On the geologic structure of the Explora Escarpment (Weddell Sea,Antarctica) revealed by satellite and Shipboard data evaluation     

Ute Christina Herzfeld  Arnold L. Brodscholl 《Marine Geophysical Researches》1994,16(5):325-345

Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory.The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began.Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the canyon's tectonic origin.  相似文献   

Influence of oxygen fugacity on mineral compositions in peralkaline melts: The Katzenbuckel volcano, Southwest Germany     

Ute Mann  Michael Marks  Gregor Markl   《Lithos》2006,91(1-4):262-285

The igneous rocks of the Katzenbuckel, Southwest Germany, represent a unique and unusual alkaline to peralkaline association within the European Volcanic Province. The magmatic activity can be subdivided into two main phases. Phase I comprises the main rock bodies of phonolite and nepheline syenite, which were later intruded by different peralkaline dyke rocks (tinguaites and alkali feldspar syenite dykes) of phase II. The dyke assemblage was accompanied by magnetite and apatite veins and was followed by a late-stage pneumatolytic activity causing autometasomatic alterations.

As is typical for alkaline to peralkaline igneous rocks, early mafic minerals of phase I rocks comprise olivine, augite and Fe–Ti oxides, which are substituted in the course of fractionation by Na-amphibole and Na-pyroxene. For the early magmatic stage, calculated temperatures range between 880 and 780 °C with low silica activities (0.4 to 0.6) but high relative oxygen fugacities between 0.5 and 1.9 log units above the FMQ buffer. Even higher oxygen fugacities (above the HM buffer) are indicated for the autometasomatic alteration, which occurred at temperatures between 585 and 780 °C and resulted in the formation of pseudobrookite and hematite.

The unusually high oxygen fugacities (even during the early magmatic stage) are recorded by the major element compositions of the mafic minerals (forsterite content in olivine between 68 and 78 mol%, up to 6.2 wt.% ZrO₂ and 8.5 wt.% TiO₂ in clinopyroxene), the unusual mineral assemblages (pseudobrookite, freudenbergite) and by the enrichment of Fe³⁺ in the felsic minerals (up to 2.8 wt.% Fe₂O₃ in alkali feldspar and up to 2.6 wt.% Fe₂O₃ in nepheline). These observations point to a metasomatically enriched and highly oxidized lithospheric mantle as a major source for the Katzenbuckel melts.  相似文献   

A high-resolution magnetotelluric survey of the Iapetus Suture Zone in southwest Scotland   总被引：1，自引：0，他引：1  

Sebastian Tauber  Roger Banks  Oliver Ritter  Ute Weckmann 《Geophysical Journal International》2003,153(3):548-568

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Environmental Monitoring and Peat Assessment Using Multivariate Analysis of Regional-Scale Geochemical Data     

Jennifer M. McKinley  Eric Grunsky  Ute Mueller 《Mathematical Geosciences》2018,50(2):235-246

A compositional multivariate approach was used to analyse regional-scale soil geochemical data obtained as part of the Tellus Project generated by the Geological Survey of Northern Ireland. The multi-element total concentration data presented comprise X-ray fluorescence (XRF) analyses of 6862 rural soil samples collected at 20-cm depth on a non-aligned grid at one site per \(2\,\hbox {km}^{2}\). Censored data were imputed using published detection limits. Each soil sample site was assigned to the regional geology map, resulting in spatial data for one categorical variable and 35 continuous variables comprised of individual and amalgamated elements. This paper examines the extent to which soil geochemistry reflects the underlying geology or superficial deposits. Since the soil geochemistry is compositional, log-ratios were computed to adequately evaluate the data using multivariate statistical methods. Principal component analysis (PCA) and minimum/maximum autocorrelation factors (MAF) were used to carry out linear discriminant analysis (LDA) as a means to discover and validate processes related to the geologic assemblages coded as age bracket. Peat cover was introduced as an additional category to measure the ability to predict and monitor fragile ecosystems. Overall prediction accuracies for the age bracket categories were 68.4 % using PCA and 74.7 % using MAF. With inclusion of peat, the accuracy for LDA classification decreased to 65.0 and 69.9 %, respectively. The increase in misclassification due to the presence of peat may reflect degradation of peat-covered areas since the creation of superficial deposit classification.  相似文献   

Lithology-derived structure classification from the joint interpretation of magnetotelluric and seismic models     

P. A. Bedrosian  N. Maercklin  U. Weckmann  Y. Bartov  T. Ryberg  O. Ritter 《Geophysical Journal International》2007,170(2):737-748

Magnetotelluric and seismic methods provide complementary information about the resistivity and velocity structure of the subsurface on similar scales and resolutions. No global relation, however, exists between these parameters, and correlations are often valid for only a limited target area. Independently derived inverse models from these methods can be combined using a classification approach to map geologic structure. The method employed is based solely on the statistical correlation of physical properties in a joint parameter space and is independent of theoretical or empirical relations linking electrical and seismic parameters. Regions of high correlation (classes) between resistivity and velocity can in turn be mapped back and re-examined in depth section. The spatial distribution of these classes, and the boundaries between them, provide structural information not evident in the individual models. This method is applied to a 10 km long profile crossing the Dead Sea Transform in Jordan. Several prominent classes are identified with specific lithologies in accordance with local geology. An abrupt change in lithology across the fault, together with vertical uplift of the basement suggest the fault is sub-vertical within the upper crust.  相似文献   

Rock magnetism of greigite bearing sediments from the Dead Sea, Israel     

Ute Frank  Norbert R. Nowaczyk  Jörg F. W. Negendank 《Geophysical Journal International》2007,168(3):921-934

