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1.
Mercury accumulation in the food chain, as a consequence of gold recovery in Brazil, has been an issue of concern. Reactions of Hg in the environment are quite complex, and can involve various Hg chemical species. Laboratory experiments were carried out on Hg0 solubility, Hg complexation and sorption on river sediments from a gold mining region in Brazil. The reactivity and the mobility of Hg species were considered. Results indicate that methyl mercury is more mobile than ionic mercury, and that the presence of humic acid enhances drastically the solubility of Hg0. The soluble complex formed has a relatively lower interaction at the sediment/water interface and is more prone to spread through the aquatic environment.  相似文献   
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The calcareous sponge Paraleucilla magna (Porifera, Calcarea) has been the subject of several studies in the last decade. It was first described along the Brazilian coast, where it is considered cryptogenic, and was subsequently found in the Mediterranean, where it is considered invasive. The wide artificial distribution of this species allows us to compare different aspects of the biology of an introduced species in different locations. Here, we analysed the effects of selected environmental parameters on the reproductive dynamics of P. magna in Rio de Janeiro (Brazil) over 18 months and compared our results with those obtained for the same species in the Mediterranean Sea. Specimens were collected monthly and analysed through histological methods. The density of reproductive elements in each month was calculated, and the effects of environmental parameters (photoperiod, precipitation, temperature, phytoplankton and bacterioplankton) were analysed using a regression tree analysis. Paraleucilla magna was reproductive throughout the study period. The densities of the reproductive elements (oocytes, embryos and larvae) showed no seasonality, and this species presented one of the highest reproductive efforts documented to date in the phylum Porifera (99.0 oocytes · mm?3; 89.0 embryos · mm?3; 319.0 larvae · mm?3). The main environmental parameters related to the reproduction of P. magna were temperature, photoperiod and bacterioplankton. Temperature was the main driver associated with the densities of oocytes and embryos, while bacterioplankton was the main driver of larvae (positive relationships). In Rio de Janeiro, larvae were present and continuously released. This strategy is different from that observed in the Mediterranean, where a larger larval output was observed but only during the summer months. Our results show that P. magna is a species with a strong invasive potential, considering its high and continuous reproductive effort. This high fecundity stimulated by high temperatures may be a key factor contributing to the growth of P. magna populations and its invasion of new areas.  相似文献   
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ABSTRACT

This study provides a spatio-temporal analysis of the great floods that occurred in South America in 1983 using hydrometeorological data and outputs from a continental-scale hydrological-hydrodynamic model. In the extreme year 1983, there were three main flooding periods (February, June and July) in many South American river basins, such as the Araguaia, Tocantins, São Francisco, Uruguay, La Plata and its tributaries, resulting in high discharge of the Paraguay River for many months. Depth–area–duration curves show that 3-day precipitation events in northern regions of South America were among the largest 15 events in the period 1980–2015 but only for specific locations, whereas in southern areas, the most extreme events in the same period were for larger durations (≥7-day precipitation). Modelled total export of water volume to the oceans indicates that rivers draining to the South Atlantic reached an anomaly of 3.7 during 1983, followed by 1998 (1.9) and 1992 (1.1), all of them corresponding to El Niño years.  相似文献   
5.
The search for suitable sites to install near-surface repositories for low to intermediate level radioactive wastes has increased in the recent years, reflecting both the continuous rise in radioactive materials applications by the society and the increasing awareness of public perception regarding radwaste management. International recommendations towards the application of higher safety standards to low and intermediate level waste disposal sites being developed by the International Atomic Energy Agency (IAEA), and the European Commission decision that each Member State must safely dispose its own radwaste in its territory, according to national radwaste management plans, has leading to new soundly scientific studies. In Portugal, possible locations for that purpose are under study since 2006, following the pre-requisites indicated by IAEA. One of these sites overlaps a significant portion of an ultramafic massif, corresponding to an allochthonous and metamorphosed ophiolite complex. In the surveyed area of this massif, the prevailing rock type consists of (serpentinised) peridotites, occasionally containing irregular bodies of (amphibolitised) gabbros, over which an irregular/ill-developed regolith exists. The activities of 40K, 137Cs, 210Pb, 226Ra and 232Th measured in samples representing three consecutive levels of the regolith upper portion in 13 stations confirm the heterogeneity put in evidence through in situ γ-ray surveys previously performed. The available dataset also demonstrates that radionuclide contents decrease prominently with depth, becoming closer to the bedrock values (up to ca. 41 Bq kg?1 for 40K in flaser-gabbros and near zero for all the remaining cases) but never reaching them. Therefore, the low/moderate radionuclide activity in the regolith upper portion reflect the contribution