Mixing of carbonate waters     

T.M.L. Wigley  L.N. Plummer 《Geochimica et cosmochimica acta》1976,40(9):989-995

When mineral solutions of different compositions are mixed, the molalities and activities of individual ions in the mixture are often non-linear functions of their end-member values. This non-linearity is particularly significant in determining mineral saturation levels. Mixtures of saturated solutions may be either undersaturated or supersaturated depending on the end-member compositions and the physical conditions in which end-members and their mixtures exist. In carbonate solutions important non-linear effects occur due to redistribution of carbonate species. In extreme cases this causes mixture pH to be below both the end-member pH values. A simple but precise computer program (WATMIX) has been developed for calculating mixture composition for closed and open system mixing of arbitrary end-members. A number of mixing examples are considered which allow one to isolate three important processes leading to non-linear behaviour: the algebraic effect, the δP_CO2 effect, and the ionic strength effect.  相似文献   

The dissolution of calcite in CO₂-saturated solutions at 25°C and 1 atmosphere total pressure     

L.Niel Plummer  T.M.L Wigley 《Geochimica et cosmochimica acta》1976,40(2):191-202

The dissolution of Iceland spar in CO₂-saturated solutions at 25°C and 1 atm total pressure has been followed by measurement of pH as a function of time. Surface concentrations of reactant and product species have been calculated from bulk fluid data using mass transport theory and a model that accounts for homogeneous reactions in the bulk fluid. The surface concentrations are found to be close to bulk solution values. This indicates that calcite dissolution under the experimental conditions is controlled by the kinetics of surface reaction. The rate of calcite dissolution follows an empirical second order relation with respect to calcium and hydrogen ion from near the initial condition (pH 3.91) to approximately pH 5.9. Beyond pH 5.9 the rate of surface reaction is greatly reduced and higher reaction orders are observed. Calculations show that the rate of calcite dissolution in natural environments may be influenced by both transport and surface-reaction processes. In the absence of inhibition, relatively short times should be sufficient to establish equilibrium.  相似文献   

A 17-Year Record of Environmental Tracers in Spring Discharge,Shenandoah National Park,Virginia, USA: Use of Climatic Data and Environmental Conditions to Interpret Discharge,Dissolved Solutes,and Tracer Concentrations   总被引：1，自引：0，他引：1  

Eurybiades Busenberg  L. Niel Plummer 《Aquatic Geochemistry》2014,20(2-3):267-290

A 17-year record (1995–2012) of a suite of environmental tracer concentrations in discharge from 34 springs located along the crest of the Blue Ridge Mountains in Shenandoah National Park (SNP), Virginia, USA, reveals patterns and trends that can be related to climatic and environmental conditions. These data include a 12-year time series of monthly sampling at five springs, with measurements of temperature, specific conductance, pH, and discharge recorded at 30-min intervals. The monthly measurements include age tracers (CFC-11, CFC-12, CFC-113, CFC-13, SF₆, and SF₅CF₃), dissolved gases (N₂, O₂, Ar, CO₂, and CH₄), stable isotopes of water, and major and trace inorganic constituents. The chlorofluorocarbon (CFC) and sulfur hexafluoride (SF₆₎ concentrations (in pptv) in spring discharge closely follow the concurrent monthly measurements of their atmospheric mixing ratios measured at the Air Monitoring Station at Big Meadows, SNP, indicating waters 0–3 years in age. A 2-year (2001–2003) record of unsaturated zone air displayed seasonal deviations from North American Air of ±10 % for CFC-11 and CFC-113, with excess CFC-11 and CFC-113 in peak summer and depletion in peak winter. The pattern in unsaturated zone soil CFCs is a function of gas solubility in soil water and seasonal unsaturated zone temperatures. Using the increase in the SF₆ atmospheric mixing ratio, the apparent (piston flow) SF₆ age of the water varied seasonally between about 0 (modern) in January and up to 3 years in July–August. The SF₆ concentration and concentrations of dissolved solutes (SiO₂, Ca²⁺, Mg²⁺, Na⁺, Cl^?, and HCO₃ ^?) in spring discharge demonstrate a fraction of recent recharge following large precipitation events. The output of solutes in the discharge of springs minus the input from atmospheric deposition per hectare of watershed area (mol ha^?1 a^?1) were approximately twofold greater in watersheds draining the regolith of Catoctin metabasalts than that of granitic gneisses and granitoid crystalline rocks. The stable isotopic composition of water in spring discharge broadly correlates with the Oceanic Niño Index. Below normal precipitation and enriched stable isotopic composition were observed during El Niño years.  相似文献   

