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This study aims to investigate the degree of the influence of contaminant sources on both the surface (Porsuk River) and groundwater in the Eskisehir plain, (Turkey) and to determine the changes in groundwater quality after the sewage system was started in 1998. For this purpose surface and groundwater samples were collected from various locations in the Eskisehir plain between May and October, 2001. The Porsuk River is already polluted in the upstream wastewater and by industries such as Nitrogen Fertilizer Factory, Sugar-beet Factory, and Magnesite Factory located around the city of Kutahya. This high-contaminated water forms an eutrophic environment which generates high phosphorus and nitrogen in downstream flow. Agricultural and industrial activities in the Eskisehir plain are an additional source of the pollution of the Porsuk River. The study revealed that some trace elements, Pb, Cr, Mn, Fe, and Cd, are present in high concentrations both in the surface and groundwater besides extremely high quantities of phosphorus, nitrogen and sulfide compounds. In addition, analyses of samples also indicated that there are no considerable contaminations in terms of local pesticides. High concentration of Cd, N and S are found in the groundwater. On the basis of a detailed analysis of the groundwater in the Eskisehir plain, it is concluded that groundwater is not suitable for drinking according to Turkish standards, European Union Standards (EU) and World Health Organization (WHO). An erratum to this article can be found at  相似文献   
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The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results, sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical equilibrium. Thermal waters in the area are characterized by Na+–Cl–HCO3, while the cold waters by CaHCO3 facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ18O and δ2H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8 to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs water quality in terms of irrigation purposes in shallow groundwaters, such as Na+, B, and Cl, are highy probably expected to increase in time.  相似文献   
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Manganese and iron are essential nutrients at low doses. However, long-term exposure in high doses may be harmful. Human activities and natural sources are responsible for manganese and iron contamination in water. This study aimed to investigate the source of high manganese and iron contents in shallow groundwater, where the groundwater is used for drinking purpose, and to decrease the excess manganese and iron from shallow groundwater. Based on the on-site analytical results taken from the wells in the study area, iron contents in water samples varied between 30 and 200 μg/L, which were under the allowable limits of Turkish Drinking Water Standards (TDWS) (Water intended for human consumption, http://rega.basbakanlik.gov.tr/eskiler/2005/02/20050217-3.htm, 2005). However, manganese levels varied from 30 to 248 μg/L, which some of them are higher than the allowable limits of TDWS (Water intended for human consumption, http://rega.basbakanlik.gov.tr/eskiler/2005/02/20050217-3.htm, 2005) (50 μg/L), and EPA (http://water.epa.gov/drink/contaminants/index.cfm, 2006) (50 μg/L). The source of excess manganese is originated mainly from geogenic source besides Porsuk River interaction in shallow aquifer in the specific section of the study area. To decrease high manganese content from the well water and reservoir water, laboratory and in situ treatment tests were applied. Among these tests, chlorination, associated with filtration (by fine sand, active carbon and zeolite) and the use of different filtration procedures by cation exchange resin were determined as the most effective methods, which was not previously applied on-site as a combinative approaches to reduce the excess manganese in water.  相似文献   
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As a new technology of analyzing crude oils, comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS) has received much research attention. Here we present a case study in the Junggar Basin of NW China. Results show that the hydrocarbons, including saturates and aromatics, were all well-separated without large co-elution, which cannot be realized by conventional one-dimensional GC–MS. The GC×GC technique is especially effective for analyzing aromatics and low-to-middle-molecular-weight hydrocarbons, such as diamondoids. The geochemical characteristics of crude oils in the study area were investigated through geochemical parameters extracted by GC×GC-TOFMS, improving upon the understanding obtained by GC–MS. Thus, the work here represents a new successful application of GC×GC-TOFMS, showing its broad usefulness in petroleum geochemistry.  相似文献   
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Alptekin  Candan  Yuce  Galip 《Water Resources》2016,43(1):184-199
Water Resources - The Eskisehir province is well-known due to its industrial and agricultural activities, which are a threat for the aquatic environment. Hence, monitoring of water quality in the...  相似文献   
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The objective of this study was to investigate the geochemical and hydrogeological effects of earthquakes on fluids in aquifers, particularly in a seismically active area such as Eskisehir (Turkey) where the Thrace–Eskisehir Fault Zone stretches over the region. The study area is also close to the North Anatolian Fault Zone generating devastating earthquakes such as the ones experienced in 1999, reactivating the Thrace–Eskisehir Fault. In the studied area, Rn and CO2 gas concentrations, redox potential, electrical conductivity, pH, water level, water temperature, and the climatic parameters were continuously measured in five stations for about a year. Based on the gathered data from the stations, some ambiguous anomalies in geochemical parameters and Rn concentration of groundwater were observed as precursors several days prior to an earthquake. According to the mid-term observations of this study, well-water level changes were found to be a good indicator for seismic estimations in the area, as it comprises naturally filtered anomalies reflecting only the changes due to earthquakes. Also, the results obtained from this study suggest that both the changes in well-water level and gas–water chemistry need to be interpretated together for more accurate estimations. Valid for the studied area, it can be said that shallow earthquakes with epicentral distances of <30 km from the observation stations have more influence on hydrochemical parameters of groundwater and well-water level changes. Although some hydrochemical anomalies were observed in the area, it requires further observations in order to be able to identify them as precursors.  相似文献   
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