Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Box model analysis of hydrography and behaviour of nitrogen and phosphorus in a eutrophic estuary     

Yasuo Matsukawa  Teruaki Suzuki 《Journal of Oceanography》1985,41(6):407-426

In order to investigate the mechanism of eutrophication in Atsumi Bay which is a shallow and partially mixed estuary, distributions of temperature, salinity and concentrations of nitrogen and phosphorus in all their chemical forms were observed once a month throughout a year. Supplies of freshwater and nutrients are estimated and balances of salt and nutrients are examined using a modified box model. The deduced estuarine hydrography and calculated values of photosynthesis, decomposition, deposition and sedimentation are compared with those obtained byin situ observations and laboratory experiments. It is found that the factors responsible for the appearance of heavy eutrophication include not only the general increase of nutrient supply from land but also nutrient accumulation in the rainy season just before summer, the N/P ratio of the supply from land being favourable for uptake by phytoplankton, formation of semi-closed circulations of the nutrients associated with stratification and vertical circulation of estuarine water, and possibly the inorganic turnover of phosphorus (PO₄-P) under aerobic and anaerobic conditions. The usefulness of the modified box model for obtaining a synoptic understanding of the estuarine system is also demonstrated.  相似文献   

Nitrogen budget in Tokyo Bay with special reference to the low sedimentation to supply ratio     

Yasuo Matsukawa  Katsuyuki Sasaki 《Journal of Oceanography》1990,46(2):44-54

In order to determine why the sedimentation to supply ratio of nutrients in Tokyo Bay is markedly small, the nitrogen budget was investigated for 1979, when a systematic and continuous observation of flow and salinity was carried out. The data were analyzed by use of a simple advective-diffusive box model and dissolved oxygen balance in the lower layer was also examined. The calculated values of two-layer flow, settling, primary production, mineralization, denitrification, and dissolved oxygen consumption were comparable to those observed.The factors making the sedimentation to supply ratio makedly small were summarized as: 1) a strong and stable two-layer flow generated by a large freshwater supply, 2) further intensification of this two-layer flow by the northern winter monsoon, 3) coincidence of the discharge region with the supply region of nutrients caused by the transverse inclination of the interface, probably due to the earth's rotation. 4) effective discharge of nutrients from the bay due to a strong tidal flow and a possible cyclonic tidal residual circulation in the inner bay mouth, 5) incomplete consumption of nutrient salts by phytoplankton in the upper layer even in the most productive season, and 6) possible denitrification in the anaerobic bottom water in summer and in the bottom sediment itself throughout the year in the inner bay.  相似文献   

The content of selenium and its chemical form in sea water   总被引：1，自引：0，他引：1  

Yukio Sugimura  Yoshimi Suzuki  Yasuo Miyake 《Journal of Oceanography》1976,32(5):235-241

By using the new fluorometric method of determination of the total selenium ( Se), Se (IV) and Se (VI), the content of selenium in sea weter was determined in the western North Pacific. Results showed that the content of Se in surface water ranged from 0.06 to 0.12g l^–1, while in deeper layers, the content increased to 0.20g l^–1. It was found that Se (IV) showed rather uniform distribution with depth, while Se (VI) increased with depth to about three times that in the surface. The ratio of Se (IV) to the Se ranged from 0.5 to 0.8 in the surface and 0.4 to 0.6 in the deep. The coexistence of the hexa- and tetravalent ions of selenium was confirmed both in surface and deep layers. Some results of observations on the content of selenium in the coastal areas of Japan were also reported.  相似文献   

Ammonium uptake kinetics and interactions between nitrate and ammonium uptake inChattonella antiqua     

Yasuo Nakamura 《Journal of Oceanography》1985,41(1):33-38

Ammonium uptake kinetics and interactions between nitrate and ammonium uptake were examined inChattonella antiqua. After the addition of ammonium to the culture ofC. antiqua, the ammonium concentration decreased linearly with time. The ammonium uptake rate as a function of ammonium concentration followed the Michaelis-Menten equation; the maximal uptake rate was 2.0 pmol cell^–1hr^–1 and the half saturation constant, 2.2M. Although the ammonium uptake was not affected by nitrate, uptake of nitrate was rapidly (15min) suppressed by ammonium and a 50% reduction in nitrate uptake was observed at an ammonium concentration ofca. 2M.  相似文献   

Hydrography and budget of dissolved total nitrogen and dissolved oxygen in the stratified season in Mikawa Bay,Japan     

