排序方式： 共有20条查询结果，搜索用时 265 毫秒
1.
L. A. J. MARTIN M. BALLÈVRE P. BOULVAIS A. HALFPENNY O. VANDERHAEGHE S. DUCHÊNE E. DELOULE 《Journal of Metamorphic Geology》2011,29(2):213-231
The analysis of texture, major element and oxygen isotope compositions of cloudy garnet crystals from a metapelite sampled on Ikaria Island (Greece) is used to assess the model of growth and re‐equilibration of these garnet crystals and to reconstruct the pressure–temperature–fluid history of the sample. Garnet crystals show complex textural and chemical zoning. Garnet cores (100–200 μm) are devoid of fluid inclusions. They are characterized by growth zoning demonstrated by a bell‐shaped profile of spessartine component (7–3 mol.%), an increase in grossular from 14 to 22 mol.% and δ18O values between 9.5 ± 0.3‰ and 10.4 ± 0.2‰. Garnet inner rims (90–130 μm) are fluid inclusion‐rich and show a decreasing grossular component from 22 to 5 mol.%. The trend of the spessartine component observed in the inner rim allows two domains to be distinguished. In contrast to domain I, where the spessartine content shows the same trend as in the core, the spessartine content of domain II increases outwards from 2 to 14 mol.%. The δ18O values decrease towards the margins of the crystals to a lowest value of 7.4 ± 0.2‰. The outer rims (<10 μm) are devoid of fluid inclusions and have the same chemical composition as the outermost part of domain II of the inner rim. Garnet crystals underwent a four‐stage history. Stage 1: garnet growth during the prograde path in a closed system for oxygen. Garnet cores are remnants of this growth stage. Stage 2: garnet re‐equilibration by coupled dissolution–reprecipitation at the temperature peak (630 < T < 650 °C). This causes the creation of porosity as the coupled dissolution–reprecipitation process allows chemical (Ca) and isotopic (O) exchange between garnet inner rims and the matrix. The formation of the outer rim is related to the closure of porosity. Stage 3: garnet mode decreases during the early retrograde path, but garnet is still a stable phase. The resulting garnet composition is characterized by an increasing Mn content in the inner rim’s domain II caused by intracrystalline diffusion. Stage 4: dissolution of garnet during the late retrograde path as garnet is not a stable phase anymore. This last stage forms corroded garnet. This study shows that coupled dissolution–reprecipitation is a possible re‐equilibration process for garnet in metamorphic rocks and that intra‐mineral porosity is an efficient pathway for chemical and isotopic exchange between garnet and the matrix, even for otherwise slow diffusing elements. 相似文献
2.
The actinic flux is the only radiometric quantity suitable for photolysisfrequency determination. It is derived from solar spectral irradiancemeasurements performed by a portable spectroradiometer in the 300–850nm wavelength range. The spectral irradiance is first divided into a directpart and a diffuse part, according to the atmospheric conditions, and thenconverted into the corresponding actinic flux quantity. As an intermediary,the ratio
of diffuse actinic flux to diffuseirradiance is calculated by the spherical harmonics radiative code withrespect to wavelength, solar zenith angle, surface albedo, and aerosolproperties.The results of extensive sensitivity studies of
asa function of the main atmospheric parameters are discussed and lead to theconclusion that aerosol optical depth is the major critical value for aprecise
determination. The global algorithm totransform spectral irradiance into actinic flux is finally applied forphotodissociation rate calculations by convolution of the obtained actinicflux spectra with the absorption cross-sections and quantum yields of themolecule studied. Photolysis rates of different atmospheric photooxidants havebeen measured with this spectroradiometric method during the summers of 1993and 1994 in Brittany and in Portugal. The ozone and nitrogen dioxidephotodissociation rates obtained present a good agreement with thej(O3) and j(NO2) actinometerresults, for the same experimental conditions in Brittany. 相似文献
3.
An approach to characterization of multilayer aquifer systems using open well borehole dilution is described. The approach involves measuring observation well flow velocities while a nearby extraction well is pumped by introducing a saline tracer into observation wells and collecting dilution vs. depth profiles. Inspection of tracer profile evolution allows discrete permeable layers within the aquifer to be identified. Dilution profiles for well sections between permeable layers are then converted into vertical borehole flow velocities and their evolution, using an analytic solution to the advection-dispersion equation applied to borehole flow. The dilution approach is potentially able to measure much smaller flow velocities that would be detectable using flowmeters. Vertical flow velocity data from the observation wells are then matched to those generated using a hydraulic model of the aquifer system, "shorted" by the observation wells, to yield the hydraulic properties of the constituent layers. Observation well flow monitoring of pumping tests represents a cost-effective alternative or preliminary approach to pump testing each layer of a multilayer aquifer system separately using straddle packers or screened wells and requires no prior knowledge of permeable layer depths and thicknesses. The modification described here, of using tracer dilution rather than flowmeter logging to obtain well flow velocities, allows the approach to be extended to greater well separations, thus characterizing a larger volume of the aquifer. An example of the application of this approach to a multilayer Chalk Aquifer in Yorkshire, Northeast England, is presented. 相似文献
4.
Permeability and stress in crystalline rocks 总被引：2，自引：0，他引：2
Groundwater from crystalline rocks is a significant resource in many areas of the world. It is also an important medium for contaminant transport from, for example, deep nuclear waste repositories. Stress distributions in fractured rocks are important in controlling groundwater flow in several ways: (i) palaeostress fields are responsible for the evolution of fracture systems which transmit groundwater; (ii) current in situ stress fields will influence the shape and aperture of fractures; (iii) humans can influence the natural stress field in a rock mass to enhance fracture flows. The significance of stresses for groundwater flow can be investigated by field techniques (hydraulic fracturing), laboratory techniques (stress cells) or by numerical modelling. 相似文献
5.
