Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria     

Brent L. Lewis  Pamela D. Holt  Steven W. Taylor  Steven W. Wilhelm  Charles G. Trick  Alison Butler  George W. Luther  III 《Marine Chemistry》1995,50(1-4)

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.  相似文献   

Whale conservation     

Sidney J. Holt 《Marine Policy》1982,6(4):350-351

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An integrated global model of present-day plate motions and plate boundary deformation   总被引：18，自引：0，他引：18  

Corné Kreemer  William E. Holt  A. John Haines 《Geophysical Journal International》2003,154(1):8-34

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The geoid EDIN2000 and mean sea surface topography around the British Isles   总被引：2，自引：0，他引：2  

Roger Hipkin  Keith Haines  Ciaran Beggan  Richard Bingley  Fabrice Hernandez  Jason Holt  Trevor Baker 《Geophysical Journal International》2004,157(2):565-577

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The influence of weather extremes on the spatial correlation of corn yields     

Jesse B. Tack  Matthew T. Holt 《Climatic change》2016,134(1-2):299-309

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Barred Spirals,Double Galaxies and massive Halos1     

Sidney Van Den Bergh 《Astronomische Nachrichten》1979,300(5):225-228

It is shown that there is no significant dependence of the frequency with which barred spirals occur on environment. Therefore, the difference between normal and barred spirals must be largely due to initial conditions. The excess of early type galaxie (in particular ellipticals and SO's) among the statistically selected binary samples is probably caused by a contamination by cluster members and will therefore result in a systematic overestimate of the masses of binary galaxies. The large fraction of multiple first-ranked galaxies found in rich clusters of BAUTZ -MORGAN type I is surprising in view of tidal effects and dynamical friction, which should lead to the destruction of such massive binary systems on a time scale much shorter than the age of the Universe.  相似文献   

The tidal range energy potential of the West Coast of the United Kingdom     

R. Burrows  I.A. Walkington  N.C. Yates  T.S. Hedges  J. Wolf  J. Holt 《Applied Ocean Research》2009,31(4):229-238

With concerns mounting over the UK’s energy future and the effects of climate change, it will soon become paramount that all viable sources of renewable energy are fully exploited. This study has examined the scope for reliable and fully predictable tidal electricity generation from the conjunctive operation of 5 major estuary barrages on the West Coast of the UK in an attempt to establish the potential scale of the extractable resources. Two levels of investigation have been undertaken: simple 0-D (‘two-tank’) modelling of barrage energy generation under different operational modes, using the hydraulic characteristics of turbine performance; and 2-D modelling of tidal hydrodynamics over a wide sea area in a computational grid incorporating the barrages with turbines and sluices. It has been demonstrated that more than 33TWh per year of electricity should be attainable, from 22GW of installed capacity, this representing close to 10% of present UK demand.  相似文献   

Can marine fisheries and aquaculture meet fish demand from a growing human population in a changing climate?     

Gorka Merino  Manuel Barange  Julia L. Blanchard  James Harle  Robert Holmes  Icarus Allen  Edward H. Allison  Marie Caroline Badjeck  Nicholas K. Dulvy  Jason Holt  Simon Jennings  Christian Mullon  Lynda D. Rodwell 《Global Environmental Change》2012,22(4):795-806

Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products.  相似文献   

Aircraft and ship observations of the mean structure of the marine boundary layer over the Arabian Sea during MONEX 79     

T. Holt  S. Sethuraman 《Boundary-Layer Meteorology》1985,33(3):259-282

Analysis of the mean wind, equivalent potential temperature and virtual potential temperature profiles observed by the National Center for Atmospheric Research (NCAR) Electra aircraft and obtained from dropwindsondes and ship-launched radiosondes were made in conjunction with synoptic observations to study the structure of the monsoon boundary layer over the Arabian Sea during MONEX 79. Comparison of mean profiles indicates the monsoon boundary layer to be much different from the trade wind boundary layer. Results confirm the existence of a boundary-layer jet known as East African or Somali Jet. Regions of multiple cloud layers at roughly the height of the capping inversion layer were associated with the jet. Regions in which a more well-mixed layer was observed showed a jet structure depressed in height. A free-jet surface-layer model appears to describe the mean wind structure of this jet observed during the present study and by others. An approximate balance of forces was found in the monsoon boundary layer between friction, advective acceleration, Coriolis and pressure gradient forces. Friction and advective acceleration terms were significant in the lower levels of the boundary layer. Forces in a typical trade wind boundary layer were found to be approximately one order of magnitude smaller than those observed in the monsoon boundary layer.  相似文献   

A study of mean boundary-layer structures over the Arabian Sea and the Bay of Bengal during active and break monsoon periods     

Teddy Holt  Sethu Raman 《Boundary-Layer Meteorology》1987,38(1-2):73-94

Observations from research ships which took part in the Indo-Soviet Monsoon Experiment of 1977 (MONSOON 77) and the International Monsoon Experiments (MONEX 79) over the central Arabian Sea and the north central Bay of Bengal were analyzed to study the mean wind and temperature structure of the monsoon boundary layer during active and break conditions. Mean profiles of wind speed and direction along with virtual potential temperature obtained by averaging data from several research ships during 1977 and 1979 indicate that onset conditions were associated with substantial increases in wind speed over the Arabian Sea and a shift to strong southwest flow. Monsoon onset was also characterized by near-neutral to slightly unstable temperature profiles in the lowest kilometer. Break conditions in 1977 in which the monsoon trough moved northward and substantial (5 mb) pressure rises were noted over the Arabian Sea show wind speeds typically decreasing from approximately 18 m s^–1 during active conditions to roughly 8 m s ^–1. Temperature profiles during break conditions are similar to those observed in pre-monsoon conditions in that the boundary layer is observed to be generally much more stable up to 900 mb. Above 900 mb, profiles of virtual potential temperature show little variation.Analysis of latent and sensible heat fluxes during June 1977 calculated by the bulk aerodynamic method indicates values of latent heat flux during active conditions to be roughly two to three times larger than those during break conditions. Sensible heat flux shows an increase from approximately 20 to 80 W m ^–1 during the onset of the monsoon. Surface fluxes of water vapor indicate the importance of water vapor transport over the ship observation region in the central Arabian Sea during active conditions. Onset of the monsoon over the Arabian Sea is accompanied by an increase in the surface moisture flux by a factor of about two. Time histories of precipitable water show decreases of approximately 15% from active to break periods.  相似文献