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1.
Because of the ubiquitous nature of anthropogenic nitrate (NO3(-)) in many parts of the world, determining background concentrations of NO3(-) in shallow ground water from natural sources is probably impossible in most environments. Present-day background must now include diffuse sources of NO3(-) such as disruption of soils and oxidation of organic matter, and atmospheric inputs from products of combustion and evaporation of ammonia from fertilizer and livestock waste. Anomalies can be defined as NO3(-) derived from nitrogen (N) inputs to the environment from anthropogenic activities, including synthetic fertilizers, livestock waste, and septic effluent. Cumulative probability graphs were used to identify threshold concentrations separating background and anomalous NO(3)-N concentrations and to assist in the determination of sources of N contamination for 232 spring water samples and 200 well water samples from karst aquifers. Thresholds were 0.4, 2.5, and 6.7 mg/L for spring water samples, and 0.1, 2.1, and 17 mg/L for well water samples. The 0.4 and 0.1 mg/L values are assumed to represent thresholds for present-day precipitation. Thresholds at 2.5 and 2.1 mg/L are interpreted to represent present-day background concentrations of NO(3)-N. The population of spring water samples with concentrations between 2.5 and 6.7 mg/L represents an amalgam of all sources of NO3(-) in the ground water basins that feed each spring; concentrations > 6.7 mg/L were typically samples collected soon after springtime application of synthetic fertilizer. The 17 mg/L threshold (adjusted to 15 mg/L) for well water samples is interpreted as the level above which livestock wastes dominate the N sources. 相似文献
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Samuel V. Panno Zohreh Askari Walton R. Kelly Thomas M. Parris Keith C. Hackley 《Ground water》2018,56(1):32-45
The conservative nature of chloride (Cl?) in groundwater and the abundance of geochemical data from various sources (both published and unpublished) provided a means of developing, for the first time, a representation of the hydrogeology of the Illinois Basin on a basin‐wide scale. The creation of Cl? isocons superimposed on plan view maps of selected formations and on cross sections across the Illinois Basin yielded a conceptual model on a basin‐wide scale of recharge into, groundwater flow within and through the Illinois Basin. The maps and cross sections reveal the infiltration and movement of freshwater into the basin and dilution of brines within various geologic strata occurring at basin margins and along geologic structures. Cross‐formational movement of brines is also seen in the northern part of the basin. The maps and cross sections also show barriers to groundwater movement created by aquitards resulting in areas of apparent isolation/stagnation of concentrated brines within the basin. The distribution of Cl? within the Illinois Basin suggests that the current chemical composition of groundwater and distribution of brines within the basin is dependent on five parameters: (1) presence of bedrock exposures along basin margins; (2) permeability of geologic strata and their distribution relative to one another; (3) presence or absence of major geologic structures; (4) intersection of major waterways with geologic structures, basin margins, and permeable bedrock exposures; and (5) isolation of brines within the basin due to aquitards, inhomogeneous permeability, and, in the case of the deepest part of the basin, brine density effects. 相似文献
3.
Three regolith-collapse sinkholes formed near the Dongola Unit School and the Pentecostal Church in the southern Illinois village of Dongola (Union County) during the spring of 1993. The sinkholes appeared over a three-month period that coincided with development of a new municipal well. The new well was drilled through clay-rich, valley-fill sediment into karstified limestone bedrock. The piezometric surface of the limestone aquifer is above land surface, indicating the presence of an upward hydraulic gradient in the valley and that the valley fill is acting as a confining unit. Pumping during development of the well lowered the piezometric surface of the limestone aquifer to an elevation below the base of the valley fill. It is hypothesized that drainage of water from the sediments, the resulting loss of hydrostatic pressure and buoyant force in overlying sediments, increased intergranular pressure, and the initiation of groundwater flow toward the well resulted in rapid sediment transport, subsurface erosion, and collapse of the valley-fill sediment. The sinkholes follow an approximately east-west alignment, which is consistent with one of the two dominant alignments of passages of nearby joint-controlled caves. A constant electrode-separation resistivity survey of the school playground was conducted to locate areas that might contain incipient sinkholes. The survey revealed a positive resistivity anomaly trending N75E in the southern part of the study area. The anomaly is linear, between 5 and 10 m wide, and its trend either intersects or is immediately adjacent to the three sinkholes. The anomaly is interpreted to be a series of pumping-induced cavities in the valley-fill sediments that formed over a preexisting crevice in the karstified bedrock limestone. 相似文献
4.
