Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Building blocks in hierarchical clustering scenarios and their connection with damped Lyα systems     

Sofía A. Cora  Patricia B. Tissera †  Diego G. Lambas ‡  Mirta B. Mosconi 《Monthly notices of the Royal Astronomical Society》2003,343(3):959-970

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The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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Testing the consistency of the Starburst scenario for active galactic nuclei     

María Luisa García Vargas  Angeles Díaz  Roberto Terlevich  Elena Terlevich 《Astrophysics and Space Science》1993,205(1):77-84

In the frame of the Starburst Model, we show that the evolution of a massive stellar cluster in a high metallicity environment can reproduce the observed emission-line spectrum and the UV-optical Spectral Energy Distribution of the Seyfert 2 galaxies and LINERs. We apply the results of our models to three objects: NGC 5506, NGC 5643 and Mk 348.  相似文献   

Chemical Enrichment of the Intra-Cluster Medium     

SofÍa A. Cora  Simon D.M. White 《Astrophysics and Space Science》2003,284(2):425-428

We investigate the metal enrichment of the intra-cluster medium by using a method that combines N-Body simulations and a semi-analytic model (SAM) of galaxy formation. The cluster of galaxies is simulated in a flat, low density universe, with a numerical resolution that allows the detection of substructures in the dark matter background of the cluster. The phenomenological approach used to model the physical processes involved in the galaxy formation and metal production is applied to the substructures found in the dark matter halos detected at different redshifts. Details of the chemical implementation in the SAM and first results related to the mean properties of the baryonic matter components are presented. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

The estimate of the deceleration in the earth's rotation due to the sun     

Milan Burša 《Earth, Moon, and Planets》1992,56(1):57-60

The tidal long-term decrease in the angular velocity of the Earth's rotation has been estimated on the basis of the angular momentum tidal balance in the Earth-Moon-Sun system. The observed (LLR) tidal long-term decrease in the Moon's mean motion, the apparent secular acceleration in the mean longitude of the Sun and the long-term decrease in the 2nd degree zonal geopotential parameter were used.Presented at the XXth General Assembly of the I.A.G., Vienna, August 15, 1991.  相似文献   

Radiative association in Li+H revisited: the role of quasi-bound states     

O. J. Bennett  A. S. Dickinson  T. Leininger  F. X. Gadéa 《Monthly notices of the Royal Astronomical Society》2003,341(1):361-368

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.  相似文献   

Beam Mode Expansion of Corrugated Conical Horns with Phase Correcting Lens: Application to Radioastronomy Receivers     

E. García  L. De Haro  C. O'Sullivan  G. Cahill  J. A. López Fernández  F. Tercero  B. Galocha  J. L. Besada 《Experimental Astronomy》2003,15(3):173-193

A classical radioastronomy receiver is fed with a corrugated horn and an independent lens, both placed in a cryostat to lower the noise temperature. The beam is focused and directed using a combination of elliptical and plane mirrors. This paper proposes modifying the initial feeding system by placing the lens onto the horn aperture, thereby allowing a size reduction of the horn and lens, and a simplification of their mechanical design. The profiled lens is shaped to correct the phase error on the horn aperture. A quasi-optical model of the horn-plus-lens system has been developed using a Beam Mode Expansion (BME). Results using both a hyperbolic-planar lens and a spherical-elliptical lens, as well as results obtained by using Geometrical Optics (GO) with a Kirchoff–Huygens integration to get the far-field pattern, have been compared with measurements. As a direct application, a full focusing system for the new 40-m radiotelescope at the “Centro Astronómico de Yebes” is presented for the 22, 30 and 45 GHz bands. This paper has developed a QO model for a corrugated conical horn with a phase-correcting lens. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Astronomical Site Testing in Northwest of Argentina     

Pablo Recabarren  Pablo Recabarren  Mirta Mosconi  Hernán Muriel  Hernán Muriel  Diego García Lambas  Diego García Lambas  Marc Sarazin  Riccardo Giovanelli 《Astrophysics and Space Science》2004,290(3-4):409-413

We present the preliminary results of the astronomical site testing, which the group IATE of the OAC is developing in northwest of Argentine in collaboration with ESO and the Department of Astronomy of Cornell University. We show the results, which we have obtained from the analysis of GOES 8 satellite images in the 10.7 μm band, which allowed us to configurate a map of clear sky regions in an area between 23° and 28° S, and 66° 30′ and 69° W. We also comment logistical and tectonic aspects, and discuss next steps to follow in the research.  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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