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The heat capacity and vibrational entropy of a calcium aluminate and three peraluminous calcium aluminosilicate glasses have been determined from 2 to 300 K by heat-pulse relaxation calorimetry. Together with previous adiabatic data for six other glasses in the system CaO-Al2O3-SiO2, these results have been used to determine partial molar heat capacities and entropies for five species namely, SiO2, CaO and three different sorts of Al2O3 in which Al is 4-, 5- and 6-fold coordinated by oxygen. Given the determining role of oxygen coordination on low-temperature heat capacity, the composition independent entropies found for SiO2 and CaO indicate that short-range order around Si and Ca is not sensitive to aluminum speciation up to the highest fraction of 25% observed for VAl by NMR spectroscopy. Because of the higher room-temperature vibrational entropy of IVAl2O3 (72.8 J/mol K) compared to VAl2O3 (48.5 J/mol K), temperature-induced changes from IVAl to VAl give rise to a small negative contribution of the order of 1 J/mol K to the partial molar configurational heat capacity of Al2O3 in melts. Near 0 K, pure SiO2 glass distinguishes itself by the importance of the calorimetric boson peak. On a g atom basis, the maximum of this peak varies with the composition of calcium aluminosilicate glasses by a factor of about 2. It does not show smooth variations, however, either as a function of SiO2 content, at constant CaO/Al2O3 ratio, or as a function of Al2O3 content, at constant SiO2 content. 相似文献
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Chaotic rock units exposed in the upper part of the accretionary complex preserve detailed tectonic information related to the periods before, during, and immediately after accretion. Based on the detailed survey in the upper Miocene Miura–Boso accretionary complex, central Japan, three types of chaotic rock units were identified on the basis of the grain sizes and characteristics of blocks and surrounding matrices. The chaotic rock units composed of silt matrices and sandy to pebbly blocks (Type 3) formed by gravity-driven slumping upon the seafloor. The slumping occurred contemporaneously with deposition of the Misaki and Nishizaki Formations within the Izu–Bonin forearc. Vertical variations in the direction of slump vergence represent successive changes from an initially flat seabed to tilting to the northwest and finally to the southeast. Slumping with a northwest vergence indicates landward tilting of the seafloor immediately prior to accretion, whereas vergence to the southeast reflects oceanward tectonic tilting that occurred once the sediments had crossed the deformation front. Other chaotic rock units that have matrices abundant in sand and pebbles (Types 1, 2) formed as a result of subsurface liquefaction and injection associated with large earthquakes that occurred during and after accretion of the sediments. These chaotic rock units are useful in examining surface/subsurface changes such as tectonic tilting of the seafloor and earthquake events during the initial accretion process. 相似文献
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