Boron incorporation into mullite     

K. J. Griesser  A. Beran  D. Voll  H. Schneider 《Mineralogy and Petrology》2008,92(3-4):309-320

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria  相似文献   

The occurrence of OH absorptions in phenakite—an IR spectroscopic study     

Prof. Dr. A. Beran 《Mineralogy and Petrology》1990,41(2-4):73-79

Summary IR spectra of phenakite single crystals from different localities show a distinct variability in the region of the OH stretching fundamental. Minute hydrous mineral phases (tourmaline, bertrandite) are included in Piracicaba phenakite. Structural OH, ranging up to 0.005 equivalent wt.% H₂O, is characterized by two extremely pleochroic bands centered at 3380 and 3120 cm^–1. On the basis of their pleochroic scheme it is proposed that (O₂(OH)₂) and (O₃(OH)) tetrahedra occur as structural elements, assuming that the vacancies are on Be sites.

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Das Auftreten von OH Absorptionen in Phenakit—eine IR spektroskopische Untersuchung

Zusammenfassung Die IR Spektren von Phenakit-Einkristallen verschiedener Vorkommen zeigen im Bereich der OH-Streckschwingungen eine deutliche Variabilität. Piracicaba Phenakit enthält feinste Einschlüsse von OH-hältigen Mineralphasen (Turmalin, Bertrandit). Strukturell gebundene OH-Gruppen (bis 0,005 äquivalente Gew.% H₂O) sind durch zwei extrem pleochroitische Banden bei 3380 und 3120 cm^–1 charakterisiert. Unter der Annahme von Be-Leerstellen werden aufgrund des Pleochroismus dieser Banden (O₂(OH)₂) und (O₃(OH)) Tetraeder als strukturelle Baueinheiten vorgeschlagen.

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With 3 Figures  相似文献   

Size Scaling of Cross Correlation Between Multiple Variables     

Oz  Bora  Deutsch  Clayton V. 《Natural Resources Research》2002,11(1):1-18

Reservoir models have large uncertainty because of spatial variability and limited sample data. The ultimate aim is to use simultaneously all available data sources to reduce uncertainty and provide reliable reservoir models for resource assessment and flow simulation. Seismic impedance or some other attribute provides a key source of data for reservoir modeling. These seismic data are at a coarser scale than the hard well data and it not an exact measurement of facies proportions or porosity. A requirement for data integration is the cross-covariance between the well and seismic data.The size-scaling behavior of the cross correlation for different measurement scales was nvestigated. The size-scaling relationship is derived theoretically and validated by numerical studies (including an example with real data). The limit properties of the cross-correlation coefficient when the averaging volume becomes large is shown. After some averaging volume, the volume-dependent cross-correlation coefficient reaches a limit value. This plateau value is controlled mainly by the large-scale behavior of the cross and direct variograms.The cross correlation can increase or decrease with volume support depending on the relative importance of long- and short-scale covariance structures. If the direct and cross variograms are proportional, there is no change in the cross correlation as the averaging volume changes. Our study shows that the volume-dependent cross-correlation coefficient is sensitive to the shape of the cross variogram and differences between the direct variograms of the well data and seismic data.  相似文献   

An Integrated Geomechanical Investigation,Multi-Parameter Monitoring and Analyses of Babadağ-Gündoğdu Creep-like Landslide     

Halil Kumsar  Ömer Aydan  Hisataka Tano  Sefer Beran Çelik  Reşat Ulusay 《Rock Mechanics and Rock Engineering》2016,49(6):2277-2299

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Field evidence for normal fault linkage and relay ramp evolution: the Kırkağaç Fault Zone,western Anatolia (Turkey)     

Bora Uzel 《Geodinamica Acta》2016,28(4):311-327

Linking of normal faults forms at all scales as a relay ramp during growth stages and represents the most efficient way for faults to lengthen during their progressive formation. Here, I study the linking of normal faulting along the active K?rka?aç Fault Zone within the west Anatolian extensional system to reconstruct fault interaction in time and space using both field- and computer-based data. I find that (i) connecting of the relay zone/ramp occurred with two breaching faults of different generations and that (ii) the propagation was facilitated by the presence of pre-existing structures, inherited from the ?zmir-Bal?kesir transfer zone. Hence, the linkage cannot be compared directly to a simple fault growth model. Therefore, I propose a combined scenario of both hangingwall and footwall fault propagation mechanisms that explain the present-day geometry of the composite fault line. The computer-based analyses show that the approximate slip rate is 0.38 mm/year during the Quaternary, and a NE–SW-directed extension is mainly responsible for the recent faulting along the K?rka?aç Fault Zone. The proposed structural scenario also highlights the active fault termination and should be considered in future seismic hazard assessments for the region that includes densely populated settlements.  相似文献   

