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High-resolution oxygen-isotope records of benthic ostracods and molluscs from Ammersee, southern Germany, show high-frequency climatic changes during the last deglaciation and parallel in great detail published faunal and floral variations reconstructed from Norwegian Sea sediments and isotope variations in Greenland ice cores. The marine and the terrestrial records give evidence of a synchronous late glacial climatic development in Greenland, NW- and Mid-Europe. However,14C-ages of the supraregional climatic events and of two tephra layers in the marine sediments of the northeastern Atlantic Ocean are significantly older than the14C-ages of the corresponding horizons on land. These differences strongly suggest that major short-term events have affected the exchangeable carbon on earth during the dramatic environmental changes related to the deglaciation and in particular have affected the CO2-distribution within the ocean and between ocean and atmosphere. Dating methods independent of climatic variations and of the global carbon budget should be given priority to refine the timescales of the marine and atmospheric processes during the last deglaciation.This is the fourth paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr. A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.  相似文献   
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Measurements of tritium and 18O concentrations in precipitation and runoff were used to provide further insight into the groundwater storage properties of the Wimbachtal Valley, a catchment area of 33.4 km2, extending between 636 and 2713 m a.s.l. in the Berchtesgaden Alps. The catchment includes three aquifer types: a dominant porous aquifer; a fractured dolomite; a karstic limestone aquifer. Employing a simple hydrological model, information about mean transit times of environmental tracers is derived for the groundwater runoff component and several karst springs from the application of the exponential and dispersion flow models to the isotopic input and output data. The mean transit times calculated from a dispersion model with transit times of 4.1 years for 18O and 4.2 years for tritium, which agree well, allow calculation of total (mobile + stagnant) groundwater storage volume, which is equivalent to 6.6 m of water depth. Direct runoff appears negligible as in many other cases.  相似文献   
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The particle size distribution and incidence of spherical, glassy particles commonly found in lunar samples has been determined from Apollo 12 surface samples of fine dust. Some of the spherical particles are hollow and this aspect has also been investigated. The atomisation process by which these particles were probably formed is described and the known physics of this phenomenon is used to define the conditions under which the particles were formed. Other physical limitations are also discussed in order to explain the measured particle size.  相似文献   
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For our ancestors, oil seeps were both a fascination and a resource but as the planet's reserves of high quality low density oil becomes increasingly depleted, so there is now a renewed interest in heavier,biodegraded oils such as those encountered in terrestrial seeps. One such seep is Pitch Lake in the Caribbean island of Trinidad, which is the largest natural deposit of asphalt in the world. At the northern end of the Caribbean, oil emerges along a tectonic contact on the island on Cuba. The sources of the oils from these seeps are relatively recent and both are subject to intense weathering due to the tropical conditions. When analysed by gas chromatography(GC) both oils appear as unresolved complex mixtures(UCM) and show a very high degree of biodegradation thus presenting an analytical challenge. In this case study, these two Caribbean seep oils were analysed by comprehensive two dimensional GC with time of flight mass spectrometry(GC×GC-TOFMS) to expose many thousands of the individual compounds that comprise the UCM. The high chromatographic resolution of the GC×GC-TOFMS produced good quality mass spectra allowing many compounds including molecular fossil ‘biomarkers' to be identified. Compound classes included diamondoid hydrocarbons, demethylated hopanes and secohopanes, mono-and tri-aromatic steroids. D-ring aromatised structures of the 8,14-seco-hopanes,including demethylated forms were present in both oils but further demethylation, probably at position C-25 during biodegradation, was only observed in the Pitch Lake oil. Many polycyclic aromatic hydrocarbons(PAHs) were absent although the fungal-derived pentacyclic PAH perylene was present in both oils. The presence of the angiosperm biomarker lupane in the Pitch Lake oil constrained the age to the Late Cretaceous. The higher degree of biodegradation observed in the Cuban oil was likely due to relatively slow anaerobic processes whereas oil within Pitch Lake was probably subject to additional more rapid aerobic metabolism within the lake.  相似文献   
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A charged particle detector array flown on a high altitude balloon has detected and measured some 3×104 cosmic-ray nuclei withZ12. The charge spectrum at the top of the atmosphere for nuclei withE>650 MeV·n–1 and the energy spectrum for 650E<1800 MeV·n–1 are reported and compared with previously published results. The charge spectrum at the source of cosmic rays is deduced from these data and compared with a recent compilation of galactic abundances.  相似文献   
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Acute sediment toxicity tests do not test key life stage events such as moulting and reproduction and therefore do not reveal the longer-term effects of contaminant exposure. A laboratory method is described for determining the chronic toxicity of contaminants associated with whole sediments. The test is conducted using neonates of the estuarine amphipod Corophium volutator at 15 degrees C, salinity 25 psu and a 12 h light:12 h dark photoperiod. The endpoints are survival and growth after 28 days and survival, growth and reproduction of amphipods upon termination of test i.e. reproduction within all control vessels (ca 75 days). The sediment chronic toxicity test was used to investigate the effects of sediments spiked with environmentally relevant preparations of slightly weathered Alaskan North Slope crude oil, including a water-accommodated-fraction (WAF) and a chemically-dispersed (Corexit 9527) WAF. Sediment oil concentrations were quantified using ultra-violet fluorescence. The amphipods exposed to chemically dispersed oil had higher mortality and lower growth rates than control-, Corexit 9527- and WAF-exposed organisms, resulting in reduced reproduction. The described method supplements the standard acute sediment test and would be particularly useful when long-term ecological effects are suspected but acute tests reveal no significant mortality. The sediment chronic test reported herein has shown that sediment that was not evidently toxic during 10-day acute tests could have population-level effects on sediment-dwelling amphipods.  相似文献   
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With the explosive growth of Uber and other mobility service providers, their influences on urban mobility have attracted attention from both researchers and policy circles alike, yet few quantitative studies have been conducted on the topic. Using Uber pickup data in New York City in 2014, this article investigates the spatiotemporal relationship between Uber and public transit using buffer analysis and spatial cross-correlation analysis and assesses Uber’s impact on urban transportation equity with the Gini coefficient and correlation analysis. Our results confirm previous arguments that Uber both complements and competes with public transit, but competition is more prevalent in New York City. Specifically, Uber competes with public transit during most hours of the day and in areas with good public transit coverage, whereas it complements public transit at midnight and in places with insufficient public transit services. The distribution of Uber services is highly unequal, and Uber’s role in improving transport equity is insignificant. Correlation analysis shows that there tend to be fewer Uber pickups in low-income areas, which diverges from previous studies suggesting that Uber serves low-income areas well. In addition, a weak negative correlation is detected between the number of Uber pickups and the percentage of minorities.  相似文献   
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