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1.
Following the basic incubation study, a greenhouse experiment was conducted to elucidate the efficiency of vetiver grass (Vetiveria zizanioides L.), with or without chelating agents, in remediating lead (Pb)‐contaminated soils from actual residential sites where Pb‐based paints were used. Because the primary factor affecting Pb phytoavailability in soils is soil pH, we used two soil types widely varying in pH that have total Pb concentrations above 1500 mg kg?1 soil. Lead‐contaminated, low pH, acidic soils were collected from residential sites in Baltimore, MD and high pH, alkaline soils were collected from residential sites in San Antonio, TX. Based on the soil characterization results, two most appropriate soils (one from each city, having similar Pb levels but variable soil physico‐chemical properties) were selected for this study. Ethylenediaminetetraacetic acid (EDTA) and [S,S′]ethylenediaminedisuccinate (EDDS) were applied at 5, 10, and 15 mmol kg?1 soil. Lead uptake and translocation in vetiver was determined on day 10 after chelants addition. Plant and soil analysis show that EDTA treated soils have maximum Pb uptake and lower total soil Pb levels. Prediction models developed for exchangeable Pb show a strong correlation for total Pb accumulated in vetiver grass. Results of the sequential chemical extraction of the soils at both initial and final time‐points, indicates a significant mobilization of Pb by the two chelants from carbonate‐bound fraction to exchangeable pool. Information on physico‐chemical properties of contaminated residential soils help in predicting Pb phytoextraction and thus further help in calibrating a successful chelant‐assisted phytoremediation model. 相似文献
2.
The evolution and dynamics of the north-polar cap (residual-ice-cap/layered-deposits complex) of Mars is simulated with a thermomechanical ice-sheet model. We consider a scenario with ice-free initial conditions at 5 Ma before present due to the large obliquities which prevailed prior to this time. The north-polar cap is then built up to its present shape, driven by a parameterized climate forcing (surface temperature, surface mass balance) based on the obliquity and eccentricity history. The effects of different ice rheologies and different dust contents are investigated. It is found that the build-up scenarios require an accumulation rate of approximately 0.15-0.2 mm a−1 at present. The topography evolution is essentially independent of the ice dynamics due to the slow ice flow. Owing to the uncertainties associated with the ice rheology and the dust content, flow velocities can only be predicted within a range of two orders of magnitude. Likely present values are of the order of 0.1-1 mm a−1, and a strong variation over the climatic cycles is found. For all cases, computed basal temperatures are far below pressure melting. 相似文献
3.
Rupali Chandar 《Astrophysics and Space Science》2009,324(2-4):315-319
The age, mass, and size distributions of star clusters in nearby star-forming galaxies provide important clues to the formation and evolution of cluster systems. In particular, the similarities and differences between these cluster distributions in very different environments can help to disentangle formation and disruption processes. We present the age and mass distributions for clusters younger than ≈1 Gyr in the Magellanic Clouds, which are typical, star-forming irregular galaxies, and compare the results with the more “extreme” environment found in the merging Antennae galaxies. In addition, we describe some new results on the interpretation of ancient globular cluster systems, and present an emerging picture for the life cycle of star clusters. 相似文献
4.
Syam S. Andra Rupali Datta Ramana Reddy Sumathi K. M. Saminathan Dibyendu Sarkar 《洁净——土壤、空气、水》2011,39(5):428-436
In a previous study we have demonstrated the suitability of using vetiver grass (Vetiveria zizanioides L.) for the phytostabilization of lead‐based paint contaminated residential soils. Vetiver did not show any growth retardation or toxicity symptoms despite high soil Pb levels. Antioxidant enzymes like superoxide dismutase (SOD), catalase (CAT), and glutathione peroxidase (GPx) reportedly allow plants to combat metal stress. Thus, we hypothesized that in vetiver, these antioxidant enzymes can play an important role in combating Pb induced stress, and that chelant‐bound Pb is less toxic to vetiver compared to free Pb in soil. The response of antioxidant enzymes was studied in vetiver grass grown in Pb paint‐contaminated residential soils collected from San Antonio, Texas and Baltimore, Maryland. Chelating agents such as ethylenediaminetetraacetic acid (EDTA) and ethylenediaminedisuccinic acid (EDDS) were used to mobilize Pb from bound fractions to the labile pool, facilitating Pb uptake by vetiver. Although the Pb concentration in vetiver from these treatments was significantly higher than those grown in the absence of a chelant, the antioxidant enzymes activities were lower compared to the latter. Antioxidant enzymes activity of vetiver plants grown in the presence of chelants is lower compared to those in without chelant treatment, while they tended to increase with dose in treatments with varying chelant concentrations. Data obtained support the proposed hypothesis. 相似文献
5.
