Molybdenum disulfide (MoS2), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials
and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms
in MoS2 is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the
insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these
minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion
will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia. 相似文献
Tropical cyclones and their devastating impacts are of great concern to coastal communities globally. An appropriate approach integrating climate change scenarios at local scales is essential for producing detailed risk models to support cyclone mitigation measures. This study developed a simple cyclone risk-modelling approach under present and future climate change scenarios using geospatial techniques at local scales, and tested using a case study in Sarankhola Upazila from coastal Bangladesh. Linear storm-surge models were developed up to 100-year return periods. A local sea level rise scenario of 0.34?m for the year 2050 was integrated with surge models to assess the climate change impact. The resultant storm-surge models were used in the risk-modelling procedures. The developed risk models successfully identified the spatial extent and levels of risk that match with actual extent and levels within an acceptable limit of deviation. The result showed that cyclone risk areas increased with the increase of return period. The study also revealed that climate change scenario intensified the cyclone risk area by 5–10% in every return period. The findings indicate this approach has the potential to model cyclone risk in other similar coastal environments for developing mitigation plans and strategies. 相似文献
For the managers of a region as large as the Great Barrier Reef, it is a challenge to develop a cost effective monitoring program, with appropriate temporal and spatial resolution to detect changes in water quality. The current study compares water quality data (phytoplankton abundance and water clarity) from remote sensing with field sampling (continuous underway profiles of water quality and fixed site sampling) at different spatial scales in the Great Barrier Reef north of Mackay (20 degrees S). Five transects (20-30 km long) were conducted from clean oceanic water to the turbid waters adjacent to the mainland. The different data sources demonstrated high correlations when compared on a similar spatial scale (18 fixed sites). However, each data source also contributed unique information that could not be obtained by the other techniques. A combination of remote sensing, underway sampling and fixed stations will deliver the best spatial and temporal monitoring of water quality in the Great Barrier Reef. 相似文献
Sustainable management of coastal and coral reef environments requires regular collection of accurate information on recognized ecosystem health indicators. Satellite image data and derived maps of water column and substrate biophysical properties provide an opportunity to develop baseline mapping and monitoring programs for coastal and coral reef ecosystem health indicators. A significant challenge for satellite image data in coastal and coral reef water bodies is the mixture of both clear and turbid waters. A new approach is presented in this paper to enable production of water quality and substrate cover type maps, linked to a field based coastal ecosystem health indicator monitoring program, for use in turbid to clear coastal and coral reef waters. An optimized optical domain method was applied to map selected water quality (Secchi depth, Kd PAR, tripton, CDOM) and substrate cover type (seagrass, algae, sand) parameters. The approach is demonstrated using commercially available Landsat 7 Enhanced Thematic Mapper image data over a coastal embayment exhibiting the range of substrate cover types and water quality conditions commonly found in sub-tropical and tropical coastal environments. Spatially extensive and quantitative maps of selected water quality and substrate cover parameters were produced for the study site. These map products were refined by interactions with management agencies to suit the information requirements of their monitoring and management programs. 相似文献
This article shows the potential impact on global GHG emissions in 2030, if all countries were to implement sectoral climate policies similar to successful examples already implemented elsewhere. This assessment was represented in the IMAGE and GLOBIOM/G4M models by replicating the impact of successful national policies at the sector level in all world regions. The first step was to select successful policies in nine policy areas. In the second step, the impact on the energy and land-use systems or GHG emissions was identified and translated into model parameters, assuming that it would be possible to translate the impacts of the policies to other countries. As a result, projected annual GHG emission levels would be about 50 GtCO2e by 2030 (2% above 2010 levels), compared to the 60 GtCO2e in the ‘current policies’ scenario. Most reductions are achieved in the electricity sector through expanding renewable energy, followed by the reduction of fluorinated gases, reducing venting and flaring in oil and gas production, and improving industry efficiency. Materializing the calculated mitigation potential might not be as straightforward given different country priorities, policy preferences and circumstances.
Key policy insights
Considerable emissions reductions globally would be possible, if a selection of successful policies were replicated and implemented in all countries worldwide.
This would significantly reduce, but not close, the emissions gap with a 2°C pathway.
From the selection of successful policies evaluated in this study, those implemented in the sector ‘electricity supply’ have the highest impact on global emissions compared to the ‘current policies’ scenario.
Replicating the impact of these policies worldwide could lead to emission and energy trends in the renewable electricity, passenger transport, industry (including fluorinated gases) and buildings sector, that are close to those in a 2°C scenario.
Using successful policies and translating these to policy impact per sector is a more reality-based alternative to most mitigation pathways, which need to make theoretical assumptions on policy cost-effectiveness.
As part of the Copenhagen Accord, Annex I Parties (industrialised countries) and non-Annex I Parties (developing countries) have submitted reduction proposals (pledges) and mitigation actions to the UNFCCC secretariat. Our calculations show that if the current reduction offers of Annex I and non-Annex I countries are fully implemented, global greenhouse gas emissions could amount to 48.6-49.7 GtCO2eq by 2020. Recent literature suggests that the emission level should be between 42 and 46 GtCO2eq by 2020 to maintain a “medium” chance (50-66%) of meeting the 2 °C target. The emission gap is therefore 2.6-7.7 GtCO2eq. We have identified a combined set of options, which could result in an additional 2.8 GtCO2eq emission reduction. This would lead to an emission level just within the range needed. The options include reducing deforestation and emissions from bunker fuels, excluding emissions allowance increases from land use and forestry rules, and taking into account the national climate plans of China and India. However, there are also important risks that could widen the emissions gap, like lower reductions from countries with only a conditional pledge and the use of Kyoto and/or trading of new surplus emission allowances. 相似文献
Blue carbon initiatives require accurate monitoring of carbon stocks. We examined sources of variability in seagrass organic carbon (Corg) stocks, contrasting spatial with short temporal scales. Seagrass morphology and sediment Corg stocks were measured from biomass and shallow sediment cores collected in Moreton Bay, Australia. Samples were collected between 2012 and 2013, from a total of 77 sites that spanned a gradient of water turbidity. Environmental measures of water quality between 2000 and 2013 revealed strong seasonal fluctuations from summer to winter, yet seagrass biomass exhibited no temporal variation. There was no temporal variability in Corg stocks, other than below ground biomass stocks were slightly higher in June 2013. Seagrass locations were grouped into riverine, coastal, and seagrass loss locations and short temporal variability of Corg stocks was analysed within these categories to provide clearer insights into temporal patterns. Above ground Corg stocks were similar between coastal and riverine meadows. Below ground Corg stocks were highest in coastal meadows, followed by riverine meadows. Sediment Corg stocks within riverine meadows were much higher than at coastal meadows and areas of seagrass loss, with no difference in sediment Corg stocks between these last two categories. Riverine seagrass meadows, of higher turbidity, had greater total Corg stocks than meadows in offshore areas irrespective of time. We suggest that Corg stock assessment should prioritise sampling over spatial gradients, but repeated monitoring over short time scales is less likely to be warranted if environmental conditions remain stable. 相似文献