Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

QUEST on DASI: a South Pole CMB polarization experiment     

Sarah Church  Peter Ade  James Bock  Melanie Bowden  John Carlstrom  Ken Ganga  Walter Gear  James Hinderks  Wayne Hu  Brian Keating  John Kovac  Andrew Lange  Eric Leitch  Olivier Mallie  Simon Melhuish  Anthony Murphy  Ben Rusholme  Creidhe O&#x;Sullivan  Lucio Piccirillo  Clem Pryke  Andy Taylor  Keith Thompson 《New Astronomy Reviews》2003,47(11-12):1083

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   

Another perspective on the need for international skipjack and yellowfin tuna management     

Tom Polacheck 《Marine Policy》1990,14(6)

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The HI halo of spiral galaxies     

Filippo Fraternali  Tom Oosterloo  Renzo Sancisi 《Astrophysics and Space Science》2004,289(3-4):377-380

A deep H I survey with the VLA of the spiral galaxy NGC 2403 has revealed the existence of a thick, low density layer of neutral gas surrounding the thin ‘cold’ disk. This layer has a mean rotation velocity 25–50 km s^-1 lower than that of the disk and a 10–20 km s^-1inflow towards the centre of the galaxy. In the central parts there are velocity differences from rotation of up to 150 km s^-1.Chandra observations of NGC 2403 show a diffuse, hot X-ray emitting gas component with a temperature of a few 10⁶ K. These results point at galactic fountain type of flows between disk and halo. ‘Halo’ gas with similar characteristics has also been observed in other spiral galaxies(e.g. NGC 6946, NGC 891). Such gas is probably similar to the IVCs and to some of the HVCs of the Milky Way.  相似文献   

The nature of the ionizing background at  z≈ 2.5–5      

Aaron Sokasian  Tom Abel  Lars Hernquist 《Monthly notices of the Royal Astronomical Society》2003,340(2):473-484

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Photometric study of new southern SU UMa-type dwarf novae and candidates: V877 Ara, KK Tel and PU CMa     

Taichi Kato  Roland Santallo  Greg Bolt  Tom Richards  Peter Nelson  Berto Monard  Makoto Uemura  Seiichiro Kiyota  Rod Stubbings  rew Pearce  Tsutomu Watanabe  Patrick Schmeer  Hitoshi Yamaoka 《Monthly notices of the Royal Astronomical Society》2003,339(3):861-871

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Cosmic reionization by stellar sources: Population II stars     

Aaron Sokasian  Tom Abel  Lars Hernquist  Volker Springel 《Monthly notices of the Royal Astronomical Society》2003,344(2):607-624

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The angular momentum of gas in protogalaxies – II. The impact of pre-heating     

Frank C. van den Bosch  Tom Abel  Lars Hernquist 《Monthly notices of the Royal Astronomical Society》2003,346(1):177-185

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A search for high-redshift molecular absorption lines towards millimetre-loud, optically faint quasars     

M. T. Murphy  S. J. Curran  J. K. Webb 《Monthly notices of the Royal Astronomical Society》2003,342(3):830-836

We describe initial results of a search for redshifted molecular absorption towards four millimetre-loud, optically faint quasars. A wide frequency bandwidth of up to 23 GHz per quasar was scanned using the Swedish–ESO Submillimetre Telescope at La Silla. Using a search list of commonly detected molecules, we obtained nearly complete redshift coverage up to   z _abs= 5  . The sensitivity of our data is adequate to have revealed absorption systems with characteristics similar to those seen in the four known redshifted millimetre-band absorption systems, but none were found. Our frequency-scan technique nevertheless demonstrates the value of wide-band correlator instruments for searches such as these. We suggest that a somewhat larger sample of similar observations should lead to the discovery of new millimetre-band absorption systems.  相似文献   

Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations     

B. Andersen  V. Domingo  A. Jiménez  A. Jones  S. Korzennik  P. L. Pallé  F. Pérez Hernández  C. Régulo  T. Roca Cortés  L. L. Tomás 《Solar physics》1988,116(2):391-399

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.  相似文献