全文获取类型
收费全文 | 633篇 |
免费 | 26篇 |
国内免费 | 6篇 |
专业分类
测绘学 | 54篇 |
大气科学 | 56篇 |
地球物理 | 143篇 |
地质学 | 234篇 |
海洋学 | 43篇 |
天文学 | 76篇 |
综合类 | 6篇 |
自然地理 | 53篇 |
出版年
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2018年 | 18篇 |
2017年 | 10篇 |
2016年 | 20篇 |
2015年 | 16篇 |
2014年 | 24篇 |
2013年 | 31篇 |
2012年 | 13篇 |
2011年 | 32篇 |
2010年 | 24篇 |
2009年 | 31篇 |
2008年 | 28篇 |
2007年 | 29篇 |
2006年 | 33篇 |
2005年 | 15篇 |
2004年 | 21篇 |
2003年 | 27篇 |
2002年 | 27篇 |
2001年 | 16篇 |
2000年 | 13篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 8篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1975年 | 9篇 |
1974年 | 5篇 |
1973年 | 8篇 |
1972年 | 4篇 |
1970年 | 6篇 |
1966年 | 4篇 |
1954年 | 3篇 |
排序方式: 共有665条查询结果,搜索用时 62 毫秒
1.
2.
3.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:2,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
4.
The S and O isotopic composition of dissolved SO4, used as a tracer for SO4 sources, was applied to the water of the Llobregat River system (NE Spain). The survey was carried out at 30 sites where surface water was sampled on a monthly basis over a period of 2a. The concentration of dissolved SO4 varied from 20 to 1575 mg L−1. Sulphur isotopic compositions clustered in two populations: one – 93% of the samples – had positive values with a mode of +9‰; the other had negative values and a mode of −5‰. Data for δ18OSO4 showed a mean value of +11‰, with no bi-modal distribution, though lower values of δ18O corresponded to samples with negative δ34S. These values can not be explained solely by the contribution of bedrock SO4 sources: that is, sulphide oxidation and the weathering of outcrops of sulphates, though numerous chemical sediments exist in the basin. Even in a river with a high concentration of natural sources of dissolved SO4, such as the Llobregat River, the δ34S values suggest that dissolved SO4 is controlled by a complex mix of both natural and anthropogenic sources. The main anthropogenic sources in this basin are fertilizers, sewage, potash mine effluent and power plant emissions. Detailed river water sampling, together with the chemical and isotopic characterisation of the main anthropogenic inputs, allowed determination of the influence of redox processes, as well as identification of the contribution of natural and anthropogenic SO4 sources and detection of spatial variations and seasonal changes among these sources. For instance, in the Llobregat River the input of fertilisers is well marked seasonally. Minimum values of δ34S are reported during fertilization periods – from January to March – indicating a higher contribution of this source. The dual isotope approach, δ34S and δ18O, is useful to better constrain the sources of SO4. Moreover, in small-scale studies, where the inputs are well known and limited, the mixing models can be enhanced and the contribution of the different sources can be quantified to some extent. 相似文献
5.
6.
Genetic Relationships Among One Non-Endemic and Two Endemic Mediterranean Triplefin Blennies (Pisces, Blennioidei) 总被引:1,自引:0,他引:1
Gerard J. Geertjes Albert Kamping Wilke van Delden & John J. Videler 《Marine Ecology》2001,22(3):255-265
Abstract. Three triplefin blennies occur sympatrically in the Mediterranean Sea; Tripterygion tripteronotus and T. melanurus are endemic, whereas T. delaisi is also found in the Eastern Atlantic. Although very similar in morphology, ecology and behaviour, some striking differences exist among reproductive strategies. Several authors proposed hypotheses on the evolution of these species. In order to enhance insight into the genetic structure of this genus, an enzyme electrophoretic survey was performed. Samples of 40 to 45 specimens of each species were collected near Calvi (Corsica, France). Twenty-four enzyme loci were analysed, of which 17 appeared polymorphic. T. delaisi showed a high level of average observed heterozygosity (Ho ) of 0.140, as opposed to very low levels of 0.009 and 0.021 in T. tripteronotus and T. melanurus , respectively. Nei's genetic distance was 0.21 between T. delaisi and T. tripteronotus , 0.35 between T. delaisi and T. melanurus and 0.45 between T. tripteronotus and T. melanurus . We hypothesise that divergence of these species started before the Pleistocene and that the endemic species survived the Pleistocene glaciations in refugia within the Mediterranean. The possibility that T. tripteronotus and T. delaisi diverged through sympatric speciation is discussed. 相似文献
7.
Microzooplankton production in the oceans 总被引:7,自引:0,他引:7
8.
The increasing natural disasters, especially floods during the last quarter century, are raising the economic losses in Taiwan.
The most severe hazard in Taiwan is flooding induced by typhoons and storms in summer and autumn. By comparing the rivers
around the world, the ones in Taiwan have the steepest slopes, the largest discharge per unit drainage area, and the shortest
time of concentrations. Rapid urbanization without proper land uses managements usually worsen the flood problems. Consequently,
flood hazards mitigation has become the most essential task for Taiwan to deal with. Although the government keeps improving
flood defense structures, the flood damage grows continuously. In this article, possible flood mitigation strategies are identified
for coping with complex environmental and social decisions with flood risk involved. 相似文献
9.
The formation of cold air drainage flows in a shallow gully is studied during CASES-99 (Cooperative Atmosphere-Surface Exchange Study). Fast and slow response wind and temperature measurements were obtained on an instrumented 10-m tower located in the gully and from a network of thermistors and two-dimensional sonic anemometers, situated across the gully. Gully flow formed on clear nights even with significant synoptic flow. Large variations in surface temperature developed within an hour after sunset and in situ cooling was the dominant factor in wind sheltered locations. The depth of the drainage flow and the height of the down-gully wind speed maximum were found to be largest when the external wind speed above the gully flow is less than 2 m s-1. The shallow drainage current is restricted to a depth of a few metres, and is deepest when the stratification is stronger and the external flow is weaker. During the night the drainage flow breaks down, sometimes on several occasions, due to intermittent turbulence and downward fluxes of heat and momentum. The near surface temperature may increase by 6 ° C in less than 30 min due to the vertical convergence of downward heat flux. The mixing events are related to acceleration of the flow above the gully flow and decreased Richardson number. These warming events also lead to warming of the near surface soil and reduction of the upward soil heat flux. To examine the relative importance of different physical mechanisms that could contribute to the rapid warming, and to characterize the turbulence generated during the intermittent turbulent periods, the sensible heat budget is analyzed and the behaviour of different turbulent parameters is discussed. 相似文献
10.
A stochastic channel embedded in a background facies is conditioned to data observed at wells. The background facies is a fixed rectangular box. The model parameters consist of geometric parameters that describe the shape, size, and location of the channel, and permeability and porosity in the channel and nonchannel facies. We extend methodology previously developed to condition a stochastic channel to well-test pressure data, and well observations of the channel thickness and the depth of the top of the channel. The main objective of this work is to characterize the reduction in uncertainty in channel model parameters and predicted reservoir performance that can be achieved by conditioning to well-test pressure data at one or more wells. Multiple conditional realizations of the geometric parameters and rock properties are generated to evaluate the uncertainty in model parameters. The ensemble of predictions of reservoir performance generated from the suite of realizations provides a Monte Carlo estimate of the uncertainty in future performance predictions. In addition, we provide some insight on how prior variances, data measurement errors, and sensitivity coefficients interact to determine the reduction in model parameters obtained by conditioning to pressure data and examine the value of active and observation well data in resolving model parameters. 相似文献