排序方式： 共有8条查询结果，搜索用时 31 毫秒
1
1.
Reactive surface area is one of the key parameters for studying the kinetics of mineral dissolution. The common practice in experimental kinetics is to normalize the dissolution rate to the surface area measured by the BET method. The relationship between BET surface area and the reactive surface area is not trivial in minerals such as smectites, which possess both internal and external surface areas, and in which the dissolution is controlled by the chemical attack on the edge surface. The present study examines two proxies for the reactive surface area of the Clay Mineral Society reference smectite SAz-1: BET surface area and the edge surface area measured using AFM.Since smectites are very microporous, their BET surface area is strongly influenced by the degassing procedure. It is demonstrated that outgassing the smectite powder at 135°C in a 15 mL min−1 N2 gas flow for at least 24 hours minimizes contribution from micropores to less than 11% of the BET surface area.Following dissolution experiments in solutions with a low electrolyte concentration, the BET surface area increased from 34 ± 2 m2 g−1 in raw SAz-1 to 127 ± 13 m2 g−1 in SAz-1 sample recovered from dissolution experiments. This increase in BET surface area is explained by a decrease in the average size of the smectite aggregates, and by an increase in microporosity due to the depletion in the major interlayer cation, i.e., Ca2+. As the BET surface area of the raw smectite sample includes considerably less microporosity compared to the BET surface area of the smectite recovered from dissolution experiments, the former is a better approximation of the external surface area of the dried sample powder.AFM measurements show that there is no correlation between the specific external surface area of the sample and its specific edge surface area. This observation is explained by the platy morphology of the smectite particle in which the specific external surface area depends linearly on the height reciprocal, whereas the specific edge surface area is independent of the particles height and depends linearly on the sum of the reciprocals of the length of the axes. Therefore, there is no reason to expect a correlation between the BET and the edge surface area. Our results show that the edge surface area (4.9 ± 0.7 m2 g−1) of the smectite particles cannot be predicted based on its external surface area (136 ± 20 m2 g−1). Therefore, the BET surface area cannot serve as a proxy for the reactive surface area. We suggest using AFM measurements of the specific edge surface area as an alternative proxy for the reactive surface area of smectite. 相似文献
2.
3.
Raanan Katzir 《中国沙漠》2000,20(2):113-117
以色列的沙漠地区占土总面积的６％,沙漠地区的传统农业是以大面积的牧场上放牧少量耐旱畜种以及种植少量抗时粮食作物为基础的;沙漠地区的现代化农业是依靠外来水源,如从加利利海引来的水和人口密集的中心城市的再循环污水为基础的。有些地区的咸水可用于灌溉耐盐作物,如马玲薯、瓜类、葡萄、橄榄和枣树,有些作物还可采用滴灌法。严酷的沙漠气候条件可采用温室加以控制,主要生产供出口的淡季疏散、花卉和香草。在海滨地区的浙 相似文献
4.
Raanan Katzir 《寒旱区科学》2015,7(1):0001-0006
The Israeli Desert constitutes 60% of the country's total area. Regional annual precipitation is 100–200 mm and evaporation reaches 2,500 mm. Traditional desert agriculture of rain fed wheat and sheep, goat and camels grazing is common. Despite the harsh climate conditions, advance agriculture is concentrated in foci where water resources exist. Desert agriculture takes advantage of the winter(October–April) due to a mild climate season for growing vegetables, flowers, herbs and fruit which are mostly exported to European countries. The key factor is the sustainable management of the local natural resources. The regional research and development(RD) system is generating adequate local knowledge and technologies. The most important key factor is developing water resources, and using irrigation saving water systems such as drip irrigation. Technologies of protected agriculture such as greenhouses and plastic tunnels are used. The unfit desert soil is substitute by sand and artificial growing media. For gaining market purposes, introduction of botanical species was implemented for various flowers and vegetable varieties, avocado, pitaya, and jojoba. Controlled drip irrigation and drainage helps to solve salinity problems. Integrated Pest Management(IPM) is used to overcome plant protection issues. Advance raising of milking cows was developed by using reduction heat stress methods. Tilapia are raised in open ponds and greenhouse ponds, and ostriches adapted to desert conditions were introduced. On the southern Judean hills where precipitation is 250 mm, through soil conservation and rain harvesting, significant afforestation is changing the desert scenery. The human factor on this process such as farmers, agricultural extension agents and research scientists is the leading factor. 相似文献
5.
Interval velocity analysis using post‐stack data has always been a desire, mainly for 3D data sets. In this study we present a method that uses the unique characteristics of migrated diffractions to enable interval velocity analysis from three‐dimensional zero‐offset time data. The idea is to perform a standard three‐dimensional prestack depth migration on stack cubes and generate three‐dimensional common image gathers that show great sensitivity to velocity errors. An efficient ‘top‐down’ scheme for updating the velocity is used to build the model. The effectiveness of the method is related to the incorporation of wave equation based post‐stack datuming in the model building process. The proposed method relies on the ability to identify diffractions along redatumed zero‐offset data and to analyse their flatness in the migrated local angle domain. The method can be considered as an additional tool for a complete, prestack depth migration based interval velocity analysis. 相似文献
6.
Raanan Katzir 《寒旱区科学》2013,5(6):0767-0768
Desertification is a global phenomenon that affects about two billion people. It occurs in arid zones where the annual precipitation is below 400 mm, partic- ularly in the marginal areas of the world＇s largest deserts. It is a result of water and wind erosion, over- grazing, global warm-ing, improper soil cultivation, and increased pressure ot population growth, and it causes degradation of soil and natural and agricultural vegetation. The direct result is less food for people and livestock, which influences pop- ulation and animal husbandry fluctuations. Despite ef- forts to combat and reduce desertification, the affected areas are annually increasing. 相似文献
7.
Prestack image volumes may be decomposed into specular and non‐specular parts by filters defined in the dip‐angle domain. For space‐shift extended image volumes, the dip‐angle decomposition is derived via local Radon transform in depth and midpoint coordinates, followed by an averaging over space‐shifts. We propose to employ prestack space‐shift extended reverse‐time migration and dip‐angle decomposition for imaging small‐scale structural elements, considered as seismic diffractors, in models with arbitrary complexity. A suitable design of a specularity filter in the dip‐angle domain rejects the dominant reflectors and enhances diffractors and other non‐specular image content. The filter exploits a clear discrimination in dip between specular reflections and diffractions. The former are stationary at the specular dip, whereas the latter are non‐stationary without a preferred dip direction. While the filtered image volume features other than the diffractor images (for example, noise and truncation artefacts are also present), synthetic and field data examples suggest that diffractors tend to dominate and are readily recognisable. Averaging over space‐shifts in the filter construction makes the reflectors? rejection robust against migration velocity errors. Another consequence of the space‐shift extension and its angle‐domain transforms is the possibility of exploring the image in a multiple set of common‐image gathers. The filtered diffractions may be analysed simultaneously in space‐shift, scattering‐angle, and dip‐angle image gathers by means of a single migration job. The deliverables of our method obviously enrich the processed material on the interpreter's desk. We expect them to further supplement our understanding of the Earth's interior. 相似文献
8.
1