Ingestion of As – contaminated soil by children is a growing concern in former agricultural lands converted to residential or recreational land use areas. The mobility and bioavailability of As is controlled by its reactions with soil particles. The degree and strength of As retention by soil constituents may vary greatly with time. The present authors hypothesize that aging results in reduced mobility of As thereby decreasing As release and its bioavailability. The present study is aimed at evaluating the effect of aging on soil As fractionation and bioaccessibility in a temperature and humidity-controlled greenhouse setting. The design allowed the evaluation of dynamic interactions between soils, pesticides, water, and plants. Therefore, 4 soil types (Immokalee, Millhopper, Pahokee Muck, and Orelia) were selected based on their potential differences in As reactivity. The soils were amended with the pesticide Na arsenate at two rates. Rice was used as the test crop. Soil samples collected after different time periods (0, 6 months, 1 a and 3 a) were extracted for soil-As forms via a sequential extraction technique. Bioaccessible As was extracted via an in vitro gastrointestinal method. At time 0, most of the extractable As in soil was in the soluble form, resulting in high bioaccessibility. As expected, soluble and exchangeable fractions decreased with time for up to 6 months, but remained constant thereafter. After 3 a of soil–pesticide equilibration, As bioaccessibility was still high in all the soils except for the Pahokee Muck. No significant difference in As bioaccessibility was observed between the soils. Arsenic was present predominantly as As(V) with 5–10% of the total dissolved As being present as As(III). Data obtained suggest that although aging had an impact on the geochemical forms, gastric pH was the sole important factor effecting As bioaccessibility. 相似文献
6.
Rupali S. Patgaonkar D. Ilangovan P. Vethamony M.T. Babu S. Jayakumar M.D. Rajagopal 《Ocean Engineering》2007,34(3-4):638-643
The Jatadharmohan creek lies between Mahanadi and Devi Rivers along the Orissa coast and it is separated from the sea by an elongated sand spit. It was proposed to mine a volume of 15×106 m3 of sand from the creek for land filling, but maintaining the spit intact. For this, the stability of sand spit is studied with different criteria. The results confirm that the creek mouth is a near permanent zone of deposition. The model results obtained for various depth scenarios show that the magnitude of currents would increase considerably when depth is increased by 7.0 m and marginally for further increase in depth by 10.0 m. Accordingly, a dredging scheme has to be designed without affecting the spit stability. Considering the existing hydrodynamics in the creek system, it is recommended that a bed slope of 1:6 (9.5°) be maintained during dredging, which is much less than 13.75°—the evaluated critical slope at the site when seepage flow is parallel to the bed slope. It is observed during monitoring that the creek is very productive, and the sand spit is totally intact. 相似文献
7.
A 2D Hydrodynamic-Particle Analysis model was applied to the Gulf of Kachchh (GoK) to estimate the residence time of pollutants. The tidal currents in the Gulf have a strong E-W component, which prevents the material in the north being transported towards south. In the regions situated very close to the open boundary, where the GoK waters exchange freely with the northern Arabian Sea, dilution takes place rapidly with the incoming waters and hence, the residence time is on the order of 1 day. Influence of eddies and a dynamic barrier across the Sikka-Mundra section on the residence time is apparent. Eastern GoK shows a relatively large residence time, on the order of 2-4 days, warranting caution while releasing industrial wastes in the northeastern Gulf. The region around location-5 behaves like a bay; the dissolved matter gets trapped in this bay and the residence time increases by 3-4 days. 相似文献
8.
Ocean Dynamics - A coupled numerical model is developed based on the spectral element method (SEM) and boundary element method (BEM) to predict the characteristics of tsunami wave response on... 相似文献
9.
Spectral and statistical wave parameters obtained from the measured time series wave data off Paradip, east coast of India
during May 1996–January 1997 were analysed along with MIKE 21 spectral wave model (SW) results. Statistical wave parameters
and directional wave energy spectra distinctly separate out the wave conditions that prevailed off Paradip in the monsoon,
fair weather and extreme weather events during the above period. Frequency-energy spectra during extreme events are single
peaked, and the maximum energy distribution is in a narrow frequency band with an average directional spreading of 20°. Spectra
for other seasons are multi-peaked, and energy is distributed over a wide range of frequencies and directions. The NCEP re-analysis
winds were used in the model, and the results clearly bring out the wave features during depressions. The simulated wave parameters
reasonably show good match with the measurements. For example, the correlation coefficient between the measured and modelled
significant wave height is 0.87 and the bias −0.25. 相似文献
10.
Celestial-mechanical computations show that, even stronger than for Earth, Mars is subject to Milankovi? cycles, that is, quasi-periodic variations of the orbital parameters obliquity, eccentricity and precession. Consequently, solar insolation varies on time-scales of 104-105 years. It has long been supposed that this entails climatic cycles like the terrestrial glacial-interglacial cycles. This hypothesis is supported by the light-dark layered deposits of the north- and south-polar caps indicating a strongly varying dust content of the ice due to varying climate conditions in the past. This study aims at simulating the dynamic and thermodynamic evolution of the north-polar cap (NPC) of Mars with the ice-sheet model SICOPOLIS. The boundary conditions of surface accumulation, ablation and temperature are derived directly from the solar-insolation history by applying the newly developed model MAIC. We consider steady-state scenarios under present climate conditions as well as transient scenarios over climatic cycles. It is found that the NPC is most likely not in steady state with the present climate. The topography of the NPC is mainly controlled by the history of the surface mass balance. Ice flow, which is of the order of , plays only a minor role. In order to build up the present cap during the last five million years of relatively low obliquities, a present accumulation rate of water equiv a−1 is required. Computed basal temperatures are far below pressure melting for all simulations and all times. 相似文献