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1.
Angelika van der Linde 《Mathematical Geology》1993,25(1):1-7
Least squares estimation (LSE) is theoretically related to quadratic unbiased estimation of variance components. It is argued that these methods of estimation of variance components essentially generalize LSE though they are not formally equivalent. 相似文献
2.
Metamorphic evolution of garnet-spinel peridotites from the Variscan Schwarzwald (Germany) 总被引：1，自引：0，他引：1
Garnet-spinel peridotites form small, isolated, variably retrogressed bodies within the low-pressure high-temperature gneisses
and migmatites of the Variscan basement of the Schwarzwald, southwest Germany. Detailed mineralogical and textural studies
as well as geothermobarometric calculations on samples from three occurrences are presented. Two of the garnet-spinel peridotites
have equilibrated at 680–770°C, 1.4–1.8 GPa within the garnet-spinel peridotite stability field, one of the samples having
experienced an earlier stage within the spinel peridotite stability field (790°C, <1.8 GPa). The third sample, with only garnet
and spinel preserved, probably equilibrated within the garnet peridotite stability field at higher pressures. These findings
are in line with the distinction of two groups of ultramafic garnet-bearing high-pressure rocks with different equilibration
conditions within the Schwarzwald (670–740°C, 1.4–1.8 GPa and 740–850°C, 3.2–4.3 GPa) which has previously been established
(Kalt et al. 1995). The equilibration conditions of 670–770°C and 1.4–1.8 GPa for garnet-spinel peridotites from the Central
Schwarzwald Gneiss Complex (CSGC) are similar to those for eclogites of the Schwarzwald and also correspond quite well to
those for garnet-spinel peridotites from the Moldanubian zone of the Vosges mountains and of ecologites from the Moldanubian
s.str. of the Bohemian Massif. 相似文献
3.
Leszek Marynowski Michał Zatoń Bernd R.T. Simoneit Angelika Otto Mariusz O. Jędrysek Cezary Grelowski Slawomir Kurkiewicz 《Applied Geochemistry》2007
The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C29-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C33–C35 homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ18O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples. 相似文献
4.
Benjamin Kaeser Bettina Olker Angelika Kalt Rainer Altherr Thomas Pettke 《Contributions to Mineralogy and Petrology》2009,157(4):453-472
Garnet-bearing and garnet-free pyroxenite xenoliths from Quaternary basanites of Marsabit, northern Kenya, were analysed for
microstructures and mineral compositions (major and trace elements) to constrain the thermal and compositional evolution of
the lithospheric mantle in this region. Garnet-bearing rocks are amphibole-bearing websterite with ~5–10 vol% orthopyroxene.
Clinopyroxene is LREE-depleted and garnet has high HREE contents, in agreement with an origin as cumulates from basaltic mantle
melts. Primary orthopyroxene inclusions in garnet suggest that the parental melts were orthopyroxene-saturated. Rock fabrics
vary from weakly to strongly deformed. Thermobarometry indicates extensive decompression and cooling (~970–1,100°C at ~2.3–2.6 GPa
to ~700–800°C at ~0.5–1.0 GPa) during deformation, best interpreted as pyroxenite intrusion into thick Paleozoic continental
lithosphere subsequently followed by continental rifting (i.e., formation of the Mesozoic Anza Graben). During continental
rifting, garnet websterites were decompressed (garnet-to-spinel transition) and experienced the same P–T evolution as their host peridotites. Strongly deformed samples show compositional overlaps with cpx-rich, initially garnet-bearing
lherzolite, best explained by partial re-equilibration of peridotite and pyroxenite during deformation and mechanical mingling.
In contrast, garnet-free pyroxenites include undeformed, cumulate-like samples, indicating that they are younger than the
garnet websterites. Major and trace element compositions of clinopyroxene and calculated equilibrium melts suggest crystallisation
from alkaline basaltic melt similar to the host basanite, which suggests formation in the context of alkaline magmatism during
the development of the Kenya rift.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
5.
Carsten W. Mueller Angelika KölblCarmen Hoeschen François HillionKatja Heister Anke M. HerrmannIngrid Kögel-Knabner 《Organic Geochemistry》2012,42(12):1476-1488
The specific features of the nano-scale secondary ion mass spectrometry (NanoSIMS) technology with the simultaneous analysis of up to seven ion species with high mass and lateral resolution enables us to perform multi-element and stable isotope measurements at the submicron scale. To elucidate the power of this technique, we performed an incubation experiment with soil particles of the fine silt and clay fractions (from an Albic Luvisol), with occluded particulate organic material and intact soil aggregates (from a Haplic Chernozem), using a 13C and 15N labelled amino acid mixture as tracer. Before and during 6-day incubation after the addition of the label, samples were consecutively prepared for NanoSIMS analysis. For this purpose, two different sample preparation techniques were developed: (i) wet deposition and (ii) the sectioning of epoxy resin embedded samples. Single soil particles (fine silt/clay fraction) showed an enrichment of 13C and 15N after label addition that decreased over time. On aggregates of particulate organic matter, re-aggregated during the 6-day incubation experiment, we could show a spatially heterogeneous enrichment of 13C and 15N on the particle surface. The enrichment in 15N demonstrated the diffusion of dissolved organic matter into intact soil aggregate interiors. The prospects of NanoSIMS for three dimensional studies of stable C and N isotopes in organo-mineral associations is demonstrated by the recorded depth profiles of the organic matter distribution on mineral particles. 相似文献
6.