Nitrate and herbicide loading in two groundwater basins of Illinois'' sinkhole plain 总被引：1，自引：0，他引：1
This investigation was designed to estimate the mass loading of nitrate (NO3−) and herbicides in spring water discharging from groundwater basins in an agriculturally dominated, mantled karst terrain. The loading was normalized to land use and NO3− and herbicide losses were compared to estimated losses in other agricultural areas of the Midwestern USA. Our study area consisted of two large karst springs that drain two adjoining groundwater basins (total area of 37.7 km2) in southwestern Illinois' sinkhole plain, USA. The springs and stream that they form were monitored for almost 2 years. Nitrate–nitrogen (NO3–N) concentrations at three monitoring sites were almost always above the background concentration (1.9 mg/l). NO3–N concentrations at the two springs ranged from 1.08 to 6.08 with a median concentration of 3.61 mg/l. Atrazine and alachlor concentrations ranged from <0.01 to 34 μg/l and <0.01 to 0.98 μg/l, respectively, with median concentrations of 0.48 and 0.12 μg/l, respectively. Approximately 100,000 kg/yr of NO3–N, 39 kg/yr of atrazine, and 2.8 kg/yr of alachlor were discharged from the two springs. Slightly more than half of the discharged NO3− came from background sources and most of the remainder probably came from fertilizer. This represents a 21–31% loss of fertilizer N from the groundwater basins. The pesticide losses were 3.8–5.8% of the applied atrazine, and 0.05–0.08% of the applied alachlor. The loss of atrazine adsorbed to the suspended solid fraction was about 2 kg/yr, only about 5% of the total mass of atrazine discharged from the springs. 相似文献
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Panno SV Hackley KC Hwang HH Greenberg SE Krapac IG Landsberger S O'Kelly DJ 《Ground water》2006,44(2):176-187
Elevated concentrations of sodium (Na+) and chloride (Cl-) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br), and iodide (I) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I and Br; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources. 相似文献
7.
Karst aquifers: can they be protected? 总被引：1，自引：1，他引：0
Panno SV 《Ground water》2006,44(4):494-494
8.
The occurrence of infections with Trichinella sp. in polar bears (Ursus maritimus) from northeastern Greenland has been studied by examination of muscle samples, mainly diaphragm, from 38 animals shot during the period 1983-1987. Trichinella larvae were demonstrated in 12 bears (32%) with an average of 9.2 larvae/g muscle tissue. No bears younger than three years old were infected. The prevalence of Trichinella among bears of the age group 3-4 years was 25% and 53% among older animals. 相似文献
9.
Samuel V. Panno B. Brandon Curry Hong Wang Keith C. Hackley Chao-Li Liu Craig Lundstrom Juanzuo Zhou 《Quaternary Research》2004,61(3):301-313
Matrix-supported diamicton and uniform to laminated, silty, fine-grained sediment deposited from about 42,500 to 27,600 cal yr B.P. under slackwater conditions nearly filled two caves in southwestern Illinois. At some point, most of the sediment was flushed from the caves and from about 22,700 to 4000 cal yr B.P., floods deposited a drape of sandy and silty sediment on remnant slackwater successions, cobbly alluvium, and bedrock (especially from 7700 to 4000 cal yr B.P.). Clay mineral analyses of the slackwater cave sediment reveal a provenance of chiefly Petersburg Silt, a smectite- and illite-rich proglacial lacustrine unit present in the overlying Illinois Episode glacial succession. Today, remnants of the ancient subterranean slackwater deposits nearly fill several secondary passages and, in at least two locations, cover a cobble-mantled strath terrace 1.3 to 1.5 m above active stream channels. Slumping and sinkhole formation appear to have been important mechanisms for deposition of the ancient subterranean deposits. Slumping of these surficial deposits and associated vegetation can occur along the flanks of sinkholes (in addition to sinkhole formation) and enter caves; however, the finer organics, some of them comminuted during transport into the caves, become part of the cave alluvium. This finer organic fraction is the modern analog of the humified organic matter disseminated in slackwater sediment dated in this investigation by radiocarbon methods. Twenty-four 14C ages on humified organic matter provide chronologic control. The δ13C values of the organic matter reflect the proportion of C4-type to C3-type vegetation growing in and around swallets and sinkholes at the time of redeposition. Drought-tolerant C4-type vegetation was more prevalent relative to C3-type vegetation from 42,500 to 31,200 cal yr B.P. compared to conditions from 28,800 cal yr B.P. to the present. The δ13C values are consistent with the results from other investigations of speleothems and organic matter from loessial paleosols. 相似文献
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