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Biogenic barium, mostly in the barite (BaSO4) form, has been proposed as a tracer for export production in the ocean. Here we report on biogenic barium (Baxs) and particulate organic carbon (POC) fluxes from sediment traps deployed at the DYFAMED site in the Northwestern Mediterranean Sea. Baxs fluxes display average values of 37 ± 45 and 50 ± 58 μg/m2/d at 200 and 1000 m respectively, and are linearly correlated to POC fluxes (mean values of 7.9 ± 9.3 and 6.8 ± 6.8 mg C/m2/d at 200 and 1000 m). Export production estimates, calculated using published Baxs- or POC-based algorithms, all fall below or close to the lower limit of potential export values proposed in the literature. This work clearly demonstrates the usefulness of Baxs as a tracer of oceanic export production in the Northwestern Mediterranean Sea. However, development of a quantitative export production proxy requires a clear understanding of the underlying cause(s) for the observed spatial variations in the relationship between Baxs and POC fluxes. The present study confirms that the processes leading to barite formation differ between margin and open-ocean sites and probably account for much of the regional variability in the POC/Baxs ratio.  相似文献   
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Exhumation during crustal folding in the Namche-Barwa syntaxis   总被引:6,自引:0,他引:6  
Geological observation in the eastern end of the Himalaya shows that the Asia/India Suture is folded. Metamorphic rocks derived from India occur structurally below the suture, in the core of a regional antiform. Isotopic and fission track dating establish cooling-exhumation of rocks from c.30 km depth within the last 4 Myr. We argue that exhumation is caused by ~ 10 mm yr-1 erosion coeval with crustal scale folding.  相似文献   
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High‐precision 232Th–208Pb dates have been obtained from allanite porphyroblasts that show unambiguous microstructural relationships to fabrics in a major syn‐metamorphic fold in the SE Tauern Window, Austria. Three porphyroblasts were analysed from a single garnet mica schist from the Peripheral Schieferhülle in the core of the Ankogel Synform, one of a series of folds which developed shortly before the thermal peak of Alpine epidote–amphibolite facies metamorphism: allanite grain 1 provided two analyses with a combined age of 27.7 ± 0.7 Ma; grain 2, which was slightly bent and fractured during crenulation, provided two analyses with a combined age of 27.7 ± 0.4 Ma; a single analysis from grain 3, which overgrew an already crenulated fabric, gave an age of 28.0 ± 1.4 Ma. The five 232Th–208Pb ages agree within error and define an isochron with an age of 27.71 ± 0.36 Ma (95% confidence level; MSWD = 0.46). The results imply that the crenulation event was in progress in a short interval (<1 Ma) c. 28 Ma, and that the Ankogel Synform was forming at this time. The thermal peak of regional metamorphism in the SE Tauern Window was probably attained shortly after 28 Ma, only c. 5 Ma after eclogite facies metamorphism in the central Tauern Window. Metasediment may contain allanite porphyroblasts with clear‐cut microstructural relationships to fabric development and metamorphic crystallization; for such rocks, 232Th–208Pb dating on microsamples offers a powerful geochronological tool.  相似文献   
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The adsorption/desorption ratio is an important quantity of the displacement of heavy metals in the soil. Adsorption isotherms as controlled quantities are suitable for the development of a transport model. With the aid of the T value the sorption coefficients and distribution quotients can be determined for different soils. By two examples of simulation the migrations of Cd and Pb were calculated with soil samples of warp clay/gley and loam/para-brown earth. It was found, inter alia, that with increasing time of input the concentration of dissolved and adsorbed heavy metals grows and that the added heavy-metal ions are absorbed in the uppermost layers already. For cases of continuous input the simulation model is recommended for the practice to estimate the migration of heavy metals in soils.  相似文献   
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The author reviews the historical background of the analytical orthoprojector and examines the design requirements for this instrument. The construction and performance of the Zeiss (Oberkochen)Z2 orthoprojector are described and an assessment is made of its practical advantages.  相似文献   
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Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.
Jane M. HammarstromEmail: Phone: +1-703-6486165Fax: +1-703-6486252
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