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A hydrogeologic model that has been used by many researchers and consultants to describe an area of South Lake Tahoe, California, USA impacted by MTBE contamination describes a relatively homogeneous unconfined aquifer comprised of poorly sorted glacial outwash deposits, within which water-supply wells are able to exert significant alteration in natural groundwater flow. A re-examination of the area’s hydrogeology is presented, which supports a layered heterogeneous aquifer system constructed of alternating fine and coarser-grained glacio-lacustrine depositional units. This re-evaluation was accomplished through a review of lithologic logs across an area of approximately 1 km2, combined with observations of significant hydraulic head differences and knowledge of the depositional environments controlled by Pleistocene Lake Tahoe high stands. Many of the fine-grained units observed at depths from 6 to 15 m, although relatively thin, are generally continuous and serve as significant barriers to groundwater flow. The vertical migration of contamination across these fine-grained units to deeper groundwaters was facilitated by cross-screened monitoring wells installed as part of site investigation activities. This conclusion highlights the importance of geologic characterization and proper monitoring well construction at contaminated site investigations.
Electronic supplementary material   The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Michaela NovakEmail:
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3.
 Two long time series were analysed: the C01 series of the International Earth Rotation Service and the pole series obtained by re-analysis of the classical astronomical observations using the HIPPARCOS reference frame. The linear drift of the pole was determined to be 3.31 ± 0.05 milliarcseconds/year towards 76.1 ± 0.80° west longitude. For the least-squares fit the a priori correlations between simultaneous pole coordinates x p , y p were taken into account, and the weighting function was calculated by estimating empirical variance components. The decadal variations of the pole path were investigated by Fourier and wavelet analysis. Using sliding windows, the periods and amplitudes of the Chandler wobble and annual wobble were determined. Typical periods in the variable Chandler wobble and annual wobble parameters were obtained from wavelet analyses. Received: 21 January 2000 / Accepted: 28 August 2000  相似文献   
4.
From mica fission-track maps the serpentinized and weathered portions of four ultramafic rocks from oceanic ridge systems contained 0.5 to 2.4 ppm U compared to only 2.5 ppb in clinopyroxene, 0.6 ppb in chromite and less than 7.0 ppb in olivine. Orthopyroxene grains contained 0.4 ppb U which is three orders of magnitude lower than had previously been reported.Long thin tracks from (n, α) reactions with boron were recorded in cellulose nitrate plastic and were counted like fission tracks. The track density from boron was 2×104 times higher than that from uranium fission alone. Boron in serpentine was variable on a 50-μm scale attaining 155 ppm concentrations. Orthopyroxene grains, in contrast, had maximum concentrations of 0.8 ppm.Most of the uranium and boron in the rocks is believed to have been introduced during serpentinization. From known crystal-melt partitioning ratios the uranium and boron distributions are consistent with the ultramafic rocks being cumulates or residues from partial melting events.  相似文献   
5.
The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.  相似文献   
6.
Besides Pb and U loss and mixing of crystals of different age, U gain is considered a possible cause of discordant U-Pb ages of zircons. However, whether U gain without new zircon growth occurs in nature had not been proven, so far. In order to test this possibility, two detrital zircon populations were studied for which the absence of later zircon overgrowth after deposition could be demonstrated. The samples were separated from a metaquartzite near a large pegmatite body and from metaquartzite inclusions found in the pegmatite (Martell Valley, Italian Alps). The distribution of neutron-induced fission tracks reveals distinct accumulation of U in the rims of more than 90% of the zircon grains of the inclusions (total U in the crystals: 540–850 ppm), whereas in the country rock only some of the grains show similar but weaker patterns (total U: 155–320 ppm). From the isotopic data and from additional U-Pb and Rb-Sr analyses of minerals and whole-rock samples of the pegmatite, the marginal accumulation and the higher concentration of U in the zircon grains of the inclusions are interpreted as the result of episodic U gain during the intrusion of the pegmatite and/or during a later metamorphism. From the concentration levels of common Pb, an addition of Pb - and possibly other elements - to the zircon grains is inferred.  相似文献   
7.