Building zoned ignimbrites by recycling silicic cumulates: insight from the 1,000 km<Superscript>3</Superscript> Carpenter Ridge Tuff,CO     

Olivier?BachmannEmail author  Chad?D.?Deering  Peter?W.?Lipman  Charles?Plummer 《Contributions to Mineralogy and Petrology》2014,167(6):1025

The ~1,000 km³ Carpenter Ridge Tuff (CRT), erupted at 27.55 Ma during the mid-tertiary ignimbrite flare-up in the western USA, is among the largest known strongly zoned ash-flow tuffs. It consists primarily of densely welded crystal-poor rhyolite with a pronounced, highly evolved chemical signature (high Rb/Sr, low Ba, Zr, Eu), but thickly ponded intracaldera CRT is capped by a more crystal-rich, less silicic facies. In the outflow ignimbrite, this upper zone is defined mainly by densely welded crystal-rich juvenile clasts of trachydacite composition, with higher Fe–Ti oxide temperatures, and is characterized by extremely high Ba (to 7,500 ppm), Zr, Sr, and positive Eu anomalies. Rare mafic clasts (51–53 wt% SiO₂) with Ba contents to 4,000–5,000 ppm and positive Eu anomalies are also present. Much of the major and trace-element variations in the CRT juvenile clasts can be reproduced via in situ differentiation by interstitial melt extraction from a crystal-rich, upper-crustal mush zone, with the trachydacite, crystal-rich clasts representing the remobilized crystal cumulate left behind by the melt extraction process. Late recharge events, represented by the rare mafic clasts and high-Al amphiboles in some samples, mixed in with parts of the crystal cumulate and generated additional scatter in the whole-rock data. Recharge was important in thermally remobilizing the silicic crystal cumulate by partially melting the near-solidus phases, as supported by: (1) ubiquitous wormy/sieve textures and reverse zoning patterns in feldspars and biotites, (2) absence of quartz in this very silicic unit stored at depths of >4–5 km, and (3) heterogeneous melt compositions in the trachydacite fiamme and mafic clasts, particularly in Ba, indicating local enrichment of this element due mostly to sanidine and biotite melting. The injection of hot, juvenile magma into the upper-crustal cumulate also imparted the observed thermal gradient to the deposits and the mixing overprint that partly masks the in situ differentiation process. The CRT provides a particularly clear perspective on processes of in situ crystal-liquid separation into a lower crystal-rich zone and an upper eruptible cap, which appears common in incrementally built upper-crustal magma reservoirs of high-flux magmatic provinces.  相似文献   

Climate during the last glacial maximum in the Wasatch and southern Uinta Mountains inferred from glacier modeling   总被引：1，自引：0，他引：1  

Benjamin J.C. Laabs  Mitchell A. Plummer  David M. Mickelson 《Geomorphology》2006,75(3-4):300

Recent improvements in understanding glacial extents and chronologies in the Wasatch and Uinta Mountains and other mountain ranges in the western U.S. call for a more detailed approach to using glacier reconstructions to infer paleoclimates than commonly applied AAR-ELA-ÄT methods. A coupled 2-D mass balance and ice-flow numerical modeling approach developed by [Plummer, M.A., Phillips, F.M., 2003. A 2-D numerical model of snow/ice energy balance and ice flow for paleoclimatic interpretation of glacial geomorphic features. Quaternary Science Reviews 22, 1389–1406] allows exploration of the combined effects of temperature, precipitation, shortwave radiation and many secondary parameters on past ice extents in alpine settings. We apply this approach to the Little Cottonwood Canyon in the Wasatch Mountains and the Lake Fork and Yellowstone Canyons in the south-central Uinta Mountains. Results of modeling experiments indicate that the Little Cottonwood glacier required more precipitation during the local Last Glacial Maximum (LGM) than glaciers in the Uinta Mountains, assuming lapse rates were similar to modern. Model results suggest that if temperatures in the Wasatch Mountains and Uinta Mountains were  6 °C to 7 °C colder than modern, corresponding precipitation changes were  3 to 2× modern in Little Cottonwood Canyon and  2 to 1× modern in Lake Fork and Yellowstone Canyons. Greater amounts of precipitation in the Little Cottonwood Canyon likely reflect moisture derived from the surface of Lake Bonneville, and the lake may have also affected the mass balance of glaciers in the Uinta Mountains.  相似文献   

