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Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds
varying in SiVI:SiIV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported
by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of SiVI/(SiVI+SiIV): (1) A linear relationship between the L2,3-L1 splitting and SiVI/(SiVI+SiIV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied
to both Si K- and L-edge ELNES spectra.
Received: February 10, 1997 / Revised, accepted: May 23, 1997 相似文献
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Christian Liebske Bettina Schmickler Hidenori Terasaki Brent T. Poe Akio Suzuki Ken-ichi Funakoshi Ryota Ando David C. Rubie 《Earth and Planetary Science Letters》2005,240(3-4):589-604
The viscosity of synthetic peridotite liquid has been investigated at high pressures using in-situ falling sphere viscometry by combining a multi-anvil technique with synchrotron radiation. We used a newly designed capsule containing a small recessed reservoir outside of the hot spot of the heater, in which a viscosity marker sphere is embedded in a forsterite + enstatite mixture having a higher solidus temperature than the peridotite. This experimental setup prevents spheres from falling before a stable temperature above the liquidus is established and thus avoids difficulties in evaluating viscosities from velocities of spheres falling through a partially molten sample.
Experiments have been performed between 2.8 and 13 GPa at temperatures ranging from 2043 to 2523 K. Measured viscosities range from 0.019 (± 0.004) to 0.13 (± 0.02) Pa s. At constant temperature, viscosity increases with increasing pressure up to 8.5 GPa but then decreases between 8.5 and 13 GPa. The change in the pressure dependence of viscosity is likely associated with structural changes of the liquid that occur upon compression. By combining our results with recently published 0.1 MPa peridotite liquid viscosities [D.B. Dingwell, C. Courtial, D. Giordano, A. Nichols, Viscosity of peridotite liquid, Earth Planet. Sci. Lett. 226 (2004) 127–138.], the experimental data can be described by a non-Arrhenian, empirical Vogel-Fulcher-Tamman equation, which has been modified by adding a term to account for the observed pressure dependence of viscosity. This equation reproduces measured viscosities to within 0.08 log10-units on average. We use this model to calculate viscosities of a peridotitic magma ocean along a liquid adiabat to a depth of 400 km and discuss possible effects on viscosity at greater pressures and temperatures than experimentally investigated. 相似文献
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Paul F. McMillan Brent T. Poe Thomas R. Stanton Richard L. Remmele 《Physics and Chemistry of Minerals》1993,19(7):454-459
We have obtained high quality Raman spectra for two H/D isotopically substituted hydrous aluminosilicate glasses with compositions along the NaAlSi3O8-SiO2 join. Consistent with the results of previous studies, the isotope shift for the band near 900 cm–1, whose intensity grows with increasing water content, is extremely small: v
h
/v
d
= 1.004 ± 0.004. The lack of a definite H/D isotope shift for this band does not, however, preclude its association with a vibration of a hydrous species in the glass, because of likely strong coupling between different vibrational modes of hydrated framework species. The 900 cm–1 band could well be due to a T — OH (T = Si, Al) stretching or bending vibration in the hydrous glass, as required by the presence of a combination band near 4500 cm–1 in near-infrared spectra. 相似文献
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Mark E. Byrnes R. Wayne Nelson Robert G. La Poe Dennis E. Lundquist William McNeill 《Ground Water Monitoring & Remediation》1990,10(4):90-95
A remedial investigation (RI) was performed in an area downgradient from an abandoned missile silo at Vandenberg Air Force Base, California, as part of the United States Air Force Installation Restoration Program (IRP). A number of complementary investigative techniques were used to assure a reliable assessment of site contamination. These included the review of aerial photographs, the use of an organic vapor analyzer (OVA) and carbon adsorption/mass spectrometer (MS) method to conduct a soil-gas survey; magnetic and electromagnetic geophysical surveys; bedrock permeability testing; and the chemical analysis of soil, sediment, surface water, and ground water samples. The results from this investigation revealed the presence of an undocumented landfill and a small trichloroethylene plume in ground water at concentrations ranging from 6.7 ppb to 31 ppb. The investigation also identified local ground water flow direction, provided strong evidence of the location of potential sources of contamination, and defined the downgradient extent of ground water contamination. Because the identified contaminants have not as yet reached the environmentally sensitive wetland at the base of the slope below this facility, there is still time to propose remedial alternatives that would serve to protect this environmentally sensitive area. 相似文献
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T. Sharp Z. Wu F. Seifert B. Poe M. Doerr E. Paris 《Physics and Chemistry of Minerals》1996,23(1):17-24
Si K-, L- and O K-edge ELNES spectra of natural α-quartz and synthetic coesite on one side and synthetic stishovite on the other show characteristic differences that can be related, by comparison with multiple-scattering (MS) calculations, to the fourfold vs. sixfold coordination of Si in these polymorphs of SiO2. It is shown by MS calculations on large clusters that the outer shells contribute relatively little to the overall topologies of the spectra. Therefore, distinction between fourfold- and sixfold-coordinated Si is possible even on a nm scale and probably also in amorphous substances. 相似文献
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Isabelle Daniel Philippe Gillet Brent T. Poe Paul F. McMillan 《Physics and Chemistry of Minerals》1995,22(2):74-86
We have measured in-situ Raman spectra of aluminosilicate glasses and liquids with albite (NaAlSi3 O8) and anorthite (CaAl2Si2O8) compositions at high temperatures, through their glass transition range up to 1700 and 2000 K, respectively. For these experiments, we have used a wire-loop heating device coupled with micro-Raman spectroscopy, in order to achieve effective spatial filtering of the extraneous thermal radiation. A major concern in this work is the development of methodology for reliably extracting the first and second order contributions to the Raman scattering spectra of aluminosilicate glasses and liquids from the high temperature experimental data, and analyzing these in terms of vibrational (anharmonic) and configurational changes. The changes in the first order Raman spectra with temperature are subtle. The principal low frequency band remains nearly constant with increasing temperature, indicating little change in the T-O-T angle, and that the angle bending vibration is quite harmonic. This is in contrast to vitreous SiO2, studied previously. Above Tg, intensity changes in the 560–590 cm?1 regions of both sets of spectra indicate configurational changes in the supercooled liquids, associated with formation of additional Al-O-Al linkages, or 3-membered (Al, Si)-containing rings. Additional intensity at 800 cm?1 reflects also some rearrangement of the Si-O-Al network. 相似文献
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Natural Resource Access Rights and Wrongs: Nontimber Forest Products Gathering in Urban Environments
This article uses research about non-timber forest products (NTFP) gathering in Seattle, Washington, USA to examine how people gain access to natural resources in urban environments. Our analysis focuses on gathering in three spaces: parks, yards, and public rights of way. We present a framework for conceptualizing access, and highlight cognitive mechanisms of access associated with foragers’ internal moral judgments about harvesting. Key findings are: (1) internal moral calculations about whether it is right or wrong to harvest a particular NTFP in a particular place are an important but previously unacknowledged mechanism governing resource access; and (2) these calculations may help prevent over-harvesting of NTFPs, which are common pool resources, in urban environments where social and environmental conditions lend themselves to a de facto situation of open access. Our findings suggest that voluntary codes of conduct may be the best way to manage NTFP access in cities. 相似文献
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