Modified column flotation of adsorbing iron hydroxide colloidal precipitates     

F. Capponi  M. SartoriM.L. Souza  J. Rubio 《International Journal of Mineral Processing》2006

A promising technique for the removal of heavy metal ions from wastewater streams involved firstly the ions adsorption on a colloidal precipitate (carrier) and then the separation of the loaded flocs (coagula) by a modified column flotation. Here, the effluent feed and the carrier (ferric hydroxide) enter smoothly by the top of the column through a special diffuser, in counter current with rising bubbles (100–600 μm diameter) generated by using recycled water, surfactant and air suction through a venturi. High separation values of the column flotation of the carrier precipitates were achieved, despite the high superficial flow rate and the high Fe^+ 3 concentration utilized (> 60 mg L^− 1 Fe). No rupture of colloidal carrier aggregates was observed and a low split was ensured by monitoring the concentrate (floated product) flow rate. Results indicated that best separation was attained by controlling the medium pH (for best heavy metal ion adsorption onto the carrier), followed by sodium oleate, used as “collector” and optimizing operating parameters (conditioning, flow rates, etc.). The column throughput reached 43 m h^− 1 (m³ m^− 2 h^− 1), which is about 4 times the normal capacity of DAF-dissolved air flotation unit, the most used floater in wastewater treatment. Various metals (Cu, Ni, Pb, etc.) and molybdate ions present in synthetic and real effluent were successfully removed based on this colloidal adsorbing flotation principle. The process was also applied in a pilot scale to treat an industrial electroplating wastewater. Most of toxic metals (Cu, Ni and Zn) were reduced from initial concentrations of about of 2 to 10 mg L^− 1, to below 0.5 to 1.0 mg L^− 1, meeting local municipal discharge limits (but Cd ions). It is believed that flotation separation using medium-sized bubbles has great potential as a clean water and wastewater treatment technology.  相似文献   

Simulated oil spills at two offshore fields in the Arabian gulf     

W.J. Lehr  M.S. Belen  H.M. Cekirge 《Marine pollution bulletin》1981,12(11):371-374

A computer simulation program of oil spills in the Arabian Gulf, GULFSLIK II, is developed and applied to two offshore fields. The results of the simulation are examined to ascertain the risks to the neighboring coastal areas.  相似文献   

Numerical modelling of the potential effects of a dam on a coastal aquifer in S. Spain     

M. L. Calvache  S. Ibáñez  C. Duque  W. Martín‐Rosales  M. López‐Chicano  J. C. Rubio  A. González  C. Viseras 《水文研究》2009,23(9):1268-1281

This study presents the results of a three‐dimensional variable‐density numerical modelling of the Motril‐Salobreña coastal aquifer and the possible effects of the entry into service in May 2005 of the Rules Dam, located just 17 km from the coast. Present parameters of the Motril‐Salobreña aquifer show that the system's conditions are very similar to a natural regime. The dam will substantially alter aquifer recharge, as the entry flow through the alluvial sediments of the Guadalfeo River will be entirely cut off or drastically reduced. Different scenarios reproducing the possible evolution of the aquifer under operation of the Rules Dam have been modelled. In most cases, results indicate that the conditions of the aquifer would worsen, with a general advance of the freshwater–saltwater interface. The area with most risk of saltwater intrusion is the old mouth of the Guadalfeo River, where the mixing zone could advance 1200 m inland. It is proposed that maintaining a 5–6 Mm³ year^?1 ‘ecological flow’ in the Guadalfeo River could prevent this saline advance. This application demonstrates that variable‐density models are potentially useful tools for estimating the effects of dams on the hydrodynamic and hydrochemical conditions of a coastal aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Catastrophic,rainfall-induced debris flows in Andean villages of Tarapacá, Atacama Desert,northern Chile   总被引：1，自引：0，他引：1  

Sergio A. Sepúlveda  Sofía Rebolledo  James McPhee  Marisol Lara  Mauricio Cartes  Eduardo Rubio  David Silva  Nicolle Correia  Juan P. Vásquez 《Landslides》2014,11(3):481-491

In March 2012, during the rainy season in the Altiplano plateau, a >100-year return period rainfall event affected the deeply incised valleys of the Precordillera of the Tarapacá Region, northern Chile. This extreme event in a very arid region triggered a number of debris and mud flows that caused severe damage and destruction in several small villages along the Camiña and Tarapacá valleys. The highly vulnerable location of the villages on top of alluvial fans due to socioeconomic and cultural reasons is a key factor to explain the level of destruction in most villages. In this paper, this unusual, remarkable landslide event is described, and the hazard faced by these settlements for future rainfall episodes and possible mitigation measures are discussed.  相似文献   

ACE‐2 multiple angle micro‐pulse lidar observations from Las Galletas, Tenerife, Canary Islands     

