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Twenty crude oils from Paleozoic reservoirs in the Big Horn Basin. Wyoming were fractionated into light hydrocarbons, saturates, monoaromatics. diaromatics, polyaromatics-and-polars. and asphaltenes. Amounts and isotopic composition of each fraction were found to be internally consistent with the degree of maturation of the oil. confirming the established single source origin for these oils. A variation of approximately three per mil in the carbon isotopic composition of the whole oil and individual fraction was explained as being caused by maturation. The isotope-type-curves for these oils, the variations in isotopic composition as a function of compound group-type, were not found to be as simple as commonly believed. Other alteration processes, such as migration and deasphalting, might have influenced the pattern of the isotope distributions among fractions. The conservative nature of mass balance and subsequent isotope flows among various fractions of crude oil showed that the maturation of crude oil consists of consecutive processes leading from larger and more polar components into smaller and less polar components culminating in natural gas. Calculations were made to project the amount of condensates associated with the crude oils, and the amount of natural gas which had been generated from crude oils of a given maturity.  相似文献   
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Populations of the American horseshoe crab (Limulus polyphemus) differ in broad areas of their biology. We observed a non-harvested, marked Florida Gulf coast population during their spring spawning (March–May) in 11 years across a 17-year period (1992–2009). Long-term changes occurred in the number of spawning pairs: the population was stable from 1992 to 2000 but increased markedly after 2000. Short-term variation in numbers of spawning pairs, unpaired females, unpaired males, and operational sex ratios was explained by changes over the season and during each week of spring tides and by differences in actual (not predicted) maximum high tide height. Wind direction strongly affected tidal inundation and the number of spawning horseshoe crabs. Tagging individuals revealed that females returned to the nesting beach less often than males and most females were re-sighted only within 1 week of spring tides. No animals were seen across more than 6 years. Implications for management are discussed.  相似文献   
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Journal of Seismology - Site response is a critical consideration when assessing earthquake hazards. Site characterization is key to understanding site effects as influenced by seismic site...  相似文献   
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Seafloor acoustic and photographic imagery combined with high- resolution bathymetry are used to investigate the geologic and tectonic relations between active and relict zones of hydrothermal venting in the TAG (Trans-Atlantic Geotraverse) hydrothermal field at 26°08N on the Mid-Atlantic Ridge (MAR). The TAG field consists of a large, currently active, high-temperature mound, two relict zones (the Alvin and Mir zones), and an active low-temperature zone. The active mound and the Alvin relict zone lie along a series of closely-spaced, axis-parallel (NNE-trending) faults in an area of active extension east of the neovolcanic zone. The Alvin zone extends for 2.5 km along these faults from the valley floor onto the eastern wall, and consists of at least five mounds identified using DSL-120 sidescan sonar and bathymetric data. The existence of sulfide structures on most of these mounds is verified with near-bottom electronic still camera (ESC) images from the Argo-II deep-towed vehicle, and is confirmed in at least one case with collected samples. Two of these mounds were previously unidentified. The existence of these mounds extends the length of the Alvin zone by ~0.5 km to the south. Much of the Alvin relict zone appears to be buried by debris from a large mass wasting event on the eastern wall of the median valley. The Mir zone, located on normal fault blocks of the eastern valley wall, cannot be clearly identified in the sidescan data and no structural connections from it to the active mound or Alvin zone can be discerned. The active mound is located at the intersection of an older oblique fault set with the younger axis- parallel faults which extend into the Alvin relict zone, and no fresh volcanics are observed in the vicinity of the mound. The fact that both the active mound and the Alvin relict zone lie along the same set of active, axis-parallel faults suggests that the faults may be a major control on the location of hydrothermal activity by providing pathways for fluid flow from a heat source at the ridge axis.  相似文献   
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The field of ocean geochemistry has recently been expanded to include in situ laser Raman spectroscopic measurements in the deep ocean. While this technique has proved to be successful for transparent targets, such as fluids and gases, difficulty exists in using deep submergence vehicle manipulators to position and control the very small laser spot with respect to opaque samples of interest, such as many rocks, minerals, bacterial mats, and seafloor gas hydrates. We have developed, tested, and successfully deployed by remotely operated vehicle (ROV) a precision underwater positioner (PUP) which provides the stability and precision movement required to perform spectroscopic measurements using the Deep Ocean Raman In situ Spectrometer (DORISS) instrument on opaque targets in the deep ocean for geochemical research. The positioner is also adaptable to other sensors, such as electrodes, which require precise control and positioning on the seafloor. PUP is capable of translating the DORISS optical head with a precision of 0.1 mm in three dimensions over a range of at least 15 cm, at depths up to 4000 m, and under the normal range of oceanic conditions (T, P, current velocity). The positioner is controlled, and spectra are obtained, in real time via Ethernet by scientists aboard the surface vessel. This capability has allowed us to acquire high quality Raman spectra of targets such as rocks, shells, and gas hydrates on the seafloor, including the ability to scan the laser spot across a rock surface in sub-millimeter increments to identify the constituent mineral grains. These developments have greatly enhanced the ability to obtain in situ Raman spectra on the seafloor from an enormous range of specimens.  相似文献   
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