Calculation of Si NMR shifts of silicate complexes with carbohydrates, amino acids, and muhicarboxylic acids: potential role in biological silica utilization     

Nita Sahai 《Geochimica et cosmochimica acta》2004,68(2):227-237

The existence of ether or ester-like complexes of silicate with organic compounds has long been debated in the literature on biological utilization of silicon. Comparison of theoretically calculated ²⁹Si NMR chemical shifts for such complexes with experimentally measured values in biological systems could provide a diagnostic tool for identifying which, if any of these molecules exist under physiological conditions. Results are presented here for ab initio molecular orbital calculations of ²⁹Si NMR shifts and formation energies of silicate complexes with polyalcohols, sugar-acids, pyranose sugars, amino acids and multicarboxylic acids. The effects of functional group and molecular structure including ligand size, denticity, ring size, silicon polymerization and coordination number on calculated ²⁹Si shifts were considered. The potential role of such compounds in biological silica utilization pathways is discussed.²⁹Si NMR shifts and energies were calculated at the HF/6-311+G(2d,p)//HF/6-31G* level. The main result is that only five-membered rings containing penta- and hexa-coordinated Si can explain experimentally observed resonances at ∼ −101 and −141 ppm. Further, the heptet observed in ¹H-²⁹Si coupled spectra can only be explained by structures where Si bonds to oxygens atoms in H-C-O-Si linkages with six symmetrically equivalent H atoms.While compounds containing quadra-coordinated silicon may exist in intracellular silicon storage pools within diatoms, calculated reaction energies suggest that the organism has no thermodynamic advantage in taking up extracellular organ-silicate compounds, instead of silicic acid, from the ambient aqueous environment. Hyper-coordinated complexes are deemed unlikely for transport and storage, though they may exist as transient reactive intermediates or activated complexes during enzymatically- catalyzed silica polymerization, as known previously from sol-gel silica synthesis studies.  相似文献   

Upper Ocean Four-Dimensional Variational Data Assimilation in the Arabian Sea and Bay of Bengal     

Suneet Dwivedi  Atul Srivastava  Alok Kumar Mishra 《Marine Geodesy》2018,41(3):230-257

A regional ocean circulation model with four-dimensional variational data assimilation scheme is configured to study the ocean state of the Indian Ocean region (65°E–95°E; 5°N–20°N) covering the Arabian Sea (AS) and Bay of Bengal (BoB). The state estimation setup uses 10 km horizontal resolution and 5 m vertical resolution in the upper ocean. The in-situ temperature and salinity, satellite-derived observations of sea surface height, and blended (in-situ and satellite-derived) observations of sea surface temperature alongwith their associated uncertainties are used for data assimilation with the regionally configured ocean model. The ocean state estimation is carried out for 61 days (1 June to 31 July 2013). The assimilated fields are closer to observations compared to other global state estimates. The mixed layer depth (MLD) of the region shows deepening during the period of assimilation with AS showing higher MLD compared to the BoB. An empirical forecast equation is derived for the prediction of MLD using the air–sea forcing variables as predictors. The surface and sub-surface (50 m) heat and salt budget tendencies of the region are also investigated. It is found that at the sub-surface, only the advection and diffusion temperature and salt tendencies are important.  相似文献   

The impact of northern Indian Ocean rivers on the Bay of Bengal using NEMO global ocean model     

Srivastava Atul  Gera Anith  Momin Imran M.  Mitra Ashis Kumar  Gupta Ankur 《海洋学报(英文版)》2020,39(3):45-55

The effect of river runoff over the northern Indian Ocean(NIO) especially over the Bay of Bengal(Bo B) has been studied using global Nucleus for European Modelling of the Ocean(NEMO). Two sensitivity experiments, with and without river runoff are conducted and the influence of river runoff on the Indian Ocean hydrography,stratification and circulation features are studied. It is found that due to river runoff surface salinity over the northern Bo B decreases by more than 5 and the East India Coastal Current strengthens by 2 cm/s during post monsoon season. The fresh river water reaches up to 15°N in the Bo B and is the main cause for low salinity there.Sea surface temperature in the northwestern Bo B increases by more than 0.2℃ due to the river runoff in summer monsoon while surface cooling upto 0.2℃ is seen in north-west part of Bo B in winter season. The seasonal mixed layer depth in the region is found to be dependent on river runoff. The effect of vertical shear and Brunt Vaisala frequency on stratification is also examined. The ocean water becomes highly stratified up to 3 035 m due to the river runoff. It is found that the energy required for mixing is high in the northern and coastal Bo B.  相似文献   

Upper ocean high resolution regional modeling of the Arabian Sea and Bay of Bengal     

