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1.
Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h−1, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, KD, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl+, an increase in the proportion of TlCl0 and increasing competition for adsorption sites from K+ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl+ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries. 相似文献
2.
Jennifer Vandenhecke Matthieu Waeles Jean-Yves Cabon Cédric Garnier Ricardo D. Riso 《Estuarine, Coastal and Shelf Science》2010
Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux. 相似文献
3.
Patricio Crespo Amelie Bücker Jan Feyen Kellie B. Vaché Hans‐Georg Frede Lutz Breuer 《水文研究》2012,26(25):3896-3910
In this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km2) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub‐páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C‐horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
4.
Amelie Bücker Patricio Crespo Hans-Georg Frede Kellie Vaché Felipe Cisneros Lutz Breuer 《Aquatic Geochemistry》2010,16(1):127-149
We investigated controls on the water chemistry of a South Ecuadorian cloud forest catchment which is partly pristine, and
partly converted to extensive pasture. From April 2007 to May 2008 water samples were taken weekly to biweekly at nine different
subcatchments, and were screened for differences in electric conductivity, pH, anion, as well as element composition. A principal
component analysis was conducted to reduce dimensionality of the data set and define major factors explaining variation in
the data. Three main factors were isolated by a subset of 10 elements (Ca2+, Ce, Gd, K+, Mg2+, Na+, Nd, Rb, Sr, Y), explaining around 90% of the data variation. Land-use was the major factor controlling and changing water
chemistry of the subcatchments. A second factor was associated with the concentration of rare earth elements in water, presumably
highlighting other anthropogenic influences such as gravel excavation or road construction. Around 12% of the variation was
explained by the third component, which was defined by the occurrence of Rb and K and represents the influence of vegetation
dynamics on element accumulation and wash-out. Comparison of base- and fast flow concentrations led to the assumption that
a significant portion of soil water from around 30 cm depth contributes to storm flow, as revealed by increased rare earth
element concentrations in fast flow samples. Our findings demonstrate the utility of multi-tracer principal component analysis
to study tropical headwater streams, and emphasize the need for effective land management in cloud forest catchments. 相似文献
5.
Jaffrennou C Giamarchi P Cabon JY Stephan L Burel-Deschamps L Bautin F Thomas A Dumont J Le Floch S 《Marine pollution bulletin》2007,54(12):1932-1939
Coal is currently becoming an increasingly interesting fossil energy resource and that is the reason why its maritime transport, and hence the risk of collier accidents, increase. In this work, the environmental impact of an accidental coal immersion at sea is studied: the physicochemical effects are estimated using innovative experimental setups – a laboratory seawater canal called “polludrome” is used to evaluate the behaviour of coal particles submitted to a seawater flow, and a specifically designed tub is used to study the physicochemical consequences induced when coal is introduced into continuously renewed seawater. When coal is introduced into seawater, the most easily visible consequences are physical: fine coal particles reduce the daylight penetration up to 100% and move along with the flow, and coal chunks accumulate on the floor. Chemical effects are also measured: humic matters are dissolved from coal into seawater (up to 2 mg L−1), but no release of polycyclic aromatic hydrocarbons is evidenced. Some inorganic compounds are dissolved, among which manganese, whose concentrations can reach 1 μg L−1. Fortunately, the results show that the environmental impact of this type of accident would remain limited. 相似文献
6.
This study examined the potential metal pollution induced by the accidental spill of different acids into seawater. The acids sink to the bottom according to their densities and subsequently react with marine sediments. The acids selected for this study were acetic, hydrochloric, nitric, sulfuric, and phosphoric acids; the metallic elements selected were Cr, Cu, Fe, Mn, Pb and Zn. The sediment was collected in Brest Harbour. The percentages of metals released from this sediment in the presence of various concentrations of acids in seawater were important; concentrations of approximately 7 mg L−1 for Mn and 60 mg L−1 for Zn were observed under our experimental conditions. We also examined the rate of release of these metals from the sediment into the seawater in the presence of the different acids and under different experimental conditions. We found that most of the metallic elements were released from the sediments into the seawater during the first fifteen minutes of exposure. After this time, a high degree of pollution was induced if acids leached into seawater were not rapidly diluted. 相似文献
7.
Amelie Stolle Wolfgang Schwanghart Christoff Andermann Anne Bernhardt Monique Fort John D. Jansen Hella Wittmann Silke Merchel Georg Rugel Basanta Raj Adhikari Oliver Korup 《地球表面变化过程与地形》2019,44(1):331-341
Mountain rivers respond to strong earthquakes by rapidly aggrading to accommodate excess sediment delivered by co-seismic landslides. Detailed sediment budgets indicate that rivers need several years to decades to recover from seismic disturbances, depending on how recovery is defined. We examine three principal proxies of river recovery after earthquake-induced sediment pulses around Pokhara, Nepal's second largest city. Freshly exhumed cohorts of floodplain trees in growth position indicate rapid and pulsed sedimentation that formed a fan covering 150 km2 in a Lesser Himalayan basin with tens of metres of debris between the 11th and 15th centuries AD. Radiocarbon dates of buried trees are consistent with those of nearby valley deposits linked to major medieval earthquakes, such that we can estimate average rates of re-incision since. We combine high-resolution digital elevation data, geodetic field surveys, aerial photos, and dated tree trunks to reconstruct geomorphic marker surfaces. The volumes of sediment relative to these surfaces require average net sediment yields of up to 4200 t km–2 yr–1 for the 650 years since the last inferred earthquake-triggered sediment pulse. The lithological composition of channel bedload differs from that of local bedrock, confirming that rivers are still mostly evacuating medieval valley fills, locally incising at rates of up to 0.2 m yr–1. Pronounced knickpoints and epigenetic gorges at tributary junctions further illustrate the protracted fluvial response; only the distal portions of the earthquake-derived sediment wedges have been cut to near their base. Our results challenge the notion that mountain rivers recover speedily from earthquakes within years to decades. The valley fills around Pokhara show that even highly erosive Himalayan rivers may need more than several centuries to adjust to catastrophic perturbations. Our results motivate some rethinking of post-seismic hazard appraisals and infrastructural planning in active mountain regions. © 2018 John Wiley & Sons, Ltd. 相似文献
8.