6.
In fractured-rock aquifers, the geometric and hydraulic properties of the fractures commonly have a dominant influence on transport. Tracer tests are often used to estimate directly the gross transport properties of a fractured rock mass. The prospects for understanding characteristics of the heterogeneities in a fractured porous medium were explored from evidence provided by tracer experiments. The approach was to simulate flow and transport on a large set of prescribed fracture networks in a two-dimensional homogeneous permeable medium, thus generating synthetic tracer test data. The fracture orientation, aperture, spacing and network geometry were systematically altered from one case to the next. A classification scheme was devised for the tracer breakthrough curves using principal component analysis and this classification was linked to the fracture pattern properties. Even under highly simplified and controlled conditions, quite different fracture patterns can produce very similar breakthrough curves. The classification scheme thus demonstrates that a single breakthrough curve cannot reveal the fracture geometry with any precision. However, the scheme provided a methodology for rejecting geometric properties that do not belong to the fracture pattern under investigation, thus reducing the uncertainty in fracture geometry. 相似文献
7.
8.
A recent build-up of atmospheric CO2 over Europe. Part 1: observed signals and possible explanations
By MICHEL RAMONET PHILIPPE CIAIS TUULA AALTO CÉLINE AULAGNIER FRÉDÉRIC CHEVALLIER DOMENICO CIPRIANO THOMAS J. CONWAY LASZLO HASZPRA VICTOR KAZAN FRANK MEINHARDT JEAN-DANIEL PARIS MARTINA SCHMIDT PETER SIMMONDS IRÈNE XUEREF-RÉMY JAROSLAW N. NECKI 《Tellus. Series B, Chemical and physical meteorology》2010,62(1):1-13
We analysed interannual and decadal changes in the atmospheric CO2 concentration gradient (ΔCO2 ) between Europe and the Atlantic Ocean over the period 1995–2007. Fourteen measurement stations are used, with Mace-Head being used to define background conditions. The variability of ΔCO2 reflects fossil fuel emissions and natural sinks activity over Europe, as well as atmospheric transport variability. The mean ΔCO2 increased by 1–2 ppm at Eastern European stations (∼30% growth), between 1990–1995 and 2000–2005. This built up of CO2 over the continent is predominantly a winter signal. If the observed increase of ΔCO2 is explained by changes in ecosystem fluxes, a loss of about 0.46 Pg C per year would be required during 2000–2005. Even if severe droughts have impacted Western Europe in 2003 and 2005, a sustained CO2 loss of that magnitude is unlikely to be true. We sought alternative explanations for the observed CO2 build-up into transport changes and into regional redistribution of fossil fuel CO2 emissions. Boundary layer heights becoming shallower can only explain 32% of the variance of the signal. Regional changes of emissions may explain up to 27% of the build-up. More insights are given in the Aulagnier et al. companion paper. 相似文献
9.
Noelle E. Odling 《Pure and Applied Geophysics》1992,138(1):95-114
The influence that fractures exert on the permeability of a fractured rock is, to a large extent, controlled by the nature of the network formed by the fracture system. Here, the network properties of a two-dimensional natural pattern, mapped from the surface of a sandstone layer, are investigated and compared to those of realizations of spatially randomly distributed line segments with similar orientation and length distributions and line segment density (line length per unit area) to the natural pattern. These patterns are composed of clusters of varying size and shape, made up of interconnected fracture traces or line segments. Comparing the natural pattern with the realizations, the natural pattern was found to contain roughly half the number of clusters while the mass (total line length) of the largest cluster is approximately double that of the realizations. The size of the largest cluster controls the connectivity of the patterns, as can be seen by comparing the largest cluster of the natural pattern, which connects all four sides of the region, with those of the realizations, which are unconnected or connect only two sides. Cluster scaling characteristics were found to be similar in the natural pattern and the realizations and show a crossover from a dimension of one (their topological dimension) to two (the dimension of the embedding medium) at a point that corresponds to the fracture spacing. An investigation of the self-similarity dimension, using the box-counting method, showed similar characteristics with a broad transition zone between one- and two-dimensional behaviour at smaller box sizes. The patterns are therefore found to be non-fractal. The effect of the spatial distribution shown by the natural pattern is thus to modify the manner in which fractures are distributed among clusters, increasing connectivity (and permeability in the case of open fractures), but does not affect the cluster scaling characteristics or the self-similarity dimension of the fracture patterns. 相似文献
10.
A study of sedimentary structures of cold-climate coastal dunes along Eastern Hudson Bay, Canada, showed that in areas of very sparsely vegetated surfaces, tractional sedimentary processes are dominant while in partly and well vegetated areas, grainfall deposition is the dominant sedimentary process. Alternating fine and coarse sand strata are characteristic of the vegetated foredune ridge. Coarse strata are interpreted to be mainly related to niveo-aeolian deposition. In poorly vegetated areas deformed strata associated with the melting of snow were preserved. A vaguely stratified strata interpreted as a dimpled surface as well as coarse lenses with irregular basal contact were found. Such distinctive sedimentary structures may represent good indicators of cold-climate conditions and could serve as criteria to identify aeolianites that may have been deposited in similar cold-climate environments in palaeoenvironmental reconstructions. 相似文献