Suneet Dwivedi  Alok Kumar Mishr  Atul Srivastava 《海洋学报(英文版)》2019,38(5):32-50

In this paper, effort is made to demonstrate the quality of high-resolution regional ocean circulation model in realistically simulating the circulation and variability properties of the northern Indian Ocean(10°S–25°N,45°–100°E) covering the Arabian Sea(AS) and Bay of Bengal(BoB). The model run using the open boundary conditions is carried out at 10 km horizontal resolution and highest vertical resolution of 2 m in the upper ocean.The surface and sub-surface structure of hydrographic variables(temperature and salinity) and currents is compared against the observations during 1998–2014(17 years). In particular, the seasonal variability of the sea surface temperature, sea surface salinity, and surface currents over the model domain is studied. The highresolution model's ability in correct estimation of the spatio-temporal mixed layer depth(MLD) variability of the AS and BoB is also shown. The lowest MLD values are observed during spring(March-April-May) and highest during winter(December-January-February) seasons. The maximum MLD in the AS(BoB) during December to February reaches 150 m (67 m). On the other hand, the minimum MLD in these regions during March-April-May becomes as low as 11–12 m. The influence of wind stress, net heat flux and freshwater flux on the seasonal variability of the MLD is discussed. The physical processes controlling the seasonal cycle of sea surface temperature are investigated by carrying out mixed layer heat budget analysis. It is found that air-sea fluxes play a dominant role in the seasonal evolution of sea surface temperature of the northern Indian Ocean and the contribution of horizontal advection, vertical entrainment and diffusion processes is small. The upper ocean zonal and meridional volume transport across different sections in the AS and BoB is also computed. The seasonal variability of the transports is studied in the context of monsoonal currents.  相似文献   

Characterization and radiative impact of dust aerosols over northwestern part of India: a case study during a severe dust storm     

Atinderpal Singh  Shani Tiwari  Deepti Sharma  Darshan Singh  Suresh Tiwari  Atul Kumar Srivastava  Neeraj Rastogi  A. K. Singh 《Meteorology and Atmospheric Physics》2016,128(6):779-792

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Maximum entropy spectral analysis of total ozone: Errata     

R. P. Kane  Y. Sahai  N. R. Teixeira 《Pure and Applied Geophysics》1985,123(4):638-640

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Low-latitude total ozone measurements in the Brazilian sector     

Y. Sahai  R. P. Kane  N. R. Teixeira 《Pure and Applied Geophysics》1982,120(4):615-625

Regular measurements of the atmospheric ozone in the Brazilian sector were started at Cachoeira Paulista (22.7°S, 45.0°W), and Natal (5.8°S, 35.2°W) in May 1974 and November 1978, respectively. The results of the total ozone measurements carried out at these two stations up to 1981 are presented in this communication and compared with other low-and mid-latitude stations. Although Natal is an equatorial station, it presents a prominent annual variation, and the average total ozone content is high compared to satellite measurements. During 1977–78, abnormally low values of total ozone were observed at Cachoeira Paulista. Some preliminary results about the QBO 9quasi-biennial oscillation) during 1974–81 are also presented.  相似文献   

Judicial acceptance of remote sensing     

Baldev Sahai 《Journal of the Indian Society of Remote Sensing》1995,23(2):31-32

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Remote sensing in land transformation and management     

Baldev Sahai 《Journal of the Indian Society of Remote Sensing》1988,16(4):1-4

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Prediction and monitoring of monsoon intraseasonal oscillations over Indian monsoon region in an ensemble prediction system using CFSv2   总被引：1，自引：0，他引：1  

S. Abhilash  A. K. Sahai  N. Borah  R. Chattopadhyay  S. Joseph  S. Sharmila  S. De  B. N. Goswami  Arun Kumar 《Climate Dynamics》2014,42(9-10):2801-2815

An ensemble prediction system (EPS) is devised for the extended range prediction (ERP) of monsoon intraseasonal oscillations (MISO) of Indian summer monsoon (ISM) using National Centers for Environmental Prediction Climate Forecast System model version 2 at T126 horizontal resolution. The EPS is formulated by generating 11 member ensembles through the perturbation of atmospheric initial conditions. The hindcast experiments were conducted at every 5-day interval for 45 days lead time starting from 16th May to 28th September during 2001–2012. The general simulation of ISM characteristics and the ERP skill of the proposed EPS at pentad mean scale are evaluated in the present study. Though the EPS underestimates both the mean and variability of ISM rainfall, it simulates the northward propagation of MISO reasonably well. It is found that the signal-to-noise ratio of the forecasted rainfall becomes unity by about 18 days. The potential predictability error of the forecasted rainfall saturates by about 25 days. Though useful deterministic forecasts could be generated up to 2nd pentad lead, significant correlations are found even up to 4th pentad lead. The skill in predicting large-scale MISO, which is assessed by comparing the predicted and observed MISO indices, is found to be ~17 days. It is noted that the prediction skill of actual rainfall is closely related to the prediction of large-scale MISO amplitude as well as the initial conditions related to the different phases of MISO. An analysis of categorical prediction skills reveals that break is more skillfully predicted, followed by active and then normal. The categorical probability skill scores suggest that useful probabilistic forecasts could be generated even up to 4th pentad lead.  相似文献