The Celestial Reference System (CRS) is currently realized only by Very Long Baseline Interferometry (VLBI) because it is the space geodetic technique that enables observations in that frame. In contrast, the Terrestrial Reference System (TRS) is realized by means of the combination of four space geodetic techniques: Global Navigation Satellite System (GNSS), VLBI, Satellite Laser Ranging (SLR), and Doppler Orbitography and Radiopositioning Integrated by Satellite. The Earth orientation parameters (EOP) are the link between the two types of systems, CRS and TRS. The EOP series of the International Earth Rotation and Reference Systems Service were combined of specifically selected series from various analysis centers. Other EOP series were generated by a simultaneous estimation together with the TRF while the CRF was fixed. Those computation approaches entail inherent inconsistencies between TRF, EOP, and CRF, also because the input data sets are different. A combined normal equation (NEQ) system, which consists of all the parameters, i.e., TRF, EOP, and CRF, would overcome such an inconsistency. In this paper, we simultaneously estimate TRF, EOP, and CRF from an inter-technique combined NEQ using the latest GNSS, VLBI, and SLR data (2005–2015). The results show that the selection of local ties is most critical to the TRF. The combination of pole coordinates is beneficial for the CRF, whereas the combination of \(\varDelta \hbox {UT1}\) results in clear rotations of the estimated CRF. However, the standard deviations of the EOP and the CRF improve by the inter-technique combination which indicates the benefits of a common estimation of all parameters. It became evident that the common determination of TRF, EOP, and CRF systematically influences future ICRF computations at the level of several \(\upmu \)as. Moreover, the CRF is influenced by up to \(50~\upmu \)as if the station coordinates and EOP are dominated by the satellite techniques.  相似文献   
8.
Bycatch mortality in net fisheries was the major reason for the decline of the endangered smalltooth sawfish, Pristis pectinata, in the United States. These fisheries have been reduced or eliminated in some states including Florida--where most smalltooth sawfish are currently found in the United States. To determine whether other factors are still affecting this species, we obtained non-net fishery entanglement, injury, and mortality data by soliciting information from anyone who may have encountered this species. Smalltooth sawfish were damaged by marine pollution (e.g., polyvinyl chloride pipe, monofilament line, non-monofilament line) and injured by humans. Examples of injuries caused directly by humans include removal of rostra, shooting an individual with a powerhead, and shooting another with arrows. Many people are aware that the smalltooth sawfish is protected by state and federal laws, but some are still not aware of (or willing to accept) this status. The impacts of marine pollution and injuries directly caused by humans on this endangered species can be ameliorated by incorporating fisher education into the conservation and management processes.  相似文献   
9.
This paper studies the connection between the subdaily model for polar motion used in the processing of very long baseline interferometry (VLBI) observations and the estimated nutation offsets. By convention accepted by the International Earth Rotation Service, the subdaily model for polar motion recommended for routine processing of geodetic observations does not contain any daily retrograde terms due to their one-to-one correlation with the nutation. Nevertheless, for a 24-h VLBI solution a part of the signal contained in the polar motion given by the used subdaily model is numerically mistaken for a retrograde daily sidereal signal. This fictitious retrograde daily signal contributes to the estimated nutation, leading to systematic differences between the nutation offsets from VLBI solutions computed with different subdaily polar motion models. We demonstrate this effect using solutions for all suitable 24-h VLBI sessions over a time span of 11 years (2000–2011). By changing the amplitudes of one tidal term in the underlying subdaily model for polar motion and comparing the estimated parameters to the solutions computed with the unchanged subdaily model, the paper shows and explains theoretically the effects produced by the individual subdaily terms on the VLBI nutation estimates.  相似文献   
10.
Ocean Dynamics - With the continued rise in global mean sea level, operational predictions of tidal height and total water levels have become crucial for accurate estimations and understanding of...  相似文献   
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