of sources that are independent of the lithological background; i.e. they indicate external and miscellaneous contributions to the “soil”-forming components, most of them coming from (dry or wet) atmospheric deposition. The chemical composition of the (serpentinised) peridotites and (amphibolitised) gabbros in the surveyed area, as well as their alteration products included in regolith, is homogeneous enough to be used as a faithful reference in monitoring studies of any kind. In addition, the significant 137Cs activities measured in some top “soil” samples (up to 92 Bq kg?1) strongly suggest that there are mineralogical specificities of the peridotite-derived regolith able to fix that radionuclide. This particular feature reinforces the existing criteria that favour the peridotites of Morais as a suitable host for a near surface repository of low to intermediate level radwaste.  相似文献   
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ABSTRACT

An accurate comprehension of celerity (flood wave speed) dynamics is a key step for understanding flood wave propagation in rivers. We present the results of empirically estimated celerity values in 12 Brazilian rivers, and analyse the behaviour of celerity–discharge relationships (CxQ). Celerity was estimated with a reach-scale (RS) method, based on the peak travel time between stations; and with a local-scale (LS) method, based on the derivative of discharge–cross-section area relationships surveyed at gauging stations. The results indicate that the magnitudes of celerity values obtained by the methods are reasonably comparable, and can rarely be considered constant, varying with river discharge. Three reaches presented differing CxQ relationships at local and reach scales, which suggests that in situ cross-sections at gauging stations should not be extrapolated as representative of the whole reach for flood routing studies, and that CxQ relationship assessments might provide relevant insights for hydrological modelling.  相似文献   
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Pulp and paper mills utilise huge amount of natural resources, inorganic and organic materials along with large volume of water in different stages of paper manufacturing, resulting in a significant volume of effluents. The aim of this work was to investigate the treatment of a bleaching effluent [effluent chlorine free (ECF)] from the cellulose industry with white-rot fungi in an air-lift bioreactor. This effluent was submitted to the biological treatment with three white-rot fungi, and, every 24 h for 120 h, analytical tests were performed to analyse the quality parameters of treatment (COD, phenols, colour, pH). Before and after treatment, the effluent was analysed as its molecular mass distribution and absorptivity in the UV/VIS. Lentinus edodes, Trametes versicolor and Trametes villosa promoted similarly significant reductions in the following characteristics: (a) effluent colour (40–44 %), (b) total phenol (30–51 %) and (c) COD (37–43 %). The UV/visible spectrometry reading of the effluent after the fungi treatment showed a reduction in the absorbance of all wavelengths between 260 and 500 nm. The size exclusion HPLC profile of the effluent was modified, and the treatment promoted changes in the intensity of the peaks associated with compounds of high and low molecular weight. Phenoloxidases were produced during the treatment. T. versicolor produced the highest levels of laccase, and L. edodes was the only fungus that produced peroxidases.  相似文献   
9.
Historical mortars from sixteenth to seventeenth century military forts located at the mouth of the Tagus River in Lisbon have been characterized by polarized light microscopy (PLM), thermal analysis (TG/DTA), X-ray diffractometry (XRD) and scanning electron microscopy + energy dispersive spectroscopy (SEM + EDS). The results indicate that the mortars used were all hydraulic lime-based. The presence of well-rounded lime lumps indicates a limited use of water during the lime hydration process. The detection of hydrated calcium chloroaluminate and carboaluminate compounds mostly at binder-aggregate interfaces provides evidence for the onset of pozzolanic reactions during mortar production as further confirmed by the presence of ceramic fragments in the aggregate fractions intentionally added by the fort builders to increase the hydraulic properties of the mortars. The higher mechanical strength and greater resistance to degradation processes imparted by these pozzolanic compounds could explain why, despite the extreme proximity of the investigated sites to the sea, salt weathering processes do not appear to have significantly affected the studied mortars.  相似文献   
10.
Little is known about the recruitment and behaviour of sponge larvae, especially of the class Calcarea. The calcareous sponge Paraleucilla magna is very common in Southeast Brazil, where it is considered a cryptogenic species. This study quantified recruitment rates in shaded and illuminated habitats for 2 years in Rio de Janeiro, Brazil, and analyzed larval photoresponses of this species. Four structures, each containing a shaded and an illuminated surface, were exchanged every 3 months for 2 years. The number of recruits was quantified on each plate. In the laboratory, larvae of P. magna were placed in half‐shaded Petri dishes and the number of settlers in each side was counted after 24 h. Paraleucilla magna recruited continuously throughout the experiment. Recruits occurred in greater abundance on shaded surfaces than on illuminated surfaces, and the larvae were negatively phototactic in vitro. Despite the possible influence of other factors in the recruitment of sponges (such as sedimentation, competition and predation), the prevalence of P. magna in shaded habitats may also be related to larval choice.  相似文献   
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