Adaptive co-management and the paradox of learning   总被引：10，自引：1，他引：9  

Derek Armitage  Melissa Marschke  Ryan Plummer 《Global Environmental Change》2008,18(1):86-98

Much emphasis has been placed on the importance of learning to support collaborative environmental management and achieve sustainability under conditions of social–ecological change. Yet, on-going struggles to learn from experience and respond to complex social–ecological conditions reflect an emerging paradox. Despite widespread support of learning as a normative goal and process, core concepts, assumptions and approaches to learning have been applied in vague and sometimes uncritical ways. Greater specificity with respect to learning goals, approaches and outcomes is required. In response to this gap, we examine five dimensions of the learning paradox in the context of adaptive co-management, where the learning and linking functions of governance are stressed: (i) definitions of learning; (ii) learning goals and expectations; (iii) mechanisms by which learning takes place; (iv) questions regarding who is involved in the process of learning; and (v) the risks and ethical ambiguities faced by different actors expected to willingly participate in a learning process, whether formal or informal. Lessons from experience with a series of cases from the global North and South illustrate the implications of these dimensions. Resolving the dimensions of this learning paradox will require greater attention to capacity-building, recognition of the role of risk, and consideration of how incentives could be used to encourage learning. Further consideration of the role of power and marginality among groups participating in the learning process is also needed, as is more systematic evaluation to monitor and measure learning outcomes.  相似文献   

Meteoritics and Planetary Science goes electronic     

Derek Sears  Bradley R. Plummer 《Meteoritics & planetary science》1999,34(5):687-687

  相似文献   

Changes in Climate Extremes Over the Australian Region and New Zealand During the Twentieth Century   总被引：10，自引：0，他引：10  

Neil Plummer  M. James Salinger  Neville Nicholls  Ramasamy Suppiah  Kevin J. Hennessy  Robert M. Leighton  Blair Trewin  Cher M. Page  Janice M. Lough 《Climatic change》1999,42(1):183-202

Analyses of high quality data show that there have been some interesting recent changes in the incidence of some climate extremes in the Australian region and New Zealand.  相似文献   

Radiocarbon dating of dissolved inorganic carbon in groundwater from confined parts of the Upper Floridan aquifer, Florida, USA   总被引：3，自引：1，他引：3  

Niel L. Plummer  Craig L. Sprinkle 《Hydrogeology Journal》2001,9(2):127-150

Geochemical reaction models were evaluated to improve radiocarbon dating of dissolved inorganic carbon (DIC) in groundwater from confined parts of the Upper Floridan aquifer in central and northeastern Florida, USA. The predominant geochemical reactions affecting the ¹⁴C activity of DIC include (1) dissolution of dolomite and anhydrite with calcite precipitation (dedolomitization), (2) sulfate reduction accompanying microbial degradation of organic carbon, (3) recrystallization of calcite (isotopic exchange), and (4) mixing of fresh water with as much as 7% saline water in some coastal areas. The calculated cumulative net mineral transfers are negligibly small in upgradient parts of the aquifer and increase significantly in downgradient parts of the aquifer, reflecting, at least in part, upward leakage from the Lower Floridan aquifer and circulation that contacted middle confining units in the Floridan aquifer system. The adjusted radiocarbon ages are independent of flow path and represent travel times of water from the recharge area to the sample point in the aquifer. Downgradient from Polk City (adjusted age 1.7 ka) and Keystone Heights (adjusted age 0.4 ka), 14 of the 22 waters have adjusted ¹⁴C ages of 20–30 ka, indicating that most of the fresh-water resource in the Upper Floridan aquifer today was recharged during the last glacial period. All of the paleowaters are enriched in ¹⁸O and ²H relative to modern infiltration, with maximum enrichment in δ¹⁸O of approximately 2.0‰. Electronic Publication  相似文献   

Crystal growth of calcite from calcium bicarbonate solutions at constant P_CO2 and 25°C: a test of a calcite dissolution model     

Michael M Reddy  L.Niel Plummer  E Busenberg 《Geochimica et cosmochimica acta》1981,45(8):1281-1289

A highly reproducible seeded growth technique was used to study calcite crystallization from calcium bicarbonate solutions at 25°C and fixed carbon dioxide partial pressures between 0.03 and 0.3 atm. The results are not consistent with empirical crystallization models that have successfully described calcite growth at low P_CO2 (< 10^?3 atm). Good agreement was found between observed crystallization rates and those calculated from the calcite dissolution rate law and mechanism proposed by Plummer et al. (1978).  相似文献