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1.
The content of selenium and its chemical form in sea water   总被引:1,自引:0,他引:1  
By using the new fluorometric method of determination of the total selenium ( Se), Se (IV) and Se (VI), the content of selenium in sea weter was determined in the western North Pacific. Results showed that the content of Se in surface water ranged from 0.06 to 0.12g l–1, while in deeper layers, the content increased to 0.20g l–1. It was found that Se (IV) showed rather uniform distribution with depth, while Se (VI) increased with depth to about three times that in the surface. The ratio of Se (IV) to the Se ranged from 0.5 to 0.8 in the surface and 0.4 to 0.6 in the deep. The coexistence of the hexa- and tetravalent ions of selenium was confirmed both in surface and deep layers. Some results of observations on the content of selenium in the coastal areas of Japan were also reported.  相似文献   
2.
A new method of determination of selenium and separation of Se(IV) and Se(VI) in sea water is described. The selenium is determined by fluorometric method using Se-DAN complex in cyclohexane media. Prior to the fluorometric determination, Se(IV) is separated from sea water by means of Se(IV)-DDTC complex which is adsorbed on the macroreticular resin. As to the separation of the total selenium from sea water sample, the reduction and coprecipitation method is used. Se(VI) is determined with the same method as used for the total selenium after the separation of Se(IV). The average recoveries are 92.5±1.3% for Se(IV) and 97.4±0.9% for Se. The standard deviation of analytical results is below 10%.  相似文献   
3.
The localized near-bottom water with silica content higher than that in the adjacent shelf water was observed to exist at the eastern margins of the East China Sea continental shelf. The core of the high silica water possessed the silica content corresponding to that in the Kuroshio at depths greater than on the shelf. The mixing analysis of water masses using temperature (T) and silica (Si) showed that the core water can be produced through the vertical mixing of intermediate water of the Kuroshio deeper than 100 m. This study provides us a conclusion that the intermediate water of the Kuroshio is strongly mixed on the shelf slope and then upwelled to form the ridge-like distribution of water masses with low temperature and high silica content at the shelf edge.  相似文献   
4.
An internal wavetrain, generated by a tidal current in superposition with the Tsushima Warm Current, has been observed by use of an acoustic echo-sounder upstream of the Shichiri-Ga-Sone Seamounts in the East Tsushima Strait of the Japan Sea. The sea surface above the internal wavetrain was simultaneously observed and was found to be undulated at the wavelength of the internal wave.  相似文献   
5.
Carbon isotopic fractionation during the air/sea exchange process is not fully understood at present. Information on the equilibrium and kinetic fractionation factors is an essential requirement, together with the value of the CO2 partial pressure, for understanding the carbon cycle in the atmosphere and marine environments. Using a specially designed countercurrent equilibrator system, the fractionation factors between gaseous CO2 and dissolved inorganic carbon in sea water were determined under both kinetic and equilibrium conditions. The following results were obtained: kinetic fractionation factor for air to sea (αas) is 0.998 at 288.2 K; kinetic fractionation factor for sea to air (αsa) is 0.990; equilibrium fractionation factor (αeq) is 0.991 at pH = 8.3 and 288.2 K. From these results, the carbon isotopic ratio of CO2 passed through the air/ sea interface is estimated to be about ?10 %. for air to sea and ?8 %. for sea to air when CO2 exchange takes place between air (δ13C = ?8 %.) and surface sea water (δ13C = 2 %.) at 288.2 K.  相似文献   
6.
Thorium isotopes in the airborne dust collected at Tsukuba Science City in Japan from January 1981 to December 1982 show clear seasonal variations. Especially228Th in the airborne particles have a typical maximum cincentration between February and April, which is about an order of magnitude higher than during the remainder of the year. According to the result of size distribution of thorium isotope-bearing particles in the air, about 53% of228Th is associated with the particles less than 1.6 μm aerodynamic diameter. These results reveal that228Th in the airborne particles is present in fine soily matters originating from the East Asian deserts.  相似文献   
7.
The late Cenozoic orogeny in Japan is briefly reviewed. Amounts of volcanic materials in the three periods of the orogeny are estimated at: early Neogene 150 × 103 km3 (mafic 40 %, salic 60 %), middle and late Neogene 20 × 103 km3 (mafic 70 %, salic 30 %), Quaternary 5 × 103 km3 (mafic 80 %, salic 20 %). The largest volume per unit time is in the early Neogene, and the smallest in the middle and late Neogene. Volume per unit area becomes larger towards the southeastern margin or «front» of the volcanic belt. Thermal energy transported by volcanic materials is compared with the terrestrial heat flow in the belt.  相似文献   
8.
The paper utilizes previously developed microtremor simulation technique to evaluate the reliability of Rayleigh wave dispersion curve estimated by fk spectral analysis of microtremor array measurement. The simulated microtremors are obtained for a fictitious (TEST) site. Attempt is also made to obtain the dispersion curve for two real sites (OHDATE and SKC) by inverse analysis of the microtremor array measurement using fk spectra method. The estimated dispersion curve from simulated microtremors (TEST site) compares well with the theoretical dispersion curve, demonstrating the reliability of fk spectra method and indicating that the estimated dispersion curve from microtremor measurements could be adequately used as the target for inverse analysis purposes. It is also demonstrated that the dispersion curve from microtremor measurements can be utilized to estimate the soil profile at OHDATE and SKC sites by inverse analysis. Results show that the theoretical dispersion curve of the fundamental mode of Rayleigh wave after the end of inverse analysis are in good agreement with the dispersion curve obtained by fk spectral analysis of microtremor array measurement.  相似文献   
9.
10.
Using hydrographic data and moored current meter records and the ADCP observed current data during May–June 1996, a modified inverse method is applied to calculate the Kuroshio east of Taiwan and in the East China Sea and the currents east of Ryukyu Islands. There are three branches of the Kuroshio east of Taiwan. The Kuroshio in the East China Sea comes from the main (first) and second branches of the Kuroshio east of Taiwan. The easternmost (third) branch of the Kuroshio flows northeastward to the region east of Ryukyu Islands. The net northward volume transports of the Kuroshio through Section K2 southeast of Taiwan and Section PN in the East China Sea are 44.4×106 and 27.2×106 m3s−1, respectively. The western boundary current east of Ryukyu Islands comes from the easternmost branch of the Kuroshio east of Taiwan and an anticyclonic recirculating gyre more east, making volume transports of 10 to 15×106 m3s−1. At about 21°N, 127°E southeast of Taiwan, there is a cold eddy which causes branching of the Kuroshio there.  相似文献   
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