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Elemental mobility based on major element geochemistry from 58 horizons related to six paleosols profiles in a typical Miocene — Pliocene Siwalik fluvial sequence in the NW Himalaya has been reported here. The paleosols developed over felsic parent material of fine to medium grained sandstone indicate notable enrichment of sesquioxides (Al2O3 = 29 % and Fe2O3 = 54 %) depicting significant leaching and dissolution. The depletion of base cations (mean wt% of Na2O = 0.24; CaO = 0.51) and SiO2 (mean wt% = 63.6) in the pedogenic layers and its enrichment in the parental material (mean wt% of Na2O = 0.44; CaO = 1.3; SiO2 = 70.1) shows a good gradient of elemental mobility due to pedogenesis. Bivariate plots of the base ratios (Na2O/K2O, CaO/K2O, and MgO/K2O) vs. Al2O3 reveal independent distribution for parent material, pedogenic horizons and the incipient zone indicating the gradual addition/removal of immobile/mobile elements with varying pedogenesis. Discontinuous and segmented pattern of the geochemical parameters enables discrimination of multiple pedogenic episodes and recognition of soil welding processes in the multistorey composite paleosols. We also test the applicability of the geochemical climofunctions: the Mean Annual Precipitation (MAP) and Mean Annual Temperature (MAT); that demands more data for calibration in the Siwalik paleosols.  相似文献   
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Investigation for high yielding water wells in the khondalitic terrain (graneti ferrous silliminite gnesiss) is mostly faced with the problem of identification of the extent of the depth of kaolinisation of the aquifer. The traditional Vertical Electrical Sounding survey, Seismic Refraction survey and Very Low Frequency Electromagnetic survey could not identify the kaolinisation of the aquifer in the present investigations. The Two Dimensional (2D) Resistivity and Induced Polarization (IP) Imaging surveys are attempted for the identification of kaolinised layer and depth of kaolinisation. Number of 2D Resistivity and IP Imaging profiles were conducted near Chipurupally in Vizianagaram district of Andhra Pradesh, India along successful and failed wells located within short distances. Resistivity and IP measurements were carried out using an ABEM SAS 4000 Terrameter. The resistivity and I.P. images have provided a clear view of the thickness of the highly weathered zone (kaolinised zone) at both successful and failed wells. The highly weathered zone is identified with the resistivity values below 25 ohm.m. The depth of highly weathered material at failed well is extended about 8–10 m more deeper than the successful wells at some places to as much as 20 m more deep at some other places. This extended deeper kaolinisation of the aquifer is responsible for failure of wells. Layers having resistivities between 25–65 Ohm.m are identified as aquifer layers which are composed of moderately weathered and fractured khondalitic suit of rocks (Garnti ferrous sillimanite/biotite gneiss). Layers with resistivities greater than 65 Ohm.m are interpreted to have basement characteristics belonging to the granite gneiss. Interestingly IP imaging has not provided any greater insights in delineating the kaolinistion of the aquifer when compared to resistivity Imaging, in fact resitivity imaging has shown greater depths of kaolinisation than IP Imaging.  相似文献   
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Hydrogeological and climatic effect on chemical behavior of groundwater along a climatic gradient is studied along a river basin. ‘Semi-arid’ (500–800 mm of mean annual rainfall), ‘sub-humid’ (800–1,200 mm/year) and ‘humid’ (1,200–1,500 mm/year) are the climatic zones chosen along the granito-gneissic plains of Kabini basin in South India for the present analysis. Data on groundwater chemistry is initially checked for its quality using NICB ratio (<±5 %), EC versus TZ+ (~0.85 correlation), EC versus TDS and EC versus TH analysis. Groundwater in the three climatic zones is ‘hard’ to ‘very hard’ in terms of Ca–Mg hardness. Polluted wells are identified (>40 % of pollution) and eliminated for the characterization. Piper’s diagram with mean concentrations indicates the evolution of CaNaHCO3 (semi-arid) from CaHCO3 (humid zone) along the climatic gradient. Carbonates dominate other anions and strong acids exceeded weak acids in the region. Mule Hole SEW, an experimental watershed in sub-humid zone, is characterized initially using hydrogeochemistry and is observed to be a replica of entire sub-humid zone (with 25 wells). Extension of the studies for the entire basin (120 wells) showed a chemical gradient along the climatic gradient with sub-humid zone bridging semi-arid and humid zones. Ca/Na molar ratio varies by more than 100 times from semi-arid to humid zones. Semi-arid zone is more silicaceous than sub-humid while humid zone is more carbonaceous (Ca/Cl ~14). Along the climatic gradient, groundwater is undersaturated (humid), saturated (sub-humid) and slightly supersaturated (semi-arid) with calcite and dolomite. Concentration–depth profiles are in support of the geological stratification i.e., ~18 m of saprolite and ~25 m of fracture rock with parent gneiss beneath. All the wells are classified into four groups based on groundwater fluctuations and further into ‘deep’ and ‘shallow’ based on the depth to groundwater. Higher the fluctuations, larger is its impact on groundwater chemistry. Actual seasonal patterns are identified using ‘recharge–discharge’ concept based on rainfall intensity instead of traditional monsoon–non-monsoon concept. Non-pumped wells have low Na/Cl and Ca/Cl ratios in recharge period than in discharge period (Dilution). Few other wells, which are subjected to pumping, still exhibit dilution chemistry though water level fluctuations are high due to annual recharge. Other wells which do not receive sufficient rainfall and are constantly pumped showed high concentrations in recharge period rather than in discharge period (Anti-dilution). In summary, recharge–discharge concept demarcates the pumped wells from natural deep wells thus, characterizing the basin.  相似文献   
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Landslides - Limited by the independence and its defects of each general software package, simultaneous analysis of runoff, seepage, and large-deformation analysis is still an inevitable challenge....  相似文献   
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This paper examines the difference in the geophysical and chemical characteristic of the volcanic ash and thermal fly ash to evaluate environmental pollution. Natural volcanic ash (VA) samples from Sagirelu, Cuddapah dist., Andhra Pradesh and thermal fly ash (FA) samples from the Thermal Power Station, Ennore, Chennai, were collected, analysed and compared. The particle sizes of the ash samples were determined using the laser particle size analyzer and the different surface morphological characters were studied using SEM analyses. The chemical components such as pH, major oxides, trace metals and mineral compositions were determined using pH metre, XRF and XRD methods. pH value of the volcanic ash varies from 8.5 to 8.9 indicating its alkalinity (8.5 to 9) in volcanic ash, while the thermal ash is neutral to mildly alkaline with pH varying from 6 to 7.5. Both the ash samples have higher concentration value in SiO2 (VA - 69.25%, FA - 46%) in major oxides and Cl (VA - 0.8%, FA - 0.1%) in trace elements. Quartz is the dominant mineral in both the types of ash, however, the volcanic ash has amorphous silica, while the fly ash contains crystalline quartz.  相似文献   
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海岸带是动态地区,由于众多因素,包括海平面的上升、波浪与洋流的类型、飓风乃至人类的影响,海岸地区经常受到变动。2004年12月26日巨大海啸席卷了堪雅库玛里至奥瓦利之间的海岸。当海浪冲上海滩时波高达30英尺。许多人因为巨浪的冲击和退浪的强力推拉而淹死在海里,许多村庄被毁。死亡总数超过300人,而且财产损失严重。海啸的规模与洋底移动的面积、移动距离是有关系的。该区显示为海成阶地、沙丘、滩脊、河口、洪积平原、海滩、红树林、准平原、高地、海蚀崖等等。我们试图通过现场在线勘查、政府记录以及采用遥感技术所做的海岸地貌研究等资料,通过海滩剖面测量和海岸环境的变化,进行海岸线动力学研究。文中也对主要的破坏予以认定。  相似文献   
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Mass concentration and mass size distribution of total (composite) aerosols near the surface are essential inputs needed in developing aerosol models for radiative forcing estimation as well as to infer the environment and air quality. Using extensive measurements onboard the oceanographic research vessel, Sagar Kanya, during its cruise SK223B in the second phase of the ocean segment of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB), the spatial distribution of the mass concentration and mass size distribution of near-surface aerosols are examined for the first time over the entire Arabian Sea, going as far as 58°E and 22°N, within a span of 26 days. In general, the mass concentrations (M T ) were found to be low with the mean value for the entire Arabian Sea being 16.7 ± 7 μg m?3; almost 1/2 of the values reported in some of the earlier campaigns. Coarse mode aerosols contributed, on an average, 58% to the total mass, even though at a few pockets accumulation mode contribution dominated. Spatially, significant variations were observed over central and northern Arabian Sea as well as close to the west coast of India. In central Arabian Sea, even though the M T was quite low, contribution ofs accumulation aerosols to the total mass concentration was greater than 50%. Effective radius, a parameter important in determining scattering properties of aerosol size distribution, varied between 0.07 and 0.4 μm with a mean value of 0.2 μm. Number size distributions, deduced from the mass size distributions, were approximated to inverse power-law form and the size indices (ν) were estimated. It was found to vary in the range 3.9 to 4.2 with a mean value of 4.0 for the entire oceanic region. Extinction coefficients, estimated using the number-size distributions, were well-correlated with the accumulation mode mass concentration with a correlation coefficient of 0.82.  相似文献   
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