Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites     

Milton BLANDER  Arthur D. PELTON  In‐Ho JUNG  Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   

The discovery of new galaxy members in the NGC 5044 and 1052 groups     

N. P. F. MKay  C. G. Mundell †  S. Brough  Duncan A. Forbes  D. G. Barnes  P. A. James  P. Goudfrooij  V. Kozhurina-Platais  R. Whitaker 《Monthly notices of the Royal Astronomical Society》2004,352(4):1121-1134

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Acceptance of the 2003 Distinguished Service Award     

Hubert L Barnes 《Geochimica et cosmochimica acta》2004,68(9):1969

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Tektite research 1936–1990*     

Virgil E. Barnes 《Meteoritics & planetary science》1990,25(3):149-159

Abstract— Fifty-odd years of tektite research are reviewed, proceeding from the discovery of the first North American tektites in 1936. This included the early recognition that tektites were terrestrial objects rather than meteorites and that the glassy particles in tektites were fused quartz (lechatelierite). Later, during National Science Foundation-supported research, it was found that some tektites appeared to have formed as puddles of melt, that the content and character of bubbles in lechatelierite can be used as a relative temperature scale, that rayed bubbles in tektites formed from hydrous minerals, that bubbles in tektites formed chiefly from water which was absorbed into the walls of the bubbles leaving vacuums, and that “fingers” in the surficial part of some tektites may have formed by differential volatilization. Some unpublished observations and adventures are briefly reported.  相似文献   

Coulometric TCO2 analyses for marine studies; an introduction     

Kenneth M Johnson  Arthur E King  John McN Sieburth 《Marine Chemistry》1985,16(1):61-82

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.  相似文献   

The Atacama Cosmology Telescope     

Arthur Kosowsky 《New Astronomy Reviews》2003,47(11-12):939

The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys.  相似文献   

Response of earth and venus ionospheres to corotating solar wind stream of 3 July 1979     

H. A. Taylor Jr.  P. A. Cloutier  M. Dryer  S. T. Suess  A. Barnes  R. S. Wolff 《Earth, Moon, and Planets》1985,32(3):275-290

Corotating solar wind streams emanating from stable coronal structures provide an unique opportunity to compare the response of planetary ionospheres to the energy conveyed in the streams. For recurrent solar conditions the signal propagating outward along spiral paths in interplanetary space can at times exhibit rather similar content at quite different downstream locations in the ecliptic plane. Using solar wind measurements from plasma detectors on ISEE-3, Pioneer Venus Orbiter (PVO) and Helios-A, as well as in-situ ion composition measurements from Bennett Ion Mass Spectrometers on the Atmosphere Explorer-E and PVO spacecraft, corotating stream interactions are examined at Earth and Venus. During May–July 1979 a sequence of distinct, recurrent coronal regions developed at the Sun. Analysis of these regions and the associated solar wind characteristics indicates a corrresponding sequence of corotating streams, identifiable over wide distances. The time series of solar wind velocity variations observed at Earth, Venus, and the Helios-A positions during June–July attests to intervals of corotating stream propagation. The characteristics of the stream which passed Earth on July 3, are observed at Helios-A and at Venus (PVO) about 8 days later, consistent with the spiral path propagation delay times between the locations in the ecliptic plane. On July 3, Earth and Venus have a wide azimuthal separation of about 142 . Although the planetary environments are distinctly different, pronounced and somewhat analagous ionospheric responses to the stream passage are observed at both Earth and Venus. The response to the intercepted stream is consistent with independent investigations which have shown that the variability of the solar wind momentum flux is an important factor in the solar wind-ionosphere interaction at both planets.  相似文献   

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma     

Stephen J. Barnes  J. A. C. Anderson  T. R. Smith  L. Bagas 《Mineralium Deposita》2008,43(6):641-662

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The Dynamics of Covering Behaviour in Dominant Echinoid Populations from American and European West Coasts     

Emma Verling  Anne C. Crook  & David K. A. Barnes 《Marine Ecology》2004,25(3):191-206

Abstract.  The so-called 'covering behaviour' of echinoids is known to vary with habitat according to the types of covering items available, but the full extent of the role played by habitat characteristics in this behaviour is not known. Moreover, whether or not different species inhabiting similar environmental conditions and habitats also show similar patterns of this particular behaviour has yet to be investigated. In this study, two prominent west coast echinoid species, Paracentrotus lividus and Strongylocentrotus purpuratus , were examined with respect to covering behaviour and spatial organisation. Populations of both species are found in exposed intertidal zones, occupying boreholes within tidepools. Important similarities were found in the spatial organisation of both species' populations, with lowest densities in upper shore pools. However, the size distributions of the two populations differed significantly; P. lividus within upper shore pools were significantly larger than those in mid or lower shore pools, whereas S. purpuratus on the lower shore were significantly larger than those at other shore heights. We found significant between-species variability in covering item use, although the number of covering items available at both sites was not significantly different. For example, greater densities of covering items were used by P. lividus than by S. purpuratus . We also found that the percent of echinoid surface area covered varied significantly in space for both species. These data emphasise the complex and multifaceted nature of covering behaviour, but most importantly, they also strongly suggest that habitat characteristics can only partly explain the extent of this behavioural variability amongst echinoid species.  相似文献   

Ecological characteristics of Walleye pollock eggs and larvae in the southeastern Bering Sea during the late 1970s   总被引：1，自引：0，他引：1  

Kyung-Mi Jung  Sukyung Kang  Suam Kim  Arthur W. Kendall Jr. 《Journal of Oceanography》2006,62(6):859-871

Walleye pollock (Theragra chalcogramma) is an ecologically and economically important groundfish in the eastern Bering Sea. Its population size fluctuates widely, driving and being driven by changes in other components of the ecosystem. It is becoming apparent that dramatic shifts in climate occur on a decadal scale, and these “regime shifts” strongly affect the biota. This paper examines quantitative collections of planktonic eggs and larvae of pollock from the southeastern Bering Sea during 1976–1979. Mortality, advection, and growth rates were estimated, and compared among the years encompassing the 1970s’ regime shift. These data indicate that pollock spawning starts in late February over the basin north of Bogoslof Island. Over the shelf, most spawning occurs north of Unimak Island near the 100 m isobath in early or mid April. Pollock eggs are advected to the northwest from the main spawning area at 5–10 cm/sec. Larvae are found over the basin north of Bogoslof Island in April, and over the shelf between Unimak Island and the Priblof Islands in May. Compared to 1977, the spawning period appeared to be later in 1976 (a cold year) and earlier in 1978 (a warm year) in the study area. At the lower temperatures in 1976, egg duration would be longer and thus egg mortality would operate over a longer period than in the other years. Mean larval growth appeared to be lower in 1976 than in 1977 and 1979. Estimated egg mortality rate in 1977 was 0.6 in April and 0.3 in early May.  相似文献