Donna M. Powell  John A. Reagan  Manuel A. Rubio  Wayne H. Erxleben  James D. Spinhirne 《Tellus. Series B, Chemical and physical meteorology》2000,52(2):652-661

Multiple‐angle micro‐pulse lidar (MPL) observations were made at Las Galletas on Tenerife, Canary Islands during the Aerosol Characterization Experiment‐2 (ACE‐2) conducted June–July, 1997. A principal objective of the MPL observations was to characterize the temporal/spatial distributions of aerosols in the region, particularly to identify and profile elevated Saharan dust layers which occur intermittently during the June–July time period. Vertical and slant angle measurements taken 16 and 17 July characterize such an occurrence, providing aerosol backscatter, extinction, and optical depth profiles of the dust layer between 1 and 5 km above mean sea level (MSL). Additionally, horizontal measurements taken in Las Galletas throughout the 6‐week period provide a time profile of the varying aerosol extinction at the surface. This profile exhibits the alternating periods of clean maritime air and pollution outbreaks that typified the region. Horizontal measurements also provide some evidence suggesting the possible influx of Saharan dust from the free troposphere to the surface. This paper presents estimates of aerosol optical properties retrieved from the multi‐angle MPL measurements in addition to an outline of the methodologies employed to obtain these results.  相似文献   

Impacts of warm and cold situations in the Mediterranean basins on the West African monsoon: observed connection patterns (1979–2006) and climate simulations     

Bernard Fontaine  Javier Garcia-Serrano  Pascal Roucou  Belen Rodriguez-Fonseca  Teresa Losada  Fabrice Chauvin  Sébastien Gervois  Sivarajan Sijikumar  Paolo Ruti  Serge Janicot 《Climate Dynamics》2010,35(1):95-114

Using both empirical and numerical ensemble approaches this study focuses on the Mediterranean/West African relationship in northern summer. Statistical analyses utilize skin temperature, sea surface temperature, in situ and satellite rainfall, outgoing longwave radiation (OLR) observations and reanalyzed data winds and specific humidity on isobaric surfaces. Numerical investigations are based on a large set of sensitivity experiments performed on four atmospheric general circulation models (AGCM): ARPEGE-Climat3, ECHAM4, LMDZ4 and UCLA7.3. Model outputs are compared to observations, discussed model by model and with an ensemble (multi-model) approach. As in previous studies the anomalous Mediterranean warm events are associated with specific impacts over the African monsoon region, i.e., a more intense monsoon, enhanced flux convergence and ascendances around the ITCZ, a strengthening of low level moisture advection and a more northward location of ascending motion in West Africa. The results show also new features (1) thermal variability observed in the two Mediterranean basins has unalike impacts, i.e. the western Mediterranean covaries with convection in Gulf of Guinea, while the eastern Mediterranean can be interpreted as Sahelian thermal-forcing; (2) although observations show symmetry between warming and cooling, modelling evidences only support the eastern warming influence; (3) anomalous East warm situations are associated with a more northward migration of the monsoon system accompanied by enhanced southwertely flow and weakened northeasterly climatological wind; (4) the multi-model response shows that anomalous East warm surface temperatures generate an enhancement of the overturning circulation in low and high levels, an increase in TEJ (Tropical Eeasterly Jet) and a decrease in AEJ (African Eeasterly Jet).  相似文献   

P-T evolution of eclogites from the Agualada Unit (Ordenes Complex, northwest Iberian Massif, Spain): Implications for crustal subduction     

R. Arenas  J. Abati  J.R. Martí  nez Catal  n  F. Dí  az Garcí  a  F.J. Rubio Pascual 《Lithos》1997,40(2-4):221-242

Eclogite lenses in the Agualada Unit (western Ordenes Complex, Spain) contain the peak mineral assemblage garnet (prograde rim: Alm = 48 mol%, Prp = 30 mol%), omphacite (Jd max = 36 mol%), quartz, rutile and rare zoisite, which equilibrated at T = 700 °C and P > 12–14 kbar. Garnet shows discontinuous growth zoning, with a pyrope-poor intermediate zone (Alm = 51 mol%, Prp = 10 mol%) between a core zone where pyrope is slightly higher (Alm = 46 mol%, Prp = 16 mol%) and areas just inward from the rims where the maximum pyrope contents (Alm = 48 mol%, Prp = 30 mol%) are recorded. In atoll interiors, garnet contains inclusions of a first generation of omphacite (Jd max = 40 mol%). This omphacite is replaced in the matrix by a second generation (Jd max = 36 mol%) with higher Fe/Fe + Mg ratio. The compositions of garnet and omphacite suggest a complex syneclogitic tectonothermal evolution for the Agualada Unit, characterized by: (1) eclogite-facies metamorphism (T = 585 °C, P > 12–13 kbar), followed by (2) cooling during a slight decompression (T = 500 °C, P > 11–12 kbar), and (3) a final increase in P and T to form the garnet rim-matrix omphacite mineral assemblage. The Agualada Unit is part of a subduction complex which affected the Gondwana margin at the beginning of the Variscan cycle. The P-T evolution of the Agualada eclogites is closely related to the structural evolution of the accretionary complex and the whole orogenic wedge. The cooling event recorded by the Agualada eclogites may have resulted from the accretion of a new colder crustal slice under the unit, whereas the final progradation reflects the emplacement of the Agualada Unit directly under the mantle wedge. This evolution fits well with previously presented the retical models, both for the tectonothermal evolution of accretionary complexes and for the dynamic evolution of orogenic wedges. P-T paths such as the one for the Agualada Unit eclogites, probably reflect a prolonged structural evolution. Although evidently rarely preserved, such paths are probably the rule rather than the exception during plate convergence.  相似文献   

