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Philippe E. Raison Regis Jardin Daniel Bouëxière Rudy J. M. Konings Thorsten Geisler Claudiu C. Pavel Jean Rebizant Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra. 相似文献
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Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism 总被引：2，自引：0，他引：2
Gustave Cauwet Gaëlle Dliat Anton Krastev Galina Shtereva Sylvie Becquevort Christiane Lancelot Andr Momzikoff Alain Saliot Adriana Cociasu Lucia Popa 《Marine Chemistry》2002,79(3-4)
During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production. 相似文献
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V. Popa 《Astrophysics and Space Science》2000,273(1-4):305-312
We discuss the searches for massive magnetic monopoles and for nuclearitesin the penetrating cosmic radiation performed with the MACRO detector. Independent monopole analysis were carried out using the scintillator, streamer tubes and nuclear track sub-detectors in different ranges of velocity. No candidates were found in several years of data taking; present upper flux limits are well below the Parker bound in a wide velocity range. For nuclearites only the scintillator and nuclear track sub-detectors were used. 相似文献
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The first 1,000 year long Carpathian tree-ring width chronology was established based on living and subfossil stone pine (Pinus cembra L.) samples from an upper timberline forest located in Calimani Mts. (Romania). Tree-ring data were standardized using the regional curve standardization method in order to preserve the low and medium frequency climate signals. The de-trended index strongly correlates with summer mean temperature both at annual and decadal scales. The Calimani summer mean temperature anomalies were reconstructed for the period ad 1163-2005 applying the rescaling method. This new climate proxy from the Carpathians shows similar fluctuations to other North Hemispheric temperature reconstructions, but with periods of distinct differences. The fingerprint of Little Ice Age in the Calimani area is visible between ad 1370 and 1630 followed by lagged cold decades in ad 1820 and 1840. The recent warming is evident only after the 1980s in our reconstruction. 相似文献
6.
Francisco González-Sánchez Antoni Camprubí Eduardo González-Partida Rafael Puente-Solís Carles Canet Elena Centeno-García Viorel Atudorei 《Mineralium Deposita》2009,44(3):343-361
Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine,
fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be
permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated
with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts
controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas
Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are
mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized
during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and
lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic
studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions
range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen.
Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites.
Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises
most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas
and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits
to the north and barite and Zn–Pb deposits mostly in the central part. 相似文献
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Aurelian Andrei Radu Tatiana Angelescu Valentin Curtef Florin Delia Daniel Felea Ioana Goia Dumitru Ha?egan Bogdan Lucaschi Ancuta Manea Vlad Popa Ioan Rali?? Radu V?c?reanu 《Experimental Astronomy》2012,34(1):31-42
Around the world, several scientific projects share the interest of a global network of small Cherenkov telescopes for monitoring observations of the brightest blazars??the DWARF network. A small, ground based, imaging atmospheric Cherenkov telescope of last generation is intended to be installed and operated in Romania as a component of the DWARF network. To prepare the construction of the observatory, two support projects have been initiated. Within the framework of these projects, we have assessed a number of possible sites where to settle the observatory. In this paper we submit a brief report on the general characteristics of the best four sites selected after the local infrastructure, the nearby facilities and the social impact criteria have been applied. 相似文献
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J. Derkaoui G. Giacomelli T. Lari G. Mandrioli M. Ouchrif L. Patrizii V. Popa 《Astroparticle Physics》1999,10(4):117-352
A systematic analysis of the energy losses of magnetic monopoles of different magnetic charges and of dyons in three types of detectors are investigated for a large range of β = υ/c (β > 10−5). More specifically we have computed the light yield in liquid scintillators, the ionization in streamer tubes and the Restricted Energy Loss in the CR39 nuclear track detectors. Also the total energy losses have been analyzed. 相似文献