Teruaki Suzuki  Yasuo Matsukawa 《Journal of Oceanography》1987,43(1):37-48

Distributions of salinity, dissolved total nitrogen (DTN) and dissolved oxygen (DO) were observed once a month throughout a year in Mikawa Bay, one of the most eutrophic bays in Japan. Supply of freshwater, DTN and DO from the land and precipitation was estimated. Hydrography, circulation and transformation of DTN and DO during the stratified period were investigated simultaneously by a two-layered box model analysis dividing the bay into five boxes. The two-layered circulation was confirmed. In the upper layer of the river mouth regions, a high production of particulate organic nitrogen (PON) due to the strong upwelling together with the river inflow was found. On the other hand, in the lower layer of the bay mouth region, a high deposition of PON due to weak upwelling and sometimes downwelling and a high decomposition of PON due to the inflow of DO abundant water were also found. The reason why the eutrophication is more severe in the eastern part than in the north-western part of the bay is discussed.  相似文献   

新疆阿尔泰山南部富蕴右旋走滑断裂带晚第四纪错断水系的遥感分析研究   总被引：2，自引：2，他引：0       下载免费PDF全文

张之武  付碧宏  Yasuo Awata 《第四纪研究》2008,28(2):273-279

富蕴断裂带位于阿尔泰山南侧,横切阿尔泰山褶皱带南缘及额尔齐斯深断裂,是一条呈北北西向展布的右旋走滑断裂带。沿断裂带发育一系列错断水系、错断冲积扇、挤压脊、走滑拉分盆地等反映右旋走滑活动的典型构造地貌标志。本研究在高分辨率遥感图像和数字高程模型分析的基础上,结合野外实地构造地貌测量,对沿富蕴断裂带发育的系统错断水系特征进行了详细分析研究。研究结果表明,沿富蕴断裂带发育不同级别的错断水系,大致可划分为6级:1931年地震形成的冲沟;90m左右断距的错断水系;150m左右断距的错断水系;500m左右断距的错断水系;1500m左右断距的错断水系;2000m以上断距的错断水系。同时,结合研究区及邻区的第四纪冰川资料讨论了不同级别水系可能形成时间:恰尔沟三级支流可能形成时间为末次冰期Ⅲ阶段末期,约20ka;恰尔沟二级支流可能形成时间为末次冰期Ⅰ阶段末期,约120ka;恰尔沟一级支流可能形成于该地区冰川广泛消融的倒数第2次冰期的Ⅱ阶段末期,约为250ka;恰尔沟、水磨沟、白杨沟、乌铁布拉克河、卡布尔特河等可能形成于倒数第3次冰期Ⅱ阶段末期,约为360ka。最后,我们估算出富蕴断裂带晚第四纪以来的平均右旋走滑速率为1.46～4.99mm/a。  相似文献   

Evaluation of change in subsurface thermal environment due to groundwater flow in the Tokyo Lowland,Japan     

Akinobu Miyakoshi  Takeshi Hayashi  Atsunao Marui  Yasuo Sakura  Shinichi Kawashima  Masafumi Kawai 《International Journal of Earth Sciences》2008,97(2):401-411

Information on the distribution of subsurface temperature and hydraulic heads at 24 observation wells in and around the Tokyo Lowland, the eastern part of the Tokyo Metropolitan area, were examined to make clear the relationship between groundwater and the subsurface thermal environment in the urban area. Minimums in temperature–depth logs due to subsurface temperature increasing at shallow parts were recognized in 21 wells. This fact shows subsurface temperature is affected by ground surface warming in almost all of this area. Deeper than minimums, where the effects of surface warming became relatively small, regional variation is observed as follows: high temperatures are shown in the central part to the southern part, and low temperatures shown in the inland to eastern part. The high temperature area corresponds to an area where the lower boundary of groundwater flow is relatively shallow. This area corresponds also to an area with severe land subsidence resulting from excessive groundwater pumping. It is considered that this high temperature area is formed by the effects of upward groundwater flow affected by hydrogeological conditions and pumping. On the other hand, a comparison between past data (1956–1967) and present data (2001–2003) revealed widespread decreasing temperature in the inland area. This is explained by downward groundwater flow based on an analysis of temperature–depth logs. This fact suggests that subsurface temperature is not only increasing from the effects of surface warming but also decreasing from the effects of groundwater environment change due to pumping.  相似文献   

Detection of a new interstellar molecular ion, H2COH+ (protonated formaldehyde)     

Ohishi M  Ishikawa SI  Amano T  Oka H  Irvine WM  Dickens JE  Ziurys LM  Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64

A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+.  相似文献   

Nitrogen sulfide in quiescent dark clouds     

McGonagle D  Irvine WM  Ohishi M 《The Astrophysical journal》1994,422(2):621-625

We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models.  相似文献