Phylogeographical patterns of the gastropod Siphonaria pectinata (Linnaeus, 1758)          下载免费PDF全文

Free Espinosa  Clara Morey‐Rubio  Tomoyuki Nakano 《Marine Ecology》2016,37(1):227-233

Siphonaria pectinata is a marine gastropod distributed across the shores of the Western and Eastern Atlantic. Although previous studies have indicated that the species could be a recent introduction to Central and North America from Western Africa and Europe, other authors have questioned this statement. In fact, a recent study has shown that individuals from both sides of the Atlantic are genetically disconnected, rejecting the idea of a recent invasion. However, genetic information on this species is very scarce and based only on a single study using a limited number of specimens and sites. The data reported in the present study represent one step forward, collecting information from 119 specimens from 22 sites that cover the entire distributional range of the species. Populations from the Western Atlantic separated from eastern ones around 1.4?1.9 Mya, whereas the centre of dispersion is located on the eastern side of the Atlantic. Siphonaria pectinata should be considered native to the Western Atlantic and cannot be considered as a species with an amphi‐atlantic distribution owing to the lack of genetic connection between both sides of the Atlantic, as previous authors have pointed out. The presence of a star‐shaped phylogeny is discussed in the context of Plio‐Pleistocene glaciations.  相似文献   

Beach morphodynamics forcements in oiled shorelines: Coupled physical and chemical processes during and after fuel burial     

Bernabeu AM  Nuez de la Fuente M  Rey D  Rubio B  Vilas F  Medina R  González ME 《Marine pollution bulletin》2006,52(10):1156-1168

In November 2002, the sinking of the Prestige oil tanker off the Galician coast (N.W. Spain) caused the largest ecological catastrophe in the history of Spain, affecting the coast called the 'Costa da Morte' (Galicia, N.W. Spain). This work is focused on the study of the oil contamination of the intertidal area of two beaches located on this stretch of coast. The study of twenty cores extracted from both beaches has identified fuel embedded in the sedimentary column up to a depth of 2.38 m (this being the maximum depth of extraction). This, along with the presence of oil below the groundwater indicates the existence of a new factor which determines the burial of oil: the morphodynamic behaviour of the beach. Furthermore, this morphodynamic variation conditions the physical appearance of the buried oil. Four different types have been identified: tar-balls (cm), particles (mm), oil coatings on sediment grains and on emulsion, with distribution patterns conditioned by the degree of wave exposure. The analysis of the information obtained have permitted the development of a conceptual model of the burial and oil evolution in the sedimentary column in relation to wave exposure, and thus to the morphodynamic variability of the beach.  相似文献   

A Hubble Space Telescope/NICMOS view of the prototypical giant Hii region NGC604 in M33     

Rodolfo H. Barbá  Jesús Maíz Apellániz  Enrique Pérez  Mónica Rubio  Alberto Bolatto  Cecilia Fariña  Guillermo Bosch  Nolan R. Walborn 《Astrophysics and Space Science》2009,324(2-4):309-313

We present the first high-spatial-resolution near-infrared (NIR) imaging of NGC604, obtained with the NICMOS camera onboard the Hubble Space Telescope (HST). These NICMOS broad-band images reveal new NIR point sources, clusters, and diffuse structures. We find an excellent spatial correlation between the 8.4 GHz radio continuum and the 2.2 μm nebular emission. Moreover, massive young stellar object candidates appear aligned with these radio peaks, reinforcing the idea that those areas are star-forming regions. Three different scaled OB associations are recognized in the NICMOS images. The brightest NIR sources in our images have properties that suggest that they are red supergiant stars, of which one was previously known. This preliminary analysis of the NICMOS images shows the complexity of the stellar content of the NGC604 nebula.  相似文献