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1.
An estimated average CO2 output from Etna's summit craters in the range of 13±3 Mt/a has recently been determined from the measured SO2 output and measured CO2/SO2 molar ratios. To this amount the CO2 output emitted diffusely from the soil (≈ 1 Mt/a) and the amount of CO2 dissolved in Etna's aquifers (≈ 0.25 Mt/a) must be added. Data on the solubility of CO2 in Etnean magmas at high temperature and pressure allow the volume of magma involved in the release of such an amount of
this gas to be estimated. This volume of magma (≈ 0.7 km3/a) is approximately 20 times greater than the volume of magma erupted annually during the period 1971–1995. On the basis
of C-isotopic data of CO2 collected in the Etna area and of new hypotheses on the source of Mediterranean magmas, significant contributions of CO2 from non-magmatic sources to the total output from Etna are unlikely. Such large outputs of CO2 and also of SO2 from Etna could be due to an anomalously shallow asthenosphere beneath the volcano that allows a continuous escape of gases
toward the surface, even without migration of magma.
Received: 7 August 1996 / Accepted: 9 November 1996 相似文献
2.
E.M. Bazelyan Yu.P. Raizer N.L. Aleksandrov F. D'Alessandro 《Atmospheric Research》2009,94(3):436-447
A simple model of a glow corona occurring near the tip of a grounded electrode in a thundercloud electric field that can be enhanced by an approaching downward leader has been studied analytically and numerically with regard to the effect of wind. We obtained an approximate expression for corona current taking into account the (i) removal of space charge from the coronating point due to ion drift and wind and (ii) image of the charge in the ground. As the wind velocity decreases to zero, the expression tends to that obtained previously in the absence of wind. It was shown analytically and numerically that, in a thundercloud electric field, even moderate wind velocities lead to hundreds of percent increase in the corona current. This current decreases with time only slightly in a steady thundercloud electric field, as opposed to the current behavior in the absence of wind. However, even strong wind is not sufficient to affect the properties of a corona intensified in the electric field of an approaching downward leader. The occurrence of wind does not affect the conditions for initiation of an upward connecting leader from grounded objects and consequently the efficiency of lightning rods of ordinary height. 相似文献
3.
Assunta Florenzano Anna Maria Mercuri Aurora Pederzoli Paola Torri Giovanna Bosi Linda Olmi Rossella Rinaldi Marta Bandini Mazzanti 《Geoarchaeology》2012,27(1):34-47
This paper presents the study of parasite remains recovered in pollen samples collected from archaeological layers. Laboratory treatment enabled us to obtain very high concentrations of both pollen and parasite eggs from the same samples. The case study of the site of Piazza Garibaldi in Parma, a town in the Po plain, is reported. The site was a sacred area in Roman times and a market square in Medieval times (10th–11th century A.D.). Pollen, seeds, and fruits from the latter phase were collected from four Medieval pits and one cesspit. After a palynological treatment including sieving, floating, and light acetolysis, abundant quantities of parasite eggs were extracted. Human and animal parasite eggs belonging to Trichuris, Ascaris, Taenia/Echinococcus, Capillaria, Dicrocoelium, and Diphyllobothrium were found. The analyses of animal and plant remains identified in the same samples suggested that the pit infillings consisted of waste, human and animal excrements, deteriorated plant food, and refuse of grapes. Therefore, parasite remains help the interpretation of archaeobotanical data in identifying human behaviors and site functions. 相似文献
4.
A. Aiuppa S. Bellomo L. Brusca W. D'Alessandro R. Di Paola M. Longo 《Bulletin of Volcanology》2006,68(3):255-265
Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural
sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic
compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano
(pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols
and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks.
Variation of the deposition rates during the March 2001–March 2003 period, coupled with previous measurements from 1997 to
2000 (Appl Geochem 16:985–1000, 2001), were compared with the variation of SO2 flux, volcanic activity and rainfall. The deposition rate was mainly controlled by rainfall. Commonly, about 0.1–0.9% of
HF, HCl and SO2 emitted by the summit crater's plume were deposited around the volcano. We estimate that ∼2 Gg of volcanogenic sulphur were
deposited over the Etnean area during the 2002–2003 flank eruption, at an average rate of ∼24 Mg day−1 which is two orders of magnitude higher than that typical of quiescent degassing phases. 相似文献
5.
