排序方式： 共有27条查询结果，搜索用时 31 毫秒
1.
Magnetic properties of the profiles of polluted and non-polluted soils. A case study from Ukraine 总被引：7，自引：0，他引：7
2.
In the Origin of Species, published a century‐and‐a‐half ago, Darwin was mystified by the lack of a ‘pre‐Cambrian’ fossil record, the existence of which he regarded as pivotal to his theory of evolution. For the next 100 years, this ‘missing’ fossil record—unknown and thought unknowable'stood out as arguably the single greatest blemish to Darwin's theory. Beginning in the 1950s, the answer to Darwin's problem began to be unearthed, a Precambrian record of flourishing communities of microscopic organisms now known to extend to 3500 million years ago. During recent years, studies of such ancient microbes have markedly increased, spurred by an influx of new workers and, especially, by the introduction of new analytical techniques, three of which are featured here: confocal laser scanning microscopy, and Raman‐spectral and fluorescence‐spectral imagery. Used together, these techniques provide evidence of the three‐dimensional form, cellular anatomy, and molecular structure of rock‐embedded microscopic fossils and of the minerals in which they are entombed that is unavailable by any other means. 相似文献
3.
Using the explicit form of the functions to describe the monopole and dipole spectra of the Cosmic Microwave Background (CMB) radiation, the exact expressions for the temperature dependences of the radiative and thermodynamic functions, such as the total radiation power per unit area, total energy density, number density of photons, Helmholtz free energy density, entropy density, heat capacity at constant volume, and pressure in the finite range of frequencies v 1≤v≤v 2 are obtained. Since the dependence of temperature upon the redshift z is known, the obtained expressions can be simply presented in z representation. Utilizing experimental data for the monopole and dipole spectra measured by the COBE FIRAS instrument in the 60–600 GHz frequency interval at the temperature T=2.72548 K, the values of the radiative and thermodynamic functions, as well as the radiation density constant a and the Stefan-Boltzmann constant σ are calculated. In the case of the dipole spectrum, the constants a and σ, and the radiative and thermodynamic properties of the CMB radiation are obtained using the mean amplitude T amp=3.358 mK. It is shown that the Doppler shift leads to a renormalization of the radiation density constant a, the Stefan-Boltzmann constant σ, and the corresponding constants for the thermodynamic functions. The expressions for new astrophysical parameters, such as the entropy density/Boltzmann constant, and number density of CMB photons are obtained. The radiative and thermodynamic properties of the Cosmic Microwave Background radiation for the monopole and dipole spectra at redshift z≈1089 are calculated. 相似文献
4.
Andrew D. Czaja Anatoliy B. Kudryavtsev George D. Cody J. William Schopf 《Organic Geochemistry》2009,40(3):353-364
The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state 13C nuclear magnetic resonance spectroscopy (13C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, 13C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants. 相似文献
5.
Among all problems confronting the study of ancient permineralized (petrified) microscopic fossils, two stand out, the need for (1) accurate documentation of their three-dimensional morphology, and (2) direct analysis of their chemical composition and that of their surrounding mineral matrices. To address these problems we demonstrate the use of two techniques that we have recently introduced to Precambrian paleobiology: confocal laser scanning microscopy and Raman imagery. These techniques, both of which are non-intrusive and non-destructive, can provide data by which to characterize, in situ and at micron-scale resolution, the cellular and organismal morphology of thin section-embedded organic-walled fossils. In addition, Raman imagery provides direct analyses of the molecular–structural composition of the kerogenous components of such fossils and of their surrounding matrices, and a means to assess quantitatively the geochemical maturity of the preserved organics. Use of these techniques for studies of ancient microscopic fossils can provide information in three dimensions at high spatial resolution about their morphology and cellular anatomy, taphonomy and fidelity of preservation, composition and mode of preservation, and their biogenicity and syngenetic origin with the rocks in which they occur. 相似文献
6.
G��nther J. Redhammer Anatoliy Senyshyn Martin Meven Georg Roth Sebastian Prinz Astrid Pachler Gerold Tippelt Clemens Pietzonka Werner Treutmann Markus Hoelzel Bj?rn Pedersen Georg Amthauer 《Physics and Chemistry of Minerals》2011,38(2):139-157
The compound NaFeGe2O6 was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe2O6 is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO4 tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe2O6 transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO6 octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe2O6 with NaFeSi2O6 is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane. 相似文献
7.
