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Geothermobarometry using continuous equilibria in pelitic rocks of the central and northeastern Wadi Kid areas, Sinai, yields pressure estimates of 320 MPa (3.2 kbar) and temperature estimates of 565° C and >620° C for staurolite-andalusite zone assemblages and anatectic rocks, respectively. This corresponds to geothermal gradients of 47° C/km and 50° C/km. TheseP-T conditions are shown to be compatible with burial under a volcanic cover. The principal heat source for high-grade metamorphism and anatexis is thought to be rising magmatic diapirs. Uplift was relatively slow and the final stages of heating and early stages of cooling probably occurred isobarically. The data imply a high heat flow regime for the Pan-African event in Sinai.  相似文献   
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The major advantage of the oxygen in phosphate isotope paleothermometry is that it is a system which records temperatures with great sensitivity while bone (and teeth) building organisms are alive, and the record is nearly perfectly preserved after death. Fish from seven water bodies of different temperatures (3–23°C) and different δ18O (values ?16 to +3) of the water were analysed. The δ18O values of the analysed PO4 vary from 6 to 25. The system passed the following tests: (a) the temperatures deduced from isotopic analyses of the sequence of fish from Lake Baikal are in good agreement with the temperatures measured in the thermally stratified lake; (b) the isotopic composition of fish bone phosphate is not influenced by the isotopic composition of the phosphate which is fed to the fish, but only by temperature and water composition.Isotopic analysis of fossil fish in combination with analysis of mammal bones should be a useful tool in deciphering continental paleoclimates.  相似文献   
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The analysis of micro-inclusions in fibrous diamonds from the Diavik mine, Canada revealed the presence of high density fluids (HDFs) that span a continuous compositional range between carbonatitic and saline end-members. The carbonatitic end-member is rich in Na, Ca, Mg, Fe, Ba and carbonate; the saline one is rich in K, Cl and water. In molar proportions, the composition of the saline end-member is: K38Na7.7Ca1.8Mg1.6Fe1.5Ba1.9SiO3.1Cl46(CO3)5.5(H2O)56 and that of the carbonatitic end member is: K15Na21Ca6.7Mg8.1Fe6.2Ba5.7Si4.8Ti1.4Al1.9O17Cl29(CO3)29(H2O)29. The micro-inclusions in one diamond span a narrow range between a silicic end-member (rich in Si, K and water) and a carbonatitic one (rich in Mg, Ca, Fe and carbonate). Its average composition is: K26Na5.5Ca13.8Mg8.3Fe9.6Ba0.9P2.5Si25Ti1.6Al3.8Cl2.5O81(CO3)29(H2O)78. Thus, the Diavik diamonds span most of the known compositional range for fluids trapped in diamonds. Based on these data and previous analyses of fluids trapped in diamonds, we discuss possible models for the evolution of diamond-forming fluids. The most plausible model is where carbonatitic-HDFs are parental to all the other compositions. They evolve by fractionation of divalentions- and alkali-carbonates and by immiscible separation into saline- and silicic-HDFs. Each phase continues to evolve separately, crystallizing carbonates, diamond, and accessory silicates, phosphates, halides and more of the immiscible phase. Other processes, like the mixing of evolved fluids with fresh parental carbonatitic fluids, or metasomatic interactions with the wallrock also play a role in the evolution of the HDFs. We also propose that the parental carbonatitic-HDF evolves through fractional crystallization of an alkali-rich, low degree melt that is similar to the high pressure parental melts of kimberlites or lamproites.  相似文献   
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Summary The design of adaptive observations strategies must account for the particular properties of the data assimilation method. A new adjoint sensitivity approach to the targeted observations problem is proposed in the context of four-dimensional variational data assimilation (4D-Var). The method is based on a periodic update of the adjoint sensitivity field that takes into account the interaction between time distributed adaptive and routine observations. Information provided by all previously located observations is used to identify best locations for new targeted observations. Adaptive observations at distinct instants in time are selected in a sequential manner such that the method is only suboptimal. The selection algorithm proceeds backward in time and requires only one additional adjoint model integration in the assimilation window. Therefore, the method is very efficient and is suitable for practical applications. A comparative performance analysis is presented using the traditional adjoint sensitivity method as well as the total energy singular vectors technique as alternative adaptive strategies. Numerical experiments are performed in the twin experiments framework using a two-dimensional global shallow water model in spherical coordinates and an explicit Turkel-Zwas discretization scheme. Data from a NASA 500mb analysis valid for 00Z 16 Mar 2001 6h obtained with the GEOS-3 model was used to specify the geopotential height at the initial time and the initial velocities were obtained from a geostrophic balance. Numerical results show that the new adaptive observations approach is a promising method for targeted observations and its implementation is feasible for large scale atmospheric models.  相似文献   
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We examine the physics of growth of water bubbles in highly viscous melts. During the initial stages, diffusive mass transfer of water into the bubble keeps the internal pressure in the bubbles close to the initial pressure at nucleation. Growth is controlled by melt viscosity and supersaturation pressure and radial growth under constant pressure is approximately exponential. At later stages, internal pressure falls, radial growth decelerates and follows the square-root of time. At this stage it is controlled by diffusion. The time of transition between the two stages is controlled by the decompression, melt viscosity and the Peclet number of the system. The model closely fit experimental data of bubble growth in viscous melts with low water content. Close fit is also obtained for new experiments at high supersaturation, high Peclet numbers, and high, variable viscosity. Near surface, degassed, silicic melts are viscous enough, so that viscosity-controlled growth may last for very long times. Using the model, we demonstrate that bubbles which nucleate shortly before fragmentation cannot grow fast enough to be important during fragmentation. We suggest that tiny bubbles observed in melt pockets between large bubbles in pumice represent a second nucleation event shortly before or after fragmentation. The presence of such bubbles is an indicator of the conditions at fragmentation. The water content of lavas extruded at lava domes is a key factor in their evolution. Melts of low water content (<0.2 wt%) are too viscid and bubbles nucleated in them will not grow to an appreciable size. Bubbles may grow in melts with 0.4 wt% water. The internal pressure in such bubbles may be preserved for days and the energy stored in the bubbles may be important during the disintegration of dome rocks and the formation of pyroclastic flows.  相似文献   
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