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1.
Northern Brazil contains remnants of Mesozoic flood basalts and hypabyssal rocks that were apparently emplaced during tectonism related to opening of the Atlantic Ocean. Analyses and new K-Ar ages reveal that this 700x250 km Maranhão province (5°–8°S) has low-Ti basalts (1.1 wt% TiO2) in the western part that range about 160 to 190 Ma, and high-Ti basalts (3.4–4.4 wt% TiO2) in the eastern part about 115–122 Ma. Low-Ti basalt compositions are less evolved and have a smaller range, Mg# 62-56, than the high-Ti basalts, Mg# 44–33. General characteristics of the least evolved members of low- and high-Ti groups include, respectively, Zr 100 and 250 ppm, Sr 225 and 475 ppm, Ba 200 and 500 ppm, Nb 10 and 26 ppm, Y 29 and 36 ppm, La/Yb(n) 4.2 and 8.8, where La(n) is 30 and 90. Overall compositions resemble the low- and high-Ti basaltic rocks of the Mesozoic Serra Geral (Paraná) province in southern Brazil. The Maranhão low-Ti basalts have more radiogenic Sr and Pb and higher 18O than the high-Ti basalts. Respectively, low- vs high-Ti: Sr26–54 vs 15–18; 206Pb/204Pb=18.25–.78 vs 18.22–.24; and 18O 8.9–12.6 vs 6.5–8.6. Nd isotopes overlap: Nd–1.6 to –3.8 vs –2.1 to –3. Ages, compositions, and isotopes indicate that the low- and high-Ti groups had independent parentages from enriched subcontinental mantle. However, both groups can be modeled from one source composition if low-Ti basalt isotopes reflect crustal contamination, and if the parentages for each group were picritic liquids that represent either higher (for low-Ti) or lower (for high-Ti) percentages of melting of that single source. When comparing Pb isotopes of Maranhão and Serra Geral high-Ti basalts (uncontaminated) to evaluate the DUPAL anomaly, Maranhão has Pb 7/4=4.6–11, and Pb 8/4=72–87; Serra Geral has Pb 7/4=10–13, and Pb 8/4=95–125. The small difference is not enough to conform to DUPAL contours, and is inconsistent with large-scale isotopic heterogeneity of mantle beneath Brazil prior to rifting of South America from Africa. Maranhão low-Ti magmas probably relate to the opening of central North Atlantic, and high-Ti magmas to the opening of equatorial Atlantic. The proposed greater percentage of source melting for low-Ti basalts may reflect a Triassic-Jurassic hotspot, while lesser melting for high-Ti magmas may relate to Cretaceous decompressional (rifting) melting.  相似文献   
2.
The carbon isotope measurements, carried out on subsurface carbonate samples from Oxfordian Jaisalmer Formation, western India, yield positive d13C values up to +3.17%. The most positive Oxfordian C-isotope value corresponds to the carbon isotope excursion measured in samples from from other late Jurassic basins of world. The latest Oxfordian C-isotope values of Jaisalmer Basin fluctuate around 2% while the C-isotope values of 1.50% mark the base of Kimmeridgian. The Oxfordian C-isotope excursion appears to correspond to a time of overall increased organic carbon burial triggered by increased nutrient transfer from continents to oceans during a time of rising global sea level.  相似文献   
3.
The Indravati Basin represents an unmetamorphosed and unfossiliferous sequence and shows a broad similarity in lithological association with other Purana Basins of Central India. The carbonates belonging to Indravati Basin have on average, moderately positive δ13 C values (up to +4.5). Numerous successions reported from other parts of world, show similar δ13 C values and contain evidence to suggest that the latest Mesoproterozoic to early Neoproterozoic period may represent an isotopically recognizable interval globally. The elevated δ13 C values of Indravati Basin are also correlatable with other Purana Basins in India including Upper Vindhyan Supergroup.  相似文献   
4.
The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C27 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.  相似文献   
5.
A 4 km2 exposure of shallowly-emplaced leucogranite on the Atlantic coast at Cabo de Santo Agostinho, 30 km south of Recife, Brazil has been extensively studied chemically and isotopically. Twenty-three major-element analyses indicate that the Cabo granite ranges from peralkaline to peraluminous; Na2O+K2O is very high (7.4 to 10.4 wt.%), with CaO low (0.3%) and MgO vanishing (<0.06%). Microprobe analyses confirm the presence of arfvedsonite (biotite absent), and nearly total absence of plagioclase. The rocks are moderately to highly enriched in LREE (La 45 to 350 times chondritic), with extremely pronounced negative Eu anomalies (Eu/Eu*=0.02 to 0.07). Whole-rock 18O is consistent at +8.5±0.3%.oSMOW A Rb-Sr isochron age of isotopically slightly disturbed samples is 104.8±1.8 Ma, with initial87Sr/86Sr=0.7084±0.0011. Sr is depleted (2–20 ppm) but Ba is 200–750 ppm.Crystallization path calculations and petrographic observations suggest that magma formed at a pressure close to 6 kbar but rose to a crustal level equivalent to roughly 1 kbar. Quartz, the liquidus phase at moderate H2O concentrations and pressures above 2 kbar, was resorbed during decompression as the magma moved upwards. Ultimately, quartz and alkali feldspar coprecipitated. Feldspar was not retained in the source rock nor removed early from the fractionating magma. Therefore the strong negative Eu anomaly and low Sr abundance are characteristics inherited from the source. A high H2O concentration necessary for a large degree of melting was lacking, hence the Cabo magma composition must reflect a small degree of partial melting of a rather quartz-rich rock such as a feldspathic arenite.In a pre-drift reconstruction of Gondwanaland, the Cabo granite fits on the southernmost and youngest end of the trend of the Niger-Nigerian igneous centers with which it has close affinity. The Cabo granite occupies the western end of the trace of the ancestral Ascension mantle plume which presumably served as the heat source.  相似文献   
6.
The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ13C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ13C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ13C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ13C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.  相似文献   
7.
8.
To show the influence of coastal habitat degradation on the availability of food for green turtles (Chelonia mydas), we assessed the dietary preferences and macroalgae community at a feeding area in a highly urbanized region. The area showed low species richness and was classified as degraded. We examined stomach contents of 15 dead stranded turtles (CCL = 44.0 cm (SD 6.7 cm)). The diet was composed primarily of green algae Ulva spp. (83.6%). In contrast, the macroalgae community was dominated by the green alga Caulerpa mexicana. We found a selection for red algae, seagrass and Ulva spp., and avoidance for C. mexicana and brown alga Dictyopteris delicatula. The low diversity of available food items, possibly a result of environmental degradation, likely contributed to the low dietary diversity. The nutritional implications of this restricted diet are unclear.  相似文献   
9.
Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low 87Sr/86Sr ratios and highly positive δ13C values. Available geochemical data for the upper Paleoproterozoic indicate that the 87Sr/86Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.  相似文献   
10.
The bimodal Malani suite, West of Barmer, Rajasthan is characterized by discontinuous, ring shaped outcrops of Siwana peralkaline granite with minor outcrops of basalt. The peralkaline, within- plate and A-type nature of granite are evident by its chemical characteristics. The granite is characterized by high Na2O+K2O, Fe/Mg, Zr, Nb, Y, Zn; low Al2O3, CaO and Sr and is significantly low in absolute abundance of trace and REE elements compared to type area Siwana granite. The granite is correlated to the “Pan-African” event and its petrogenesis and tectonic significance are discussed.  相似文献   
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