Sergey Konovalov Anatoliy Samodurov Temel Oguz Leonid Ivanov 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):273
New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σt16.2) and anoxic layers (σt16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σt16.2±0.2 kg m−3. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σt16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate. 相似文献
8.
Dmitry P. Gladkochub Sergei A. Pisarevsky Tatiana V. Donskaya Richard E. Ernst Michael T.D. Wingate Ulf Söderlund Anatoliy M. Mazukabzov Eugene V. Sklyarov Michael A. Hamilton John A. Hanes 《Precambrian Research》2010
We present a summary of late Paleoproterozoic to Neoproterozoic mafic magmatism in the Siberian craton, including recently published U–Pb and 40Ar–39Ar dates. These new precise ages suggest that at least some of the previously published K–Ar ages of Siberian mafic bodies should be ignored. The time–space geochronological chart, or the ‘barcode’ of mafic magmatic events shows significant differences between northern and southern Siberia. Both are characterized by ∼1900–1700 Ma magmatic events, but then there was an almost 1 Ga mafic magmatic ‘pause’ in south Siberia until ∼800 Ma. Meanwhile there are indications of multiple mafic magmatic events in North Siberia (Anabar shield and Olenek uplift) between ∼1600 and 1000 Ma. A series of magmatic events probably related to the breakup of Rodinia occurred in southern Siberia after ∼800 Ma. So far, there are no indications of late Neoproterozoic mafic magmatism in North Siberia. Ca. 1000–950 Ma mafic sills were reported from Meso- to Neo-Proterozoic sedimentary successions in the Sette-Daban area on the east side of the Siberian craton, but their tectonic setting is debated. Recent Ar–Ar dates of ∼1750 Ma for NW-trending dykes in the Aldan and Anabar shields, together with similar-age NNE-trending Baikal uplift dykes in south-eastern Siberia suggest the existence of a giant radial dyke swarm possibly related to a mantle plume centred in the Vilyui River area. 相似文献
9.
The Sunyaev-Zel’dovich (SZ) effect represents a small spectral distortion to the cosmic microwave background (CMB) radiation, caused by the Compton scattering of CMB photons by the hot gas of galaxy clusters. In an early stage of universe, the SZ effect generates \(\mu\)-type of distortions for the CMB spectrum. A \(\mu\)-type distortion is created between the double Compton scattering decoupling (\(z \sim 10^{6}\)) and the thermalization decoupling by the Compton scattering (\(z \sim 10^{5}\)). In this case, to describe the small spectral distortion of the CMB spectrum, we use the Bose-Einstein (\(\mu\)-type) distribution with a non-zero chemical potential. At present, it is interesting to investigate the effect of this spectral distortion on the integral characteristics of the Bose-Einstein (\(\mu\)-type) spectrum. The thermal radiative and thermodynamic functions are such integral characteristics. These functions are as follows: a) the total radiation power per unit area; b) total energy density; c) number density of photons; d) grand potential density; e) Helmholtz free energy density; f) entropy density; g) heat capacity at constant volume; h) enthalpy density; and i) pressure. Precise analytical expressions are obtained for the temperature dependences of these functions. Using the observational data obtained by the COBE FIRAS, PIXIE, PRISM, and Planck missions, the thermal radiative and thermodynamic functions are calculated. A comparative analysis of the results obtained with the results for the same functions of the CMB spectrum at \(T = 2.72548~\mbox{K}\) is carried out. Very small distortions are observed for the thermal radiative and thermodynamic functions. In the redshift range \(10^{5} < z < 3 \times10^{6}\), these functions are calculated. The expressions are obtained for new astrophysical parameters, such as the entropy density/Boltzmann constant and number density, created by the Bose-Einstein (\(\mu\)-type) spectrum. 相似文献
10.
Igor S. Falkovich Alexander A. Konovalenko Anatoliy A. Gridin Leonid G. Sodin Igor N. Bubnov Nikolay N. Kalinichenko Sergey L. Rashkovskii Dmitriy V. Mukha Peter L. Tokarsky 《Experimental Astronomy》2011,32(2):127-145
We have developed an active dipole that is intended for use in new generation low frequency array applications. The preamplifier of the active dipole has very high linearity (input IP2 = 70 dBm, input IP3 = 31 dBm) and low noise temperature (100?C360 K). The frequency dependence of the dipole impedance and the match between the dipole and preamplifier have been optimized to achieve Galactic noise limited operation. The ratio between the antenna temperature due to Galactic noise and the noise temperature of the preamplifier is 10 ± 1.5 dB over the whole 10 to 70 MHz range. The total cost of the active cross-dipole is 220 euro. 相似文献