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Is the ocean floor a fractal?   总被引：1，自引：0，他引：1  

Ute C. Herzfeld  Isaac I. Kim  John A. Orcutt 《Mathematical Geology》1995,27(3):421-462

The topographic structure of the ocean bottom is investigated at different scales of resolution to answer the question: Can the seafloor be described as a fractal process? Methods from geostatistics, the theory of regionalized variables, are used to analyze the spatial structure of the ocean floor at different scales of resolution. The key to the analysis is the variogram criterion: Self-similarity of a stochastic process implies self-similarity of its variogram. The criterion is derived and proved here: it also is valid for special cases of self-affinity (in a sense adequate for topography). It has been proposed that seafloor topography can be simulated as a fractal (an object of Hausdorff dimension strictly larger than its topological dimension), having scaling properties (self-similarity or self-affinity). The objective of this study is to compare the implications of these concepts with observations of the seafloor. The analyses are based on SEABEAM bathymetric data from the East Pacific Rise at 13°N/104°W and at 9°N/104°W and use tracks that run both across the ridge crest and along the ridge flank. In the geostatistical evaluation, the data are considered as a stochastic process. The spatial continuity of this process is described by variograms that are calculated for different scales and directions. Applications of the variogram criterion to scale-dependent variogram models yields the following results: Although the seafloor may be a fractal in the sense of the definition involving the Hausdorff dimension, it is not self-similar, nor self-affine (in the given sense). Mathematical models of scale-dependent spatial structures are presented, and their relationship to geologic processes such as ridge evolution, crust formation, and sedimentation is discussed.  相似文献   

Optimization techniques for integrating spatial data     

Ute C. Herzfeld  Daniel F. Merriam 《Mathematical Geology》1995,27(5):559-588

Two optimization techniques ta predict a spatial variable from any number of related spatial variables are presented. The applicability of the two different methods for petroleum-resource assessment is tested in a mature oil province of the Midcontinent (USA). The information on petroleum productivity, usually not directly accessible, is related indirectly to geological, geophysical, petrographical, and other observable data. This paper presents two approaches based on construction of a multivariate spatial model from the available data to determine a relationship for prediction. In the first approach, the variables are combined into a spatial model by an algebraic map-comparison/integration technique. Optimal weights for the map comparison function are determined by the Nelder-Mead downhill simplex algorithm in multidimensions. Geologic knowledge is necessary to provide a first guess of weights to start the automatization, because the solution is not unique. In the second approach, active set optimization for linear prediction of the target under positivity constraints is applied. Here, the procedure seems to select one variable from each data type (structure, isopachous, and petrophysical) eliminating data redundancy. Automating the determination of optimum combinations of different variables by applying optimization techniques is a valuable extension of the algebraic map-comparison/integration approach to analyzing spatial data. Because of the capability of handling multivariate data sets and partial retention of geographical information, the approaches can be useful in mineral-resource exploration.  相似文献   

Evidence for high-pressure core-mantle differentiation from the metal-silicate partitioning of lithophile and weakly-siderophile elements     

Ute Mann  Daniel J. Frost  David C. Rubie 《Geochimica et cosmochimica acta》2009,73(24):7360-470

Liquid Fe metal-liquid silicate partition coefficients for the lithophile and weakly-siderophile elements Ta, Nb, V, Cr, Si, Mn, Ga, In and Zn have been measured in multianvil experiments performed from 2 to 24 GPa, 2023-2873 K and at oxygen fugacities of −1.3 to −4.2 log units relative to the iron-wüstite buffer. Compositional effects of light elements dissolved in the metal liquid (S, C) have been examined and experiments were performed in both graphite and MgO capsules, specifically to address the effect of C solubility in Fe-metal on siderophile element partitioning. The results were used to examine whether there is categorical evidence that a significant portion of metal-silicate equilibration occurred under very high pressures during core-mantle fractionation on Earth. Although the depletion of V from the mantle due to core formation is significantly greater than that of Nb, our results indicate that both elements have similar siderophile tendencies under reducing conditions at low pressures. With increasing pressure, however, Nb becomes less siderophile than V, implying that average metal-silicate equilibration pressures of at least 10-40 GPa are required to explain the Nb/V ratio of the mantle. Similarly the moderately-siderophile, volatile element ratios Ga/Mn and In/Zn are chondritic in the mantle but both volatility and core-mantle equilibration at low pressure would render these ratios strongly sub-chondritic. Our results indicate that pressures of metal-silicate partitioning exceeding 30-60 GPa would be required to render these element ratios chondritic in the mantle. These observations strongly indicate that metal-silicate equilibration must have occurred at high pressures, and therefore support core-formation models that involve deep magma oceans. Moreover, our results allow us to exclude models that envisage primarily low-pressure (<1 GPa) equilibration in relatively small planetary bodies. We also argue that the core cannot contain significant U as this would require metal-silicate equilibration at oxygen fugacities low enough for significant amounts of Ta to have also been extracted from the mantle. Likewise, as In is more siderophile than Pb but similarly volatile and also quite chalcophile it would have been difficult for Pb to enter the core without reversing the relative depletions of these elements in the mantle unless metal-silicate equilibration occurred at high pressures >20 GPa.  相似文献   

Geostatistics for Compositional Data: An Overview   总被引：1，自引：0，他引：1  

Tolosana-Delgado  Raimon  Mueller  Ute  van den Boogaart  K. Gerald 《Mathematical Geosciences》2019,51(4):485-526

Mathematical Geosciences - This paper presents an overview of results for the geostatistical analysis of collocated multivariate data sets, whose variables form a composition, where the components...  相似文献