A Pliocene composite shell concentration from a shallow-marine carbonate succession located in the small, slowly subsiding Novoli graben (Salento peninsula, Puglia, S-Italy) is interpreted as a tsunamite. This interpretation is based on taphonomic, palaeoecological and sedimentologic features. The deposit appears to drape the previous substrate, with thinning on the topographic highs and thickening in the lows, and consists of up to six sub-layers showing repeated grading (normal and reverse), suggesting that deposition occurred during up to six surges. The shell assemblage results from a chaotic mixing of taxa spanning a large spectrum of environments and taphonomic features. Although a fraction of broken shells is present, most shells are integral, suggesting a transport mechanism preventing strong impacts. On the other hand, the high comminution of skeletal remains occurring in the matrix of the deposit is thought to reflect the composition of sea-floor sediment before the inferred high-energy event.The predominance of displaced, but still articulated valves indicates that bivalves were mostly transported while still alive, after having been lifted from the sea bed. Exhumation, displacement, and large-scale transport of large-sized, deep-infaunal organisms (such as Panopea) implies that across relatively large areas the upper few decimetres of the middle–inner shelf floor were eroded by highly turbulent flows of exceptional intensity. A transport as turbulent suspension, very rapid deposition and immediate and permanent burial are strongly suggested by the general integrity of the shells indicating limited effects of physical damage and lack of biological alteration. The variable faunal characteristics of the unit lying below the inferred tsunamite suggest that deposition of the latter took place in settings ranging from a somewhat restricted, relatively low-energy bay, to a more open inner-shelf environment. 相似文献
6.
E. Bagnato A. Aiuppa F. Parello W. D'Alessandro P. Allard S. Calabrese 《Journal of Volcanology and Geothermal Research》2009,179(1-2):96-106
Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0(gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples. We find that dissolved elemental Hg0(aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano. 相似文献
7.
L. Brusca A. Aiuppa W. D'Alessandro F. Parello P. Allard A. Michel 《Journal of Volcanology and Geothermal Research》2001,108(1-4)
Systematic analysis of major and minor elements in groundwaters from springs and wells on the slopes of Mt. Etna in 1995–1998 provides a detailed geochemical mapping of the aquifer of the volcano and of the interactions between magmatic gas, water bodies and their host rocks. Strong spatial correlations between the largest anomalies in pCO2 (pH and alkalinity) K, Rb, Mg, Ca and Sr suggest a dominating control by magmatic gas (CO2) and consequent basalt leaching by acidified waters of the shallow (meteoric) Etnean aquifer. Most groundwaters displaying this magmatic-type interaction discharge within active faulted zones on the S–SW and E lower flanks of the volcanic pile, but also in a newly recognised area on the northern flank, possibly tracking a main N–S volcano-tectonic structure. In the same time, the spatial distribution of T°C, TDS, Na, Li, Cl and B allows us to identify the existence of a deeper thermal brine with high salinity, high content of B, Cl and gases (CO2, H2S, CH4) and low K/Na ratio, which is likely hosted in the sedimentary basement. This hot brine reaches the surface only at the periphery of the volcano near the Village of Paternò, where it gives rise to mud volcanoes called “Salinelle di Paternò”. However, the contribution of similar brines to shallower groundwaters is also detected in other sectors to the W (Bronte, Maletto), SW (Adrano) and SE (Acireale), suggesting its possible widespread occurrence beneath Etna. This thermal brine is also closely associated with hydrocarbon fields all around the volcano and its rise, generally masked by the high outflow of the shallow aquifer, may be driven by the ascent of mixed sedimentary–magmatic gases through the main faults cutting the sedimentary basement. 相似文献
8.
A. Aiuppa R. Avino S. Caliro W. D'Alessandro C. Federico S. Inguaggiato G. Pecoraino 《Chemical Geology》2006,229(4):313-330
This paper documents arsenic concentrations in 157 groundwater samples from the island of Ischia and the Phlegrean Fields, two of the most active volcano-hosted hydrothermal systems from the Campanian Volcanic Province (Southern Italy), in an attempt to identify the environmental conditions and mineral-solution reactions governing arsenic aqueous cycling. On Ischia and in the Phlegrean Fields, groundwaters range in composition from NaCl brines, which we interpret as the surface discharge of deep reservoir fluids, to shallow-depth circulating fluids, the latter ranging from acid-sulphate steam-heated to hypothermal, cold, bicarbonate groundwaters. Arsenic concentrations range from 1.6 to 6900 μg·l− 1 and from 2.6 to 3800 μg·l− 1 in the Phlegrean Fields and on Ischia, respectively. They increase with increasing water temperature and chlorine contents, and in the sequence bicarbonate groundwaters < steam-heated groundwaters < NaCl brines. According to thermochemical modeling, we propose that high As concentrations in NaCl brines form after prolonged water-rock interactions at reservoir T, fO2 and fH2S conditions, and under the buffering action of an arsenopyrite + pyrite + pyrrhotite rock assemblage. On their ascent toward the surface, NaCl brines become diluted by As-depleted meteoric-derived bicarbonate groundwaters, giving rise to hybrid water types with intermediate to low As contents. Steam-heated groundwaters give their intermediate to high As concentrations to extensive rock leaching promoted by interaction with As-bearing hydrothermal steam. 相似文献
9.
