Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand     

Leonard Boszke  Artur Kowalski  Witold Szczuciński  Grzegorz Rachlewicz  Stanisław Lorenc  Jerzy Siepak 《Environmental Geology》2006,51(4):527-536

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.  相似文献   

Two New Polish Geological-Environmental Reference Materials: Apatite Concentrate (CTA-AC-1) and Fine Fly Ash (CTA-FFA-1)     

Rajmund DYBCZYNASKI  Halina POLKOWSKA-MOTRENKO  Zbigniew SAMCZYNASKI  Zygmunt SZOPA 《Geostandards and Geoanalytical Research》1991,15(2):163-185

World-wide intercomparison runs has made possible the certification of two new Polish geological-environmental reference materials for multi-element trace analysis: Apatite Concentrate (CTA-AC-1) and Fine Fly Ash (CTA-FFA-1). "Recommended values' are established for 25 (CTA-AC-1) and 40 (CTA-FFA-1) elements respectively. In addition, "information values' are assigned for 12 elements in CTA-AC-1 and 10 elements in CTA-FFA-1. Our method of data evaluation has been further improved and a modified version of criteria for assigning recommended and information values is proposed.  相似文献   

Characteristics of horizontal macroturbulence due to the currents in the Baltic Sea     

Andrzej Jankowski Ph. D.  Zygmunt Catewicz M. Sc. 《Ocean Dynamics》1984,37(5):173-200

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An Attempt of the Treatment of Underground Water in an Integrated Multifunctional Plant     

E. Gomlk  Z. Kowalski 《洁净——土壤、空气、水》1987,15(1):93-101

By means of an integrated multifunctional experimental pilot plant there were tested several process variants for the treatment of carbonic-acid-aggressive and manganese-enriched model water. Deacidification and oxidation of iron- and manganese-constituents are effected by gas exchange with atmospheric oxygen. The hydrated-oxide particles formed are held back by two layers of foamed polyurethane and a sand bed lying uppermost. The process of neutralization and oxidation as well as flocculation is accelerated by the use of chalk, lime or soda. The effectiveness of the process technology investigated is illustrated by a table of results of small-scale experiments with model waters prepared from drinking water.  相似文献   

He Conductivity in Cool White Dwarf Atmospheres     

S. Mazevet  M. Challacombe  P. M. Kowalski  D. Saumon 《Astrophysics and Space Science》2007,307(1-3):273-277

We investigate the conductivity of warm dense helium under conditions found in the atmospheres of cool white dwarfs using ab initio simulations. The calculations performed consist of quantum molecular dynamics simulations where the electronic wavefunction at each time step is obtained using density functional theory, while the ion trajectories are calculated using the resulting quantum mechanical forces. We use both conventional DFT (PW91) and hybrid (PBE0) functionals to calculate the conductivities that provide an estimate of the ionization fraction. While the calculations are in good agreement with the measurements for the equation of state, a significant discrepancy exists with the recently measured conductivity.  相似文献   

Types of sedimentary environment in alluvial sediments distinguished on the basis of its chemical constitution: the example of the lower course of the Obra river (Western Poland)   总被引：1，自引：1，他引：0  

Marcin Słowik  Tadeusz Sobczyński  Zygmunt Młynarczyk 《Environmental Earth Sciences》2010,59(5):957-966

Research concerning chemical constitution of alluvial sediments was done in the lower course of the Obra river (Western Poland). The fragment of vertical profile, which consisted of various alluvial sediments (fine sands, peats, and sandy silts) was chosen for detailed analysis. The main research problem was to determine if lithology and chemical constitution of alluvial deposits are interconnected in a distinct way within studied section of the Obra river valley, and, if changes of chemical elements’ concentration could be used to illustrate depositional processes, which take place in riverbed and floodplain. Concentrations of Fe, Mn, Cu, Zn, Ca, Mg, and K were determined in collected sediment samples. Next, geochemical groups of alluvial sediments were distinguished using cluster analysis. Investigated changes of chemical elements’ concentration show that there is a distinct border between the environment of organic sediments, which marks the place of former functioning of the Obra riverbed, and sandy silts, which were deposited within floodplain during floods. Besides, floodplain sediments, riverbed sediments, and reductive environment within peat deposits were singled out on the basis of the analysis.  相似文献   

Bayesian active learning for parameter calibration of landslide run-out models     

Zhao  Hu  Kowalski  Julia 《Landslides》2022,19(8):2033-2045

Landslides - Landslide run-out modeling is a powerful model-based decision support tool for landslide hazard assessment and mitigation. Most landslide run-out models contain parameters that cannot...  相似文献   

Characteristics of airborne bacteria and fungi in some Polish wastewater treatment plants     

M. Kowalski  J. Wolany  J. S. Pastuszka  G. Płaza  A. Wlazło  K. Ulfig  A. Malina 《International Journal of Environmental Science and Technology》2017,14(10):2181-2192

The aim of this study was to characterize both the viable airborne bacteria and fungi collected in different types of wastewater treatment plants in Poland. Bacterial and fungal aerosols in five different wastewater treatment plants in Poland were studied, including the pioneering antibiotic resistance testing of airborne bacteria. Concentration level was measured using the six-stage Andersen impactor. After incubation, bioaerosol particles captured on nutrient media on Petri dishes were quantitatively evaluated and qualitatively identified. It was found that the concentration levels of both airborne bacteria and fungi ranged from 10² to 10³ colony-forming units/m³, in all stages of the wastewater treatment plants. The patterns of size distributions of airborne bacteria and fungi were very similar, showing dominant peaks typically in the size range between 3.3 and 4.7 μm. The majority fraction of small bacterial and fungal particles (less than 4.7 μm) in the studied areas indicates that the bioaerosol is relatively fresh, and mostly of local origin. The Gram-positive cocci and nonsporing Gram-positive rods were the dominating forms in the studied wastewater treatment plants environment. The existing differences in the concentration levels between sampling sites enabled identification of the main bioaerosol sources. The highest concentration of bacterial aerosol appeared in sections, where activated sludge post-processing and mechanical purifying are conducted. The most frequently occurring species in the sampled bacterial aerosol were Gram-positive cocci and nonsporing Gram-positive rods. Multi-antibiotic resistance testing showed that among the isolated airborne bacteria, the most antibiotic-resistant features were present among Bacillus species (especially Bacillus mycoides).  相似文献   

New results on ground deformation in the Upper Silesian Coal Basin (southern Poland) obtained during the DORIS Project (EU-FP 7)     

Marek Graniczny  Davide Colombo  Zbigniew Kowalski  Maria Przyłucka  Albin Zdanowski 《Pure and Applied Geophysics》2015,172(11):3029-3042

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Disentangling Turbulent Gas Diffusion from Non-diffusive Transport in the Boundary Layer     

Kowalski  Andrew S.  Serrano-Ortiz  Penélope  Miranda-García  Gabriela  Fratini  Gerardo 《Boundary-Layer Meteorology》2021,179(3):347-367

Boundary-Layer Meteorology - An analysis based on the law of linear momentum conservation demonstrates unequivocally that the mass fraction is the scalar whose gradient determines gas diffusion,...  相似文献