplaced northwards over the collapsed southern edge of the Eurasian continental margin (continental backstop) during the latest Cretaceous. Sedimentation persisted into the Early Eocene in more northerly areas of the Eurasian margin.

Collision of the Tauride and Eurasian continents took place progressively during latest Late Palaeocene–Early Eocene. The Jurassic SSZ ophiolites and the Cretaceous accretionary melange finally docked with the Eurasian margin. Coarse clastic sediments were shed from the uplifted Eurasian margin and infilled a narrow peripheral basin. Gravity flows accumulated in thrust-top piggyback basins above accretionary melange and dismembered ophiolites and also in a post-collisional peripheral basin above Eurasian crust. Thickening of the accretionary wedge triggered large-scale out-of-sequence thrusting and re-thrusting of continental margin and ophiolitic units. Collision culminated in detachment and northward thrusting on a regional scale.

Collisional deformation of the suture zone ended prior to the Mid-Eocene (~45?Ma) when the Eurasian margin was transgressed by non-marine and/or shallow-marine sediments. The foreland became volcanically active and subsided strongly during Mid-Eocene, possibly related to post-collisional slab rollback and/or delamination. The present structure and morphology of the suture zone was strongly influenced by several phases of mostly S-directed suture zone tightening (Late Eocene; pre-Pliocene), possible slab break-off and right-lateral strike-slip along the North Anatolian Transform Fault.