Wolframite- and scheelite-bearing carbonate rocks of the Nock mountains,Austria: A new type of tungsten mineralization in the Eastern Alps     

H. Neinavaie  F. Thalmann  B. Ataii  A. Beran 《Mineralium Deposita》1989,24(1):14-18

A new type of tungsten deposit was discovered in the Eastern Alps at the Mallnock, Nock mountains, Austria. The mineralization is restricted to concordant layers of carbonate rocks within phyllites belonging to the metamorphic Palaeozoic of the Upper Austroalpine Gurktal nappe system. Wolframite (ferberite 95) and scheelite occur as network fissure fillings in coarse-grained Fe-magnesite (siderite 15) rocks (average W content ca. 0.9 wt%); fine-grained dolomite marbles contain scheelite as the only tungsten mineral (average W content ca. 0.5 wt%). Assuming the dolomite marbles as a primary metal source, mobilization processes are responsible for the formation of the wolframite- and scheelite-bearing Fe-magnesite rocks.  相似文献   

Polarized single-crystal FTIR-spectra of natural staurolite     

Monika Koch-Müller  Klaus Langer  Anton Beran 《Physics and Chemistry of Minerals》1995,22(2):108-114

Polarized infrared absorption spectra of thin single-crystal slabs parallel to (010) and (001) of a staurolite from Pizzo Forno, Ticino, with analyzed composition (Fe_2.9Mg_0.9Zn_0.1Mn_0.1)Al_17.5Ti_0.1(Si_7.7Al_0.3)O₄₈H₃ have been measured in the range of 3000–4000 cm^?1. From the pleochroitic behaviour of the OH-vibrations three groups of bands can be distinguished: the bands of group I, a strong band at 3445 cm^?1 plus a weak shoulder at 3358 cm^?1, and the bands of group II, a weak band centered at 3677 cm^?1 plus a shoulder at 3635 cm^?1, are assigned to the H1 and H2 protons, respectively. The bands of group III, a weak band at 3577 cm^?1 plus a shoulder, cannot be interpreted on the basis of the proton positions known so far. We assign them to an additional proton H3, which is bonded to O1 and shows a bifurcated hydrogen bridge to two O5 in a vacant T2 site.  相似文献   

Book reviews     

Krings  Th.  Bora  Lakshmi N.  West  Robert C.  Rugg  Dean S.  Tietze  Wolf  Grotewold  Andreas  Hellen  J. A. 《GeoJournal》1990,22(3):381-384

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A model of the OH positions in olivine,derived from infrared-spectroscopic investigations     

A. Beran  A. Putnis 《Physics and Chemistry of Minerals》1983,9(2):57-60

Polarized infrared (IR) spectroscopy of olivine crystals from Zabargad, Red Sea shows the existence of four pleochroic absorption bands at 3,590, 3,570, 3,520 and 3,230 cm^?1, and of one non pleochroic band at 3,400 cm^?1. The bands are assigned to OH stretching frequencies. Transmission electron microscopy (TEM) shows no oriented intergrowths in this olivine; it is concluded that OH is structural. On the basis of the pleochroic scheme of the absorption spectra it is proposed that [□O(OH)₃] and [□O₂(OH)₂] tetrahedra occur as structural elements, assuming that the vacancies are on Si sites. If M2 site vacancies were assumed [SiO₃(OH)] and [SiO₂(OH)₂] tetrahedra occur as structural elements.  相似文献   

Die Manganschiefer der Strubbergschichten (Nördliche Kalkalpen, Österreich) — eine diagenetisch geprägte Mangankarbonatvererzung     

Univ.-Doz. Dr. A. Beran  Univ.-Doz. Dr. P. Faupl  Dr. W. Hamilton 《Mineralogy and Petrology》1983,31(3-4):175-192

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