Claire Granier Bertrand Bessagnet Tami Bond Ariela D��Angiola Hugo Denier van der Gon Gregory J. Frost Angelika Heil Johannes W. Kaiser Stefan Kinne Zbigniew Klimont Silvia Kloster Jean-Fran?ois Lamarque Catherine Liousse Toshihiko Masui Frederik Meleux Aude Mieville Toshimasa Ohara Jean-Christophe Raut Keywan Riahi Martin G. Schultz Steven J. Smith Allison Thompson John van Aardenne Guido R. van der Werf Detlef P. van Vuuren 《Climatic change》2011,109(1-2):163-190
Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NOx and SO2 show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NOx emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO2 emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned. 相似文献
7.
Angelika Brandt Katrin Linse Myriam Schüller 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2013-2025
The aim of this study is to compare the depth distributions of four major Southern Ocean macrobenthic epi- and infaunal taxa, the Bivalvia, Gastropoda, Isopoda, and Polychaeta, from subtidal to abyssal depth. All literature data up to summer 2008, as well as the unpublished data from the most recent ANDEEP I–III (Antarctic benthic deep-sea biodiversity: colonisation history and recent community patterns) expeditions to the Southern Ocean deep sea are included in the analysis. Benthic invertebrates in the Southern Ocean are known for their wide bathymetric ranges. We analysed the distributions of four of the most abundant and species-rich taxa from intertidal to abyssal (5200 m) depths in depth zones of 100 m. The depth distributions of three macrofaunal classes (Bivalvia, Gastropoda, Polychaeta) and one order (Isopoda) showed distinct differences. In the case of bivalves, gastropods and polychaetes, the number of species per depth zone decreased from the shelf to the slope at around 1000 m depth and then showed stable low numbers. The isopods showed the opposite trend; they were less species rich in the upper 1000 m but increased in species numbers from the slope to bathyal and abyssal depths. Depth ranges of families of the studied taxa (Bivalvia: 31 families, Gastropoda: 60, Isopoda: 32, and Polychaeta: 46 families) were compiled and illustrated. At present vast areas of the deep sea in the Southern Ocean remain unexplored and species accumulation curves showed that only a fraction of the species have been discovered to date. We anticipate that further investigations will greatly increase the number of species known in the Southern Ocean deep sea. 相似文献
8.
Paul C. Lyons William H. Orem Maria Mastalerz Erwin L. Zodrow Angelika Vieth-Redemann R. Marc Bustin 《International Journal of Coal Geology》1995,27(2-4)
The cuticles and cuticle-free compressions of three Carboniferous medullosan seed-fern leaf species (Macroneuropteris scheuchzeri, Neuropteris ovata var. simonii and Alethopteris lesquereuxii) were analyzed by elemental, 13C nuclear magnetic resonance (NMR), micro-FTIR (Fourier transform infrared) and coal petrographic techniques. The 13C NMR spectra of the cuticle-free compressions and the associated whole coal (high volatile A/B bituminous coal rank) are generally similar and consist of a large aromatic carbon peak, a smaller aliphatic carbon peak and a shoulder on the aromatic peak, representing phenolic carbons. In contrast, the 13C NMR spectra of the cuticles from the same leaves have a predominant peak for aliphatic carbons and a much smaller aromatic carbon peak. This difference in aromaticity between the cuticles and the cuticle-free compressions is also reflected in the higher atomic H/C ratios of the cuticles. Micro-FTIR spectra of the cuticles show oxygenated functional groups (carboxyl and ketone) similar to those in modern cuticles but their most characteristic feature is very strong bands in the aliphatic stretching region. The cuticle-free compressions (mainly vitrinite), in turn, show the absence or significant reduction in oxygenated functional groups, reduction in aliphatic stretching bands and, usually, increased absorbance of aromatic out-of-plane deformation in the 700–900 cm−1 region. Fluorescence spectra for the cuticles from all three species show a great similarity with a λmax at 580–590 nm, probably reflecting a similardegree of coalification, which is consistent with the similar vitrinite reflectance (Rr) and H/C and O/C ratios of the cuticlefree compressions.These results indicate that leaf cuticle-free compressions, which were initially cellulose rich ( 90% cellulose and hemicellulose, < 10% lignin), can alter, during peatification and coalification, to a macromolecular structure similar to that of coalified wood (initially 50% cellulose and hemicellulose, 30%–50% lignin). Thus, a lignin-enriched structure is not a prerequisite for the formation of the macromolecular structure of vitrinite. In addition, the micro-FTIR spectra reveal the complexity of the molecular structure in coalified seed-fern leaves. The micro-FFIR data reveal some significant differences among the cuticles that may be of chemotaxonomic value. Clearly, a combination of macro- and micro-techniques offers a better basis for the interpretation of the molecular structure of pre-macerals and their alteration during peatification and coalification. Also, the data presented in this paper provide important new information that extends the data from morphological and cuticular taxonomic studies of some seed ferns. The data are encouraging preliminary advances in the chemotaxonomy of medullosan seed fern species.Pyrolysis-gas chromatography (PY-GC) data for the cuticles of three seed-fern leaves indicate distinct chemical signatures for the two neuropterid leaves as compared to the Alethopteris leaf. This perhaps indicates a chemotaxomic factor, or it could be related to the greater thickness of the cuticle of Alethopteris. Mass spectrometric data are needed to identify individual components in the PY-GC chromatograms. 相似文献
9.
10.
The calculation of ground water transit times is one important factor in ground water protection. In this paper, we present an analytical solution for the transit time for a Dupuit-type flow system applicable to saturated flow through a horizontal leaky aquifer discharging to a downgradient fixed-head boundary under steady-state conditions. We investigate the influence of leakage when comparing the resulting travel times of our model based on head-dependent leakage with the commonly used model with no leakage and a simplified model with constant leakage. The results show significant differences in the position of the water divide and transit time, suggesting that leakage cannot be ignored. 相似文献