In the wider regional context, a double subduction zone model is preferred, in which northward subduction was active during the Jurassic and Cretaceous, both within the Tethyan ocean and bordering the Eurasian continental margin.  相似文献   
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In this paper, we demonstrate the effectiveness of steerable filters as a method of delineating the boundaries of subsurface geological structures. Steerable filters, generally used for edge detection on 2-D images, have the properties of band pass filters with certain directions and are applied to many image processing problems. We first tested the method on synthetic data and then applied it to the aeromagnetic data of İskenderun Basin and adjacent areas.İskenderun Basin is located in the Northeastern Mediterranean where African–Arabian and Anatolian plates are actively interacting. The basin fill records a complex tectonic evolution since the Early Miocene, involving ophiolite emplacement, diachronous collision of Eurasian and Arabian plates and subsequent tectonic escape related structures and associated basin formation. Geophysical investigations of the tectonic framework of İskenderun Basin of Turkey provide important insights on the regional tectonics of the Eastern Mediterranean and Middle East. In this study we show geological structures, which are responsible for the magnetic anomalies in İskenderun Basin and enlighten the structural setting of the Northeastern Mediterranean triple junction using steerable filters. We obtained a magnetic anomaly map of the region from the General Directorate of Mineral Research and Exploration as raw data and then evaluated this by steerable filters. We determined the magnetic anomaly boundaries for İskenderun Basin by using various types of steerable filters and correlated these to drilling data and seismic profiles from the Turkish Petroleum Corporation. The result of the steerable filter analysis was a clarified aeromagnetic anomaly map of İskenderun Basin. The tectonic structure of İskenderun Basin is divided into regions by an N–S trending oblique-slip fault defined by the steerable filter outputs. We propose a new tectonic structure model of İskenderun Basin and modify the direction of the East Anatolian Fault Zone. In our model, East Anatolian Fault Zone cross-cuts the basin as a narrow fault zone and continues towards the Cyprus arc.  相似文献   
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The Mid-Tertiary (Mid-Eocene to earliest Miocene) Misis–Andırın Complex documents tectonic-sedimentary processes affecting the northerly, active margin of the South Tethys (Neotethys) in the easternmost Mediterranean region. Each of three orogenic segments, Misis (in the SW), Andırın (central) and Engizek (in the NE) represent parts of an originally continuous active continental margin. A structurally lower Volcanic-Sedimentary Unit includes Late Cretaceous arc-related extrusives and their Lower Tertiary pelagic cover. This unit is interpreted as an Early Tertiary remnant of the Mesozoic South Tethys. The overlying melange unit is dominated by tectonically brecciated blocks (>100 m across) of Mesozoic neritic limestone that were derived from the Tauride carbonate platform to the north, together with accreted ophiolitic material. The melange matrix comprises polymict debris flows, high- to low-density turbidites and minor hemipelagic sediments.The Misis–Andırın Complex is interpreted as an accretionary prism related to the latest stages of northward subduction of the South Tethys and diachronous continental collision of the Tauride (Eurasian) and Arabian (African) plates during Mid-Eocene to earliest Miocene time. Slivers of Upper Cretaceous oceanic crust and its Early Tertiary pelagic cover were accreted, while blocks of Mesozoic platform carbonates slid from the overriding plate. Tectonic mixing and sedimentary recycling took place within a trench. Subduction culminated in large-scale collapse of the overriding (northern) margin and foundering of vast blocks of neritic carbonate into the trench. A possible cause was rapid roll back of dense downgoing Mesozoic oceanic crust, such that the accretionary wedge taper was extended leading to gravity collapse. Melange formation was terminated by underthrusting of the Arabian plate from the south during earliest Miocene time.Collision was diachronous. In the east (Engizek Range and SE Anatolia) collision generated a Lower Miocene flexural basin infilled with turbidites and a flexural bulge to the south. Miocene turbiditic sediments also covered the former accretionary prism. Further west (Misis Range) the easternmost Mediterranean remained in a pre-collisional setting with northward underthrusting (incipient subduction) along the Cyprus arc. The Lower Miocene basins to the north (Misis and Adana) indicate an extensional (to transtensional) setting. The NE–SW linking segment (Andırın) probably originated as a Mesozoic palaeogeographic offset of the Tauride margin. This was reactivated by strike-slip (and transtension) during Later Tertiary diachronous collision. Related to on-going plate convergence the former accretionary wedge (upper plate) was thrust over the Lower Miocene turbiditic basins in Mid–Late Miocene time. The Plio-Quaternary was dominated by left-lateral strike-slip along the East Anatolian transform fault and also along fault strands cutting the Misis–Andırın Complex.  相似文献   
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Supergene Mn-oxide deposits are widely distributed in Guangxi, Guangdong, Yunnan, and Hunan Provinces, South China, accounting for 18% of the total Mn reserves in the country. Direct dating of supergene Mn enrichment, however, is lacking. In this paper, we present high-resolution 40Ar/39Ar ages of Mn oxides from the Xinrong Mn deposit, western Guangdong, to place numerical constraints on the timing and duration of supergene Mn enrichment. A total of ten cryptomelane samples, spanning a vertical extent of 67 m, were dated using the 40Ar/39Ar laser incremental heating technique, with seven samples yielding well-defined plateau or pseudo-plateau ages ranging from 23.48 ± 0.91 to 2.06 ± 0.05 Ma (2σ). One sample yields a staircase spectrum that does not reach a plateau; the spectrum, however, indicates the presence of two or more generations of Mn oxides in the sample, whose ages are best estimated at 22.34 ± 0.31 and 10.2 ± 0.86 Ma, respectively. The remaining two samples gave meaningless or uninterpretable results due to significant 39Ar recoil and contamination by old phases. The 40Ar/39Ar data thus reveal a protracted history of weathering and supergene Mn enrichment that started at least in the end of the Oligocene or beginning of Miocene and extending into the latest Pliocene. Staircase-apparent age spectra, resulting from banded or botryoidal samples, yield an average growth rate of Mn oxides at 0.6–0.7 × 10−3 mm kyr−1. The values indicate that a 1-mm grain of Mn oxides may host minerals precipitated during a time span of ca. 1.5 m.y., and accumulation of Mn oxides to form economic deposits under weathering environments may take millions of years. The distribution of weathering ages shows that the oldest Mn oxides occur on the top of the profile, whereas the youngest minerals are found at the bottom, suggesting downward propagation of weathering fronts. However, two samples located at the intermediate depths of the profile yield ages comparable with those occurring at the highest elevations. Such a complexity of age distribution is interpreted in terms of preferential penetration of Mn-rich weathering solutions along more permeable fault zones, or as a result of multi stages of dissolution and re-precipitation of Mn oxides. A synthesis of geochronological and geological data suggests that formation of the Xinrong deposit was a consequence of a combination of favorable lithological, climatic, and structural conditions. Because the climatic and structural conditions are similar among the provinces of South China during the Cenozoic, the geochronological results obtained at Xinrong may also have implications for the timing of supergene Mn enrichment throughout South China.  相似文献   
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