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1.
We suggest that elliptical galaxies, as stellar systems in a stage of quasi-equilibrium, may have a specific entropy. We use the Sérsic law to describe the light profile. The specific entropy (the Boltzmann–Gibbs definition) is then calculated assuming that the galaxy behaves as a spherical, isotropic, one-component system. We predict a relation between the three parameters of the Sérsic law linked to the specific entropy, defining a surface in the parameter space, an ‘entropic plane’. We have analysed a sample of simulated merging elliptical galaxies (virtual) and a sample of galaxies belonging to the Coma Cluster (real). Both virtual and realgalaxies are: 1) located in their own ‘entropic plane‘ and 2) in this plane, they are located on a straight line, indicating constant entropy: another physical property A careful examination of the value of the specific entropy indicates a very small increase in the specific entropy with the generation after merging (virtual sample). Although one cannot distinguish between various generations for real galaxies, the distribution of specific entropy in this sample is very similar to that in the virtual sample. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
2.
The Mondego estuary, a shallow warm-temperate intertidal system located on the west coast of Portugal, has for some decades been under severe ecological stress, mainly caused by eutrophication. Water circulation in this system was, until 1998, mainly dependent on tides and on the freshwater input of a small tributary artificially controlled by a sluice. After 1998, the sluice opening was effectively minimised to reduce the nutrient loading, and the system hydrodynamics improved due to engineering work in the upstream areas. The objective of the present study was to evaluate the effect of the mitigation measures implemented in 1998. Changes to the hydrodynamics of the system were assessed using precipitation and salinity data in relation to the concentrations of dissolved inorganic nutrients, as well as the linkage between dissolved N:P ratios and the biological parameters (phytoplankton chlorophyll a concentrations, green macroalgal biomass and seagrass biomass). Two distinctive periods were compared, over a ten year period: from January 1993 to January 1997 and from January 1999 until January 2003. The effective reduction in the dissolved N:P atomic ratio from 37.7 to 13.2 after 1998 is a result of lowered ammonia, but not the oxidised forms of nitrogen (nitrate plus nitrite), or increased concentrations of dissolved inorganic phosphorus. Results suggest that the phytoplankton is not nutrient limited, yet maximum and mean biomass of green macroalgae was reduced by one order of magnitude after the mitigation measures. This suggests that besides lowering the water residence time of the system, macroalgal growth became nitrogen limited. In parallel to these changes the seagrass-covered area and biomass of Zostera noltii showed signs of recovery.  相似文献   
3.
Summary Geochemical characteristics were systematically determined for Early Cretaceous samples of carbonatitic rocks from Eastern Paraguay (Rio Apa, Amambay and Central Provinces). The data show that all the occurrences have an enriched isotopic signature and that the carbonatites have negligible or absent crustal signature. A petrogenetic model (parent liquids, fractional crystallization, hydrothermal interactions and weathering) is proposed as a function of incompatible trace element, stable (O-C) and radiogenic (Sr-Nd) isotope variations with the aim to test the significance of carbonatitic complexes as a marker of the metasomatized subcontinental lithospheric mantle. The results indicate that the carbonatites and primary carbonates from eastern Paraguay, and those from the north eastern Paraná Basin (SE Brazil), were affected by metasomatic events distinct in time and composition.
Karbonatite aus Ost-Paraguay und ihre genetische Beziehung zu Kalium-Magmatismus: C O, Sr und Nd isotope
Zusammenfassung Die geochemischen Charakteristika von frühkretazischen Karbonatitproben aus Ostparaguay (Rio Alpa, Amambay und Zentrale Provinzen) wurden untersucht. Die Daten belegen, daß alle Vorkommen eine isotopische Anreicherungssignatur zeigen und daß ihnen eine entsprechende Krustensignatur fehlt. Ein Petrologisches Modell (Ausgangsschmelze, fraktionierte Kristallisation, hydrothermale Interaktion und Verwitterung) wird auf Grund der Verteilung der inkompatiblen Spurenelemente, der stabilen (C-O) und radiogenen (Sr-Nd) Isotope vorgeschlagen. Es versucht die Bedeutung der Karbonatitkomplexe als Markerhorizonte des metasomatischen subkontinentalen Mantels zu überprüfen. Die Ergebnisse zeigen, daß die Karbonatite und die primären Karbonate in Ostparaguay, und jene aus dem Paraná Becken SüdostBrasiliens durch zeitlich und zusammensetzungsmäßig unterschiedliche metasomatische Prozesse erfaßt wurden.


With 10 Figures  相似文献   
4.
The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g−1 dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.  相似文献   
5.
Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ18O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ18O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ18O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ18O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ18O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites.  相似文献   
6.
The polyphase evolution of the Seridó Belt (NE-Brazil) includes D1 crust formation at 2.3–2.1 Ga, D2 thrust tectonics at 1.9 Ga and crustal reworking by D3 strike-slip shear zones at 600 Ma. Microstructural investigations within mylonites associated with D2 and D3 events were used to constrain the tectono-thermal evolution of the belt. D2 shear zones commenced at deeper crustal levels and high amphibolite facies conditions (600–650 °C) through grain boundary migration, subgrain rotation and operation of quartz c-prism slip. Continued shearing and exhumation of the terrain forced the re-equilibration of high-T fabrics and the switching of slip systems from c-prism to positive and negative a-rhombs. During D3, enhancement of ductility by dissipation of heat that came from syn-D3 granites developed wide belts of amphibolite facies mylonites. Continued shearing, uplift and cooling of the region induced D3 shear zones to act in ductile-brittle regimes, marked by fracturing and development of thinner belts of greenschist facies mylonites. During this event, switching from a-prism to a-basal slip indicates a thermal path from 600 to 350 °C. Therefore, microstructures and quartz c-axis fabrics in polydeformed rocks from the Seridó Belt preserve the record of two major events, which includes contrasting deformation mechanisms and thermal paths.  相似文献   
7.
8.
The Lapa do Santo archaeological site, located in the Lagoa Santa region, Brazil, represents an important hunter-gatherer occupation dated from the Early and Middle Holocene. Prior studies of archaeofauna dating to this period are few and most of them only provide basic faunal identification with limited information on taphonomic processes. The main goal of this study is to identify the archaeofauna, record the taphonomic processes, and make inferences about its natural (interpreted as the death of the animal in the rockshelter area due to natural causes or due to predation) or anthropic origins. No extinct species (including megamastofauna) were identified. Taxonomic analysis indicated that most faunal remains consist of taxa that may be of mixed origin (natural or anthropic), such as microvertebrates and carnivorous mammals. The Cervidae are the main vertebrate family found in the studied material and these are likely the result of hunting. The Cervidae Ozotoceros support the presence of a fauna that is typical of savannah environments, although the assemblage contains mostly generalist fauna that can thrive in a variety of environments. Very few remains showed clear evidence for taphonomic processes related to human interaction, such as burnt bones.  相似文献   
9.
10.
The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO3–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al2SiO5 polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.  相似文献   
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