The Breaking Celerity Index (BCI) is proposed as a new wave breaking criterion for Boussinesq-type equations wave propagation models (BTE).The BCI effectiveness in determining the breaking initiation location has been verified against data from different experimental investigations conducted with incident regular and irregular waves propagating along uniform slope [Utku, M. (1999). “The Relative Trough Froude Number. A New Criteria for Wave Breaking”. Ph.D. Dissertation, Dept. of Civil and Enviromental Engineering, Old Dominion University, Norfolk, VA; Gonsalves Veloso dos Reis, M.T.L. (1992). “Characteristics of waves in the surf zone”. MS Thesis, Department of Civil Engineering, University of Liverpool., Liverpool; Lara, J.L., Losada, I.J., and Liu, P.L.-F. (2006). “Breaking waves over a mild gravel slope: experimental and numerical analysis”. Journal of Geophysical Research, VOL 111, C11019] and barred beaches [Tomasicchio, G.R., and Sancho, F. (2002). “On wave induced undertow at a barred beach”. Proceedings of 28th International Conference on Coastal Engineering, ASCE, New York, 557–569]. The considered experiments were carried out in small-scale and large-scale facilities. In addition, one set of data has been obtained by the use of the COBRAS model based upon the Reynolds Averaged Navier Stokes (RANS) equations [Liu, P.L.-F., Lin, P., Hsu, T., Chang, K., Losada, I.J., Vidal, C., and Sakakiyama, T. (2000). “A Reynolds averaged Navier–Stokes equation model for nonlinear water wave and structure interactions”. Proceedings of Coastal Structures ‘99, Balkema, Rotterdam, 169–174; Losada, I.J., Lara, J.L., and Liu, P.L.-F. (2005). “Numerical simulation based on a RANS model of wave groups on an impermeable slope”. Proceedings of Fifth International Symposium WAVES 2005, Madrid].Numerical simulations have been performed with the 1D-FUNWAVE model [Kirby, J.T., Wei, G., Chen, Q., Kennedy, A.B., and Dalrymple, R.A. (1998). “FUNWAVE 1.0 Fully Nonlinear Boussinesq Wave Model Documentation and User's Manual”. Research Report No CACR-98-06, Center for Applied Coastal Research, University of Delaware, Newark]. With regard to the adopted experimental conditions, the breaking location has been calculated for different trigger mechanisms [Zelt, J.A. (1991). “The run-up of nonbreaking and breaking solitary waves”. Coastal Engineering, 15, 205–246; Kennedy, A.B., Chen, Q., Kirby, J.T., and Dalrymple, R.A. (2000). “Boussinesq modeling of wave transformation, breaking and run-up. I: 1D”. Journal of Waterway, Port, Coastal and Ocean Engineering, 126, 39–47; Utku, M., and Basco, D.R. (2002). “A new criteria for wave breaking based on the Relative Trough Froude Number”. Proceedings of 28th International Conference on Coastal Engineering, ASCE, New York, 258–268] including the proposed BCI.The calculations have shown that BCI gives a better agreement with the physical data with respect to the other trigger criteria, both for spilling and plunging breaking events, with a not negligible reduction of the calculation time. 相似文献
10.
Approximately 20 km south of Mt. Etna craters, at the contact between volcanic and sedimentary formations, three mud volcanoes
discharge CO2-rich gases and Na–Cl brines. The compositions of gas and liquid phases indicate that they are fed by a hydrothermal system
for which temperatures of 100–150 °C were estimated by means of both gas and solute geothermometry. The hydrothermal system
may be associated with CO2-rich groundwaters over a large area extending from the central part of Etna to the mud volcanoes. Numerous data on the He,
CH4, CO2 composition of the gases of the three manifestations, sampled over the past 5 years, indicate clearly that variations are
due to separation processes of a CO2-rich gas phase from the liquid. The effects of these processes have to be taken into account in the interpretation of the
monitoring data collected for the geochemical surveillance of Etna volcano.
Received: 4 September 1995 / Accepted: 14 February 1996 相似文献