Exploratory analysis of statistical post‐processing methods for hydrological ensemble forecasts 
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下载免费PDF全文 Despite many recent improvements, ensemble forecast systems for streamflow often produce under‐dispersed predictive distributions. This situation is problematic for their operational use in water resources management. Many options exist for post‐processing of raw forecasts. However, most of these have been developed using meteorological variables such as temperature, which displays characteristics very different from streamflow. In addition, streamflow data series are often very short or contain numerous gaps, thus compromising the estimation of post‐processing statistical parameters. For operational use, a post‐processing method has to be effective while remaining as simple as possible. We compared existing post‐processing methods using normally distributed and gamma‐distributed synthetic datasets. To reflect situations encountered with ensemble forecasts of daily streamflow, four normal distribution parameterizations and six gamma distribution parameterizations were used. Three kernel‐based approaches were tested, namely, the ‘best member’ method and two improvements thereof, and one regression‐based approach. Additional tests were performed to assess the ability of post‐processing methods to cope with short calibration series, missing values or small numbers of ensemble members. We thus found that over‐dispersion is best corrected by the regression method, while under‐dispersion is best corrected by kernel‐based methods. This work also shows key limitations associated with short data series, missing values, asymmetry and bias. One of the improved best member methods required longer series for the estimation of post‐processing parameters, but if provided with adequate information, yielded the best improvement of the continuous ranked probability score. These results suggest guidelines for future studies involving real operational datasets. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
9.
Hing-Ho Tsang James E. Daniell Friedemann Wenzel Amelie C. Werner 《Natural Hazards》2018,90(2):943-974
Among the coastal districts of mega city Istanbul, Bakirkoy is one of the most critical one with the importance of air and marine transportation and presence of many other coastal facilities and structures that are prone to suffer from marine hazards. In the history, the Sea of Marmara has experienced numerous earthquake and landslide events and associated tsunamis. Therefore, tsunami risk assessment is essential for all coastal districts of Istanbul, including Bakirkoy district. In this study, a further developed methodology for tsunami human vulnerability and risk assessment Metropolitan Tsunami Human Vulnerability Assessment (MeTHuVA) is applied for Bakirkoy district of Istanbul, considering earthquake generated tsunamis. High-resolution tsunami hazard analysis is performed with the integration of coastal inundation computation with tsunami numerical tool NAMI DANCE and tsunami human vulnerability assessment with GIS-based multi-criteria decision analysis methods (MCDA). Using analytical hierarchy process method of MCDA, a hierarchical structure is established, composed of two main elements of tsunami human vulnerability: Vulnerability at Location and Evacuation Resilience. Tsunami risk assessment for Bakirkoy district is calculated by integrating result of hazard and vulnerability assessments with a risk relation that includes a parameter (n), which represents the preparedness and awareness level of the community. Tsunami simulations revealed that the maximum inundation distance is over 350 m on land and water penetrates almost 1700 m along Ayamama stream. Inundation is observed in eleven neighborhoods of Bakirkoy district. In the inundation zone, maximum flow depth is found to be over 5.7 m. The inundated area forms 4.2% of whole Bakirkoy district, and 62 buildings are located in the inundation zone. Hazard, vulnerability and risk assessment results for different neighborhoods of Bakirkoy district are presented and discussed. 相似文献
10.
Corinne Tarits Robin W. Renaut Jean‐Jacques Tiercelin Alain Le Hriss Jo Cotten Jean‐Yves Cabon 《水文研究》2006,20(9):2027-2055
Lake Baringo, a freshwater lake in the central Kenya Rift Valley, is fed by perennial and ephemeral rivers, direct rainfall, and hot springs on Ol Kokwe Island near the centre of the lake. The lake has no surface outlet, but despite high evaporation rates it maintains dilute waters by subsurface seepage through permeable sediments and faulted lavas. New geochemical analyses (major ions, trace elements) of the river, lake, and hot spring waters and the suspended sediments have been made to determine the main controls of lake water quality. The results show that evaporative concentration and the binary mixing between two end members (rivers and thermal waters) can explain the hydrochemistry of the lake waters. Two zones are recognized from water composition. The southern part of the lake near sites of perennial river inflow is weakly influenced by evaporation, has low total dissolved species (TDS), and has a seasonally variable load of mainly detrital suspended sediments. In contrast, waters of the northern part of the lake show evidence for strong evaporation (TDS of up to eight times inflow). Authigenic clay minerals and calcite may be precipitating from those more concentrated fluids. The subaerial hot‐spring waters have a distinctive chemistry and are enriched in some elements that are also present in the lake water. Comparison of the chemical composition of the inflowing surface waters and lake water shows (1) an enrichment of some species (HCO3?, Cl, SO42?, F, Na, B, V, Cr, As, Mo, Ba and U) in the lake, (2) a depletion in SiO2 in the lake, and (3) a possible hydrothermal origin for most F. The rare earth element distribution and the F/Cl and Na/Cl ratios give valuable information on the rate of mixing of the river and hydrothermal fluids in the lake water. Calculations imply that thermal fluids may be seeping upward locally into the lake through grid‐faulted lavas, particularly